Microstructure and Properties of Micro- and Nanoscale Materials, Films, and Coatings (NAP 2019) (eBook)

Selected Articles from the International Conference on Nanomaterials: Applications and Properties, (NAP 2019)

Alexander D. Pogrebnjak, Oleksandr Bondar (Herausgeber)

eBook Download: PDF

2020 | 2020
XXIII, 404 Seiten
Springer Singapore (Verlag)
978-981-15-1742-6 (ISBN)

Infos

This book presents the findings of experimental and theoretical (including first-principles molecular dynamics simulation) studies of nanostructured and nanocomposite metal-based materials, and nanoscale multilayer coatings fabricated by physical or chemical vapor deposition, magnetron sputtering, electrospark alloying, ionic layer absorption, contact melting, and high-current electron beam irradiation. It also discusses novel methods of nanocomposite formation, as well as the structure of the deposited films, coatings and other nanoscale materials, their elemental and phase composition, and their physical-mechanical, tribological, magnetic and electrical properties. Lastly, it explores the influence of a various surface modification methods, such as thermal annealing, pulsed laser modification, and thermomechanical and ultrasonic treatment, as well as different properties of nanostructured films.

Alexander Pogrebnjak is a Professor at the Nanoelectronics Department Chair at Sumy State University, Ukraine. His scientific interests are related to nanocomposite and layered coatings, high-entropy alloy nitrides, improving physical-mechanical and chemical properties of materials using nanosized films, and modification of properties of metals and alloys by high-power particle beams. Prof. Pogrebnjak has been a Visiting Scientist at Helsinki Technology University (Finland), Trento University (, Italy), Los Alamos National Laboratory and Sandia National Laboratories (USA), the National Institute for Materials Science (Tsukuba, Japan), Lublin University of Technology (Poland), and the University of Poitiers (France). He has co-authored 14 book chapters and over 315 peer-reviewed scientific articles.

 

Dr. Oleksandr Bondar is a Leading Researcher of the Department of Nanoelectronics at Sumy State University, Ukraine. His scientific interests are related to nanostructured and nanocomposite multilayer coatings based on nitrides, carbides of transition and refractory metals, and surface treatment of materials using high-temperature annealing or high-dose ion implantation to improve the protective properties of the coatings. Dr. Bondar has been a Visiting Scientist at the University of Poitiers (France), Adam Mickiewicz University (Poznan, Poland), the National Institute for Materials Science (Tsukuba, Japan), and Riga Technical University (Latvia). He has co-authored 2 patents, 5 book chapters and over 60 peer-reviewed scientific articles.

