Organic Structure Determination Using 2-D NMR Spectroscopy
Academic Press Inc (Verlag)
978-0-12-384970-0 (ISBN)
Organic Structure Determination Using 2-D NMR Spectroscopy: A Problem-Based Approach, Second Edition, is a primary text for a course in two-dimensional (2-D) nuclear magnetic resonance (NMR) techniques, with the goal to learn to identify organic molecular structure. It presents strategies for assigning resonances to known structures and for deducing structures of unknown organic molecules based on their NMR spectra.
The book begins with a discussion of the NMR technique, while subsequent chapters cover instrumental considerations; data collection, processing, and plotting; chemical shifts; symmetry and topicity; through-bond effects; and through-space effects. The book also covers molecular dynamics; strategies for assigning resonances to atoms within a molecule; strategies for elucidating unknown molecular structures; simple and complex assignment problems; and simple and complex unknown problems. Each chapter includes problems that will enable readers to test their understanding of the material discussed. The book contains 30 known and 30 unknown structure determination problems. It also features a supporting website from which instructors can download the structures of the unknowns in selected chapters, digital versions of all figures, and raw data sets for processing.
This book will stand as a single source to which instructors and students can go to obtain a comprehensive compendium of NMR problems of varying difficulty.
Jeffrey H Simpson, PhD, was Director of the Instrumentation Facility in the Department of Chemistry at M.I.T. from 2006 to 2017. Dr. Simpson’s career in NMR/instrumentation research and instruction spans 20 years, and he has authored an introductory text on the subject of NMR as well as publishing a number of peer-reviewed articles. He is one of the Founding Members of the New England NMR Society and served as VP from its inception to 2017. He currently is a faculty member in the Department of Chemistry at the University of Richmond.
PART I: Background and Methods1. Introduction2. Instrumental Considerations3. Data Collection, Processing, and Plotting4. 1H and 13C Chemical Shifts5. Symmetry and Topicity6. Through-Bond Effects: Spin-Spin (J) Coupling7. Through-Space Effects: the Nuclear Overhauser Effect (NOE)8. Molecular Dynamics9. Strategies for Assigning Molecules10. Strategies for Elucidating Unknown Molecular Structures
PART II: Problems11. Simple Assignment Problems12. Complex Assignment Problems13. Simple Unknown Problems14. Complex Unknown Problems15. NMR Resonance Assignment Problems16. NMR Unknown Problems
| Erscheint lt. Verlag | 15.2.2012 |
|---|---|
| Verlagsort | San Diego |
| Sprache | englisch |
| Maße | 191 x 235 mm |
| Gewicht | 1060 g |
| Themenwelt | Naturwissenschaften ► Chemie ► Analytische Chemie |
| Naturwissenschaften ► Chemie ► Physikalische Chemie | |
| ISBN-10 | 0-12-384970-5 / 0123849705 |
| ISBN-13 | 978-0-12-384970-0 / 9780123849700 |
| Zustand | Neuware |
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