Ligand-Field Parameters

M. Gerloch, R. C. Slade (Autoren)

Buch | Softcover

248 Seiten

2009
Cambridge University Press (Verlag)
978-0-521-10566-8 (ISBN)

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This volume was originally published in 1973. The nature of the non-symmetry determined aspects of ligand-field theory receives inadequate treatment in most texts. This book is concerned with the nature of the ligand-field parameters used to describe the electronic properties of transition metal complexes having cubic and lower symmetries. These radial parameters constitute the non-symmetry-determined part of ligand-field theory. Symmetry-based properties are discussed here only to emphasize the separate roles of splitting factors and symmetry. The reader is assumed to be familiar with the usual approach to ligand-field theory and with elementary group theory.

1. Symmetry versus splitting parameters; 2. The crystal-field formalism; 3. Interelectron repulsion parameters; 4. Radical parameters for angularly-distorted systems; 5. Radical parametres for quadrate symmetry; 6. The nature and calculation of 10Dq; 7. A crystal-field approach to radical parameters; 8. Semi-empirical molecular-orbital approaches; 9. The Nephelauxetic effect.

Erscheint lt. Verlag	19.3.2009
Zusatzinfo	Worked examples or Exercises
Verlagsort	Cambridge
Sprache	englisch
Maße	152 x 229 mm
Gewicht	370 g
Themenwelt	Naturwissenschaften ► Chemie ► Physikalische Chemie
ISBN-10	0-521-10566-8 / 0521105668
ISBN-13	978-0-521-10566-8 / 9780521105668
Zustand	Neuware