Advances in Organometallic Chemistry (eBook)

F.G.A. Stone (Herausgeber)

eBook Download: PDF

1995 | 1. Auflage
259 Seiten
Elsevier Science (Verlag)
978-0-08-058039-5 (ISBN)

Infos

This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branchesof chemistry now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry.

Key Features
* In basic research, organometallics have contributed inter alia to:
* Metal cluster chemistry
* Surface chemistry
* The stabilization of highly reactive species by metal coordination
* Chiral synthesis
* The formulation of multiple bonds between carbon and the other elements and between the elements themselves

---

This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branchesof chemistry now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry.In basic research, organometallics have contributed inter alia to:- Metal cluster chemistry- Surface chemistry- The stabilization of highly reactive species by metal coordination- Chiral synthesis- The formulation of multiple bonds between carbon and the other elements and between the elements themselves

Inhalt

Front Cover 1
Advances in Organometallic Chemistry, Volume 38 4
Copyright Page 5
Contents 6
Contributors 8
Chapter 1. Silyl Anions 10
I. Introduction 10
II. A Brief Survey of Preparative Methods 11
III. Arylsilyl Anions 12
IV. Alkylsilyl Anions 20
V. Functionalized Silyl Anions 25
VI. Polysilanyl Anions 34
VII. Synthetic Application of Silyl Anions 48
VIII. Theoretical Study 54
IX. 29Si NMR Data of Silyl Anions 57
X. List of Silyl Anions 58
XI. Concluding Remarks 62
References 62
Chapter 2. Not for Synthesis Only: The Reactions of Organic Halides with Metal Surfaces 68
I. Some Basic Considerations 68
II. Halide Adsorption on Metal Surfaces 72
III. Mechanistic Investigations of Applied Reactions 74
IV. Nonsynthetic Applications 78
V. Conclusions 83
References 84
Chapter 3. The Bonding of Metal–Alkynyl Complexes 88
I. Introduction 88
II. Theoretical and Experimental Background 91
III. X-Ray Crystallographic Studies 99
IV. Vibrational Spectroscopic Studies 129
V. Concluding Remarks 148
VI. Appendix: Abbreviations Used in This Review 149
References 150
Chapter 4. Organotransition-Metal Chemistry and Homogeneous Catalysis in Aqueous Solution 164
I. Introduction 164
II. Metal Alkyls 165
III. Tertiary Phosphines 173
IV. Homogeneous Catalysis 176
References 193
Chapter 5. Structure/Property Relationships of Polystannanes 198
I. Introduction. 198
II. Distannanes 199
III. Linear Polystannanes 214
IV. Branched Polystannanes 224
V. Cyclopolystannanes 226
VI. Polycyclic Polystannanes 241
VII. Conclusion 248
References 249
Index 254
Cumulative List of Contributors for Volumes 1–36 264
Cumulative List of Contributors for Volumes 37–38 268

Produkt-Details

• Erscheint lt. Verlag: 20.10.1995
• Mitarbeit: Herausgeber (Serie): Anthony F. Hill, Robert C. West
• Sprache: englisch
• Themenwelt: Sachbuch/Ratgeber
• Themenwelt: Medizin / Pharmazie ► Gesundheitsfachberufe
• Themenwelt: Medizin / Pharmazie ► Medizinische Fachgebiete ► Neurologie
• Themenwelt: Medizin / Pharmazie ► Medizinische Fachgebiete ► Psychiatrie / Psychotherapie
• Themenwelt: Naturwissenschaften ► Chemie ► Anorganische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Physikalische Chemie
• Themenwelt: Naturwissenschaften ► Geowissenschaften ► Mineralogie / Paläontologie
• Themenwelt: Technik ► Maschinenbau
• ISBN-10: 0-08-058039-4 / 0080580394
• ISBN-13: 978-0-08-058039-5 / 9780080580395