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Principles of Plasma Discharges and Materials Processing -  Allan J. Lichtenberg,  Michael A. Lieberman

Principles of Plasma Discharges and Materials Processing (eBook)

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2024 | 1. Auflage
832 Seiten
Wiley (Verlag)
978-1-394-24539-0 (ISBN)
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A new edition of this industry classic on the principles of plasma processing

Plasma-based technology and materials processes have been central to the revolution of the last half-century in micro- and nano-electronics. From anisotropic plasma etching on microprocessors, memory, and analog chips, to plasma deposition for creating solar panels and flat-panel displays, plasma-based materials processes have reached huge areas of technology. As key technologies scale down in size from the nano- to the atomic level, further developments in plasma materials processing will only become more essential.

Principles of Plasma Discharges and Materials Processing is the foundational introduction to the subject. It offers detailed information and procedures for designing plasma-based equipment and analyzing plasma-based processes, with an emphasis on the abiding fundamentals. Now fully updated to reflect the latest research and data, it promises to continue as an indispensable resource for graduate students and industry professionals in a myriad of technological fields.

Readers of the third edition of Principles of Plasma Discharges and Materials Processing will also find:

  • Extensive figures and tables to facilitate understanding
  • A new chapter covering the recent development of processes involving high-pressure capacitive discharges
  • New subsections on discharge and processing chemistry, physics, and diagnostics

Principles of Plasma Discharges and Materials Processing is ideal for professionals and process engineers in the field of plasma-assisted materials processing with experience in the field of science or engineering. It is the premiere world-wide basic text for graduate courses in the field.

Michael A. Lieberman, PhD, is Professor of the Graduate School, Department of Electrical Engineering and Computer Sciences, University of California, Berkeley.

Allan J. Lichtenberg, PhD, was Emeritus Professor of the Department of Electrical Engineering and Computer Sciences, University of California, Berkeley.


A new edition of this industry classic on the principles of plasma processing Plasma-based technology and materials processes have been central to the revolution of the last half-century in micro- and nano-electronics. From anisotropic plasma etching on microprocessors, memory, and analog chips, to plasma deposition for creating solar panels and flat-panel displays, plasma-based materials processes have reached huge areas of technology. As key technologies scale down in size from the nano- to the atomic level, further developments in plasma materials processing will only become more essential. Principles of Plasma Discharges and Materials Processing is the foundational introduction to the subject. It offers detailed information and procedures for designing plasma-based equipment and analyzing plasma-based processes, with an emphasis on the abiding fundamentals. Now fully updated to reflect the latest research and data, it promises to continue as an indispensable resource for graduate students and industry professionals in a myriad of technological fields. Readers of the third edition of Principles of Plasma Discharges and Materials Processing will also find: Extensive figures and tables to facilitate understanding A new chapter covering the recent development of processes involving high-pressure capacitive discharges New subsections on discharge and processing chemistry, physics, and diagnostics Principles of Plasma Discharges and Materials Processing is ideal for professionals and process engineers in the field of plasma-assisted materials processing with experience in the field of science or engineering. It is the premiere world-wide basic text for graduate courses in the field.

List of Figures


  1. Figure 1.1 High aspect ratio anisotropic etches, showing the extraordinary capabilities of plasma processing; such etched features are used for device isolation, charge storage capacitors, channel holes, and many other purposes in integrated circuits: trench etch (0.2 m wide by 4 m deep) in single-crystal silicon, circa 2004; set of channel holes (each approximately 0.1 m in diameter by 7.5 m deep) etched into a stacked set of dielectric layers, circa 2023. Source: (a) M. A. Lieberman (Book Author). (b) Courtesy of Lam Research Corporation
  2. Figure 1.2 Deposition and pattern transfer in manufacturing an integrated circuit: metal deposition; photoresist deposition; optical exposure through a pattern; photoresist development; anisotropic plasma etch; remaining photoresist removal
  3. Figure 1.3 Plasma etching in integrated circuit manufacture: example of isotropic etch; sidewall etching of the resist mask leads to a loss of anisotropy in film etch; illustrating the role of bombarding ions in anisotropic etch; illustrating the role of sidewall passivating films in anisotropic etch
  4. Figure 1.4 Experimental demonstration of ion-enhanced plasma etching. Source: Adapted from Coburn and Winters (1979)
  5. Figure 1.5 Illustrating ion implantation