Advances in Organometallic Chemistry (eBook)

eBook Download: PDF

1997 | 1. Auflage
328 Seiten
Elsevier Science (Verlag)
978-0-08-058042-5 (ISBN)

Infos

This widely-acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon–metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambienttemperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry.
This book is an essential reference work for the academic and industrial chemist and will provide up-to-date material at the cutting edge of chemistry research.

Key Features
* In basic research, organometallics have contributed inter alia to:
* Metal cluster chemistry
* Surface chemistry
* The stabilization of highly reactive species by metal coordination
* Chiral synthesis
* The formulation of multiple bonds between carbon and the other elements and between the elements themselves
* Metal organic compounds of calcium, strontium, and barium in chemical vapor deposition
* 17- and 19-electron organometallic complexes
* Halocarbonyl complexes of molybdenum and tungsten
* Substituent effects in metallacene chemistry

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This widely-acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbonmetal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambienttemperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry.This book is an essential reference work for the academic and industrial chemist and will provide up-to-date material at the cutting edge of chemistry research.In basic research, organometallics have contributed inter alia to:- Metal cluster chemistry- Surface chemistry- The stabilization of highly reactive species by metal coordination- Chiral synthesis- The formulation of multiple bonds between carbon and the other elements and between the elements themselves- Metal organic compounds of calcium, strontium, and barium in chemical vapor deposition- 17- and 19-electron organometallic complexes- Halocarbonyl complexes of molybdenum and tungsten- Substituent effects in metallacene chemistry

Inhalt

Front Cover 1
Advances in Organometallic Chemistry, Volume 41 4
Copyright Page 5
Contents 6
Contributors 8
Chapter 1. Transition-Metal Assisted Syntheses of Rings and Cages from Phosphaalkenes and Phosphaalkynes 10
I. Introduction 10
II. Phosphaalkenes as Ligands in Transition-Metal Complexes 11
III. Rings and Cages from Phosphaalkenes 11
IV. Phosphaalkynes as Ligands in Transition-Metal Complexes 43
V. Rings and Cages from Phosphaalkynes 44
VI. Conclusions and Prospects 71
VII. Abbreviations Used in This Review 72
References 73
Chapter 2. Synthesis and Reactions of Polynuclear Cobalt–Alkyne Complexes 78
I. Introduction 78
II. Dinuclear Complexes 78
III. Trinuclear Clusters 114
IV. Tetranuclear Complexes 119
V. Higher Nuclearity Complexes 125
VI. Applications 126
VII. Conclusions 128
References 129
Chapter 3. Rhenium and Technetium Oxo Complexes in the Study of Organic Oxidation Mechanisms 136
I. Introduction 136
II. Methyl Rhenium Trioxide (MTO) 137
III. Bishydroxylation of Alkenes 151
IV. Conclusions 166
References 166
Chapter 4. (1 -Alkynyl)carbene Complexes (= 1-Metalla-1-buten-3-ynes): Tools for Synthesis 172
I. Introduction 174
II. Preparation, Spectroscopic and Structural Data 174
III. Reaction with Carbon Nucleophiles (and Homologs) 179
IV. Reaction with Nitrogen and Phosphorus Nucleophiles 203
V. Reaction with Oxygen and Sulfur Nucleophiles 224
VI. 1-Alkynyl Acylmetallates 234
VII. Metallation/Transmetallation 236
VIII. 1,2-Elimination with Formation of Alkynyl Carbyne Complexes 238
References 242
Chapter 5. Chalcogen-Bridged Metal–Carbonyl Complexes 252
I. Introduction 252
II. Cationic Clusters 253
III. Anionic Clusters 259
IV. Neutral Clusters 275
References 319
Index 324
Comulative List of Contributors for Volumes 1–36 332
Cumulative Index for Volumes 37–41 336

Produkt-Details

• Erscheint lt. Verlag: 23.7.1997
• Mitarbeit: Herausgeber (Serie): Anthony F. Hill, Robert C. West
• Sprache: englisch
• Themenwelt: Sachbuch/Ratgeber
• Themenwelt: Medizin / Pharmazie ► Gesundheitsfachberufe
• Themenwelt: Medizin / Pharmazie ► Medizinische Fachgebiete ► Pharmakologie / Pharmakotherapie
• Themenwelt: Naturwissenschaften ► Chemie ► Anorganische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Organische Chemie
• Themenwelt: Technik ► Maschinenbau
• ISBN-10: 0-08-058042-4 / 0080580424
• ISBN-13: 978-0-08-058042-5 / 9780080580425