Inhalt

Preface 6
Contents 7
Contributors 12
1 Electrical and Magnetic Behavior of GdOH Thin Films: A Search for Hydrogen Anion Superconductivity 23
1.1 Introduction 23
1.2 Experiment Details 24
1.2.1 Samples Preparation 24
1.2.2 Measurements Techniques 25
1.3 Results and Discussion 25
References 29
2 Electrical Properties of Heterojunction n-MoOx/p-Cd3In2Te6 30
2.1 Introduction 30
2.2 Experiment Details 31
2.3 Results and Discussion 31
2.4 Conclusions 35
References 35
3 Transport Properties of Cubic Cuprous Iodide Films Deposited by Successive Ionic Layer Adsorption and Reaction 39
3.1 Introduction 39
3.2 Experimental Procedure 42
3.3 Results and Discussion 44
3.4 Conclusions 49
References 50
4 Optical Absorption and Refractive Index of X-ray Irradiated Cu6PSe5I-Based Thin Film 51
4.1 Introduction 51
4.2 Experiment Details 52
4.3 Results and Discussions 53
4.4 Conclusions 55
References 55
5 Study of the Correlations Between the Dynamics of Thermal Destruction and the Morphological Parameters of Biogenic Calcites by the Method of Thermoprogrammed Desorption Mass Spectrometry (TPD-MS) 57
5.1 Introduction 58
5.2 Experiment Details 59
5.3 Results and Discussion 59
5.4 Conclusions 68
References 69
6 Floquet-Bloch Theory for Semiconductor Bragg Structure 71
6.1 Introduction 71
6.2 Floquet—Bloch Waves Theory 72
6.3 Analysis of Results 76
6.4 Conclusions 77
References 78
7 Investigation of the Process of Spatial Self-organization of Linear Defects in Nanocrystalline Materials 80
7.1 Introduction 80
7.2 Basic Equations 81
7.3 Stationary Value of Dislocation Velocity 84
7.4 Effective Energy 85
References 87
9 Temperature Dependence of Conductivity in Composite Film of Single-Walled Carbon Nanotubes with Graphene Oxide 97
9.1 Introduction 97
9.2 Experimental Details 98
9.2.1 Materials 98
9.2.2 Methods 99
9.3 Results and Discussion 99
9.3.1 Temperature Dependence of GO-SWNTs Composite Film Conductivity 99
9.3.2 Approximation of Temperature Dependencies of GO-SWNTs and SWNTs Films with Different Models 100
9.3.3 Parameters of Electronic Transport in GO-SWNTs and SWNTs Films Within Framework of VRH Model 103
9.4 Conclusions 104
References 106
10 Structure and Properties of Nitride Coatings Based on Ti and Cr Synthesized by PIII& D Technique
10.1 Introduction 108
10.2 Experiment Details 110
10.3 Results and Discussion 112
10.4 Conclusions 119
References 120
11 Features of the Microstructure of Multilayered (TiAlSiY)N/MoN Coatings Prepared by CA-PVD and Their Influence on Mechanical Properties 122
11.1 Introduction 123
11.2 Methods and Experiments 124
11.2.1 Deposition Technology 124
11.2.2 Investigation Methods 124
11.3 Results and Discussion 125
11.3.1 Surface Morphology and Elemental Composition 125
11.3.2 Phase State and Microstructure 126
11.3.3 Microhardness 128
11.4 Conclusions 128
References 129
12 Changing Cohesive Energy Between Atoms in Metal-to-Metal Transition Layer for Fe–Sn and Fe–Cu–Sn Compounds in the Course of Spark Alloying Process 134
12.1 Introduction 134
12.2 Analysis of Major Achievements and Publications 135
12.3 Research Results 139
12.4 Conclusions 147
References 148
13 New Process for Forming Multicomponent Wear-Resistant Nanostructures by Electrospark Alloying Method 151
13.1 Introduction 151
13.2 Problem Formulation. Analysis of Major Achievements and Publications 153
13.3 Research Methods 154
13.4 Research Results 155
13.5 Conclusions 160
References 164
14 Effect of Structure on the Properties of Composite Cr3C2 + NiCr Coatings 166
14.1 Introduction 166
14.2 General Information 167
14.2.1 Objectives 167
14.2.2 Materials and Conditions for Obtaining the Coatings 167
14.3 Results and Discussion 168
14.3.1 Microstructure Studies 168
14.3.2 Transmission Electron Microscopy 170
