Metalloporphyrins Catalyzed Oxidations

Buch | Softcover

354 Seiten

2010 | Softcover reprint of hardcover 1st ed. 1994
Springer (Verlag)
978-90-481-4355-9 (ISBN)

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Oxidative catalysis by metalloporphyrin systems occupies a prominent role in the current research in the fields of chemical and biological catalysis. Our particular interest and approach has been to collect in the same volume papers dealing with both the chemical and biological aspects of the reactivity of heme systems because of the realization that a better understanding of the complementary discipline can be extremely useful for the researchers from either field. The current progress of the research on synthetic metalloporphyrin catalysts has led to the development of several systems that are able to reproduce the heme-enzyme mediated oxygenation and oxidation reactions, at least in terms of reaction types, mechanisms and often rates. These achievements have stimulated the of creating metalloporphyrin catalysts which are both ambitious project efficient and stable enough to become competitive for large-scale industrial processes. Although this project is still far from being realized, the efforts in this direction parallel those aimed at the application of heme enzymes to chemical technologies, e. g. for the mild, selective oxidation of organics or the detoxification of pollutants. Both the two approaches will be advantageous because while the enzyme systems can achieve selectivities which are probably unattainable by synthetic catalysts, the latter can be active under experimental conditions that would readily inactivate the enzymes.

General Overview on Oxidations Catalyzed by Metalloporphyrins; B. Meunier. The Synthesis of Meso-Substituted Porphyrins; J.S. Lindsey. Oxidation of Alkanes; A.E. Shilov, E.I. Karasevich. Oxidations Catalyzed by Ruthenium Porphyrins; T. Mlodnicka, B.R. James. Oxygenation Reactions under Two-Phase Conditions; F. Montanari, S. Banfi, G. Pozzi, S. Quici. Nitrene and Carbene Transfer Catalyzed by Metalloporphyrins; D. Mansuy, J.P. Mahy. On the Electronic Structure of Oxo-Metalloporphyrins and Mechanistic Aspects of Oxygen-Transfer Reactions; K.A. Jorgensen. Biological Oxidations: Stereochemical Aspects; L. Casella, S. Colonna. Index.

Erscheint lt. Verlag	9.12.2010
Reihe/Serie	Catalysis by Metal Complexes ; 17
Zusatzinfo	XIV, 354 p.
Verlagsort	Dordrecht
Sprache	englisch
Maße	155 x 235 mm
Themenwelt	Naturwissenschaften ► Biologie ► Biochemie
	Naturwissenschaften ► Chemie ► Anorganische Chemie
	Naturwissenschaften ► Chemie ► Organische Chemie
	Naturwissenschaften ► Chemie ► Technische Chemie
	Technik
ISBN-10	90-481-4355-1 / 9048143551
ISBN-13	978-90-481-4355-9 / 9789048143559
Zustand	Neuware