Ligand-Field Parameters
Seiten
1973
Cambridge University Press (Verlag)
978-0-521-20137-7 (ISBN)
Cambridge University Press (Verlag)
978-0-521-20137-7 (ISBN)
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This volume was originally published in 1973. The nature of the non-symmetry determined aspects of ligand-field theory receives inadequate treatment in most texts. This book is concerned with the nature of the ligand-field parameters used to describe the electronic properties of transition metal complexes having cubic and lower symmetries. These radial parameters constitute the non-symmetry-determined part of ligand-field theory. Symmetry-based properties are discussed here only to emphasize the separate roles of splitting factors and symmetry. The reader is assumed to be familiar with the usual approach to ligand-field theory and with elementary group theory.
1. Symmetry versus splitting parameters; 2. The crystal-field formalism; 3. Interelectron repulsion parameters; 4. Radical parameters for angularly-distorted systems; 5. Radical parametres for quadrate symmetry; 6. The nature and calculation of 10Dq; 7. A crystal-field approach to radical parameters; 8. Semi-empirical molecular-orbital approaches; 9. The Nephelauxetic effect.
| Erscheint lt. Verlag | 2.8.1973 |
|---|---|
| Zusatzinfo | Worked examples or Exercises |
| Verlagsort | Cambridge |
| Sprache | englisch |
| Gewicht | 532 g |
| Themenwelt | Naturwissenschaften ► Chemie |
| ISBN-10 | 0-521-20137-3 / 0521201373 |
| ISBN-13 | 978-0-521-20137-7 / 9780521201377 |
| Zustand | Neuware |
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