14.3.3 Analytical Evaluations of the Operational Properties 172
14.4 Conclusions 173
References 174
15 Combined Magnetron-Ion-Source System for Reactive Synthesis of Complex Nanostructured Coatings 175
15.1 Introduction 175
15.2 MISSS Design 176
15.3 Experimental Setup and Diagnostic Equipment 177
15.4 Physical Characterization of MISSS 178
15.5 Technological Characterization of MISSS 182
15.6 Discussion 186
15.7 Conclusions 188
References 188
16 AlCoNiFeCrTiVx High-Entropy Coatings Prepared by Electron-Beam Cladding 190
16.1 Introduction 190
16.2 Experiment Details 192
16.2.1 Materials and Processing 192
16.2.2 Structural Characterization 192
16.2.3 Mechanical Testing 193
16.3 Results and Discussion 193
16.3.1 Structure Evolution of Elemental Powders to Coatings by Electron-Beam Cladding 193
16.3.2 Microstructure Characterization of AlCoNiFeCrTiVx High-Entropy Coatings Resulted from Electron-Beam Cladding 196
16.3.3 Mechanical Properties of AlCoNiFeCrTiVx High-Entropy Coatings Resulted from Electron-Beam Cladding 196
16.4 Conclusions 196
References 198
17 A Novel Method for the Formation of Silver-Containing Nanocomposites—Thermochemical Reduction of Ag+ Ions in Polymer Films 200
17.1 Introduction 200
17.2 Experiment Details 201
17.3 Results and Discussion 201
17.4 Conclusions 203
References 205
18 Application of Multicomponent Wear-Resistant Nanostructures Formed by Electrospark Allowing for Protecting Surfaces of Compression Joints Parts 207
18.1 Introduction 208
18.2 Actual Scientific Researches and Issues Analysis 208
18.3 Research Methods 212
18.4 Research Results 212
18.5 Conclusions 217
References 219
19 Preparation, Properties and Application of Miscanthus Nanocellulose as Coating Layer 222
19.1 Background 222
19.2 Methods 223
19.3 Results and Discussion 225
19.4 Conclusions 229
References 229
20 Effect of Thermomechanical and Ultrasonic Treatment on the Properties of Amorphous Alloys 230
20.1 Introduction 231
20.2 Experimental Technique 231
20.3 Experimental Results and Discussion 232
20.4 Conclusions 236
References 236
22 Surface Phosphorylated Activated Carbons: Preparation and Acidity Studies 245
22.1 Introduction 245
22.2 Experimental 246
22.2.1 Materials 246
22.2.2 Methods 247
22.3 Results and Discussion 248
22.4 Conclusions 256
References 257
23 Flexible Thermostable Metal Spin-Valves Based on Co, Cu, Fe, Au, Ru Thin Films 259
23.1 Introduction 259
23.2 Experiment Details 260
23.3 Experiment Results 261
23.4 Application 264
23.5 Conclusions 268
References 269
24 Formation of Composite Reinforced Coating by Chemical Deposition and Chemical-Thermal Treatment of Boron and Carbon 271
24.1 Introduction 271
24.2 Materials and Methods 272
24.3 Discussion 273
24.4 Conclusions 280
References 280
25 The Effect of the Transition from Layered to Granular Structures on the Magnetoresistive Properties in the Systems Based on FexNi100?x and Cu 281
25.1 Introduction 281
25.2 Method and Technique of Experiment 282
25.3 Results and Discussion 283
25.4 Conclusions 286
References 286
26 Enhancement of the Wear Resistance of Tungsten Cobalt Carbide Plates Using Ion Implantation and Al–Si–N Coatings 288
26.1 Introduction 288
26.2 Experimental Technique 289
26.3 Results and Discussion 291
26.3.1 Effect of the Ion Implantation on the Wear Resistance of Carbide Plates 292
26.4 Conclusions 294
References 295
27 Contact Melting in Ag/Ge Layered Nanofilms: Critical Thickness and Onset Temperature 296
27.1 Introduction 296
27.2 Objects and Experimental Techniques 297
27.3 Experimental Results and Discussion 298
27.3.1 Critical Thickness of Contact Melting in Ag/Ge Films 298
27.3.2 Onset Temperature of Contact Melting in Ag/Ge Films 301
27.3.3 General Discussion 302
27.4 Conclusions 303
References 303
28 Characteristics of Nanocomposites Formed on the Steel Surface Contacting with Precious Metal Solutions 305
28.1 Introduction 305
28.2 Objects and Methods of the Research 306
28.3 Results and Discussion 307
28.3.1 A Study of the Phase Composition of Nanocomposite Particles Formed on the St3 Surface Contacting with Precious Metal Solutions 307
28.3.2 Kinetic Regularities of the Phase Formation Processes on the Steel Surface in the Presence of Precious Metals 309
28.3.3 Magnetic Properties of Composite Particles Formed on the Steel Surface When It Was Contacting with Precious Metal Water Solutions 310
28.4 Conclusions 313
References 314
29 Increase of Mechanical Properties of Weld Metal of High-Strength Low-Alloy Steels 315
29.1 Introduction 315
29.2 General Information 316
29.2.1 Objectives 316
29.2.2 Materials and Conditions for Obtaining of Welded Joints 316
29.2.3 Techniques and Equipment for Research 317
29.3 Results and Discussion 318
29.4 Conclusions 322
References 322
30 Effect of Growth Conditions on Structural and Optical Properties of SnS2 Thin Film 324
30.1 Introduction 324
30.2 Experimental Details 325
30.3 Results and Discussions 325
30.4 Conclusions 330
References 331
31 Effect of Mn Doping on the Optical Properties of Chalcogenide Compounds ZnS and ZnTe 332
31.1 Introduction 332
31.2 Experiment Details 333
31.3 Results and Discussions 335
31.4 Conclusions 340
References 341
33 Size-Dependent Melting Behavior of Silver Nanoparticles: A Molecular Dynamics Study 349
33.1 Introduction 349
33.2 Model 350
33.3 Results 353
33.4 Conclusions 356
References 357
34 Fabrication and Pulsed Laser Modification of Antireflective Composite Materials for the Visible and Near-IR Ranges 359
34.1 Introduction 359
34.2 Experiment Details 360
34.3 Results and Discussion 361
34.4 Conclusions 364
References 364
35 Photo- and Electroluminescence of Layered Structures Based on Silicon Oxide and Nitride Films 366
35.1 Introduction 366
35.2 Experiment Details 367
35.3 Results and Discussion 368
35.4 Conclusions 370
References 371
36 Influence of Hydrogen Annealing on Ordering in FePd Films with Ag Underlayer 372
36.1 Introduction 372
36.2 Experiment Details 374
36.3 Results 374
36.3.1 Annealing in the Vacuum 374
36.3.2 Annealing in the Hydrogen Atmosphere 377
36.4 Conclusions 381
References 381
38 Structure and Low-Temperature Properties of U-15 at.% T Alloys (T = Mo, Nb, Pt, Ru, Ti) 393
38.1 Introduction 393
38.2 Experiment Details 394
38.3 Results 395
38.3.1 Crystal Structure 395
38.3.2 Electrical Resistivity and Superconducting Transition 396
38.3.3 Specific Heat 398
38.4 Conclusions 398
References 399
39 Multilayer PECVD Si–C–N Films 400
39.1 Introduction 400
39.2 Experimental Details 401
39.3 Results and Discussion 402
39.3.1 Film Structure and Composition 403
39.3.2 Chemical Bonding Configurations 403
39.3.3 Optical Properties 404
39.3.4 Hardness and Wear Resistance 405
39.4 Conclusions 406
References 406

Produkt-Details

• Erscheint lt. Verlag: 28.1.2020
• Reihe/Serie: Springer Proceedings in Physics
• Reihe/Serie: Springer Proceedings in Physics
• Zusatzinfo: XXIII, 404 p.
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Physik / Astronomie ► Atom- / Kern- / Molekularphysik
• Themenwelt: Naturwissenschaften ► Physik / Astronomie ► Festkörperphysik
• Themenwelt: Technik ► Maschinenbau
• Schlagworte: Biogenic Calcites • Bismuth Oxysulfide Films • Cellulose-Chitosan Based Edible Films • Chemical Vapour Deposition • Cuprous Iodide Films • electron beam irradiation • Electrospark Alloying • magnetron sputtering • Multilayer Coatings • Nanocomposite coatings • Nanocomposite films • Optical Absorption • Phosphorylated Activated Carbons • Pulsed Laser Modification
• ISBN-10: 981-15-1742-8 / 9811517428
• ISBN-13: 978-981-15-1742-6 / 9789811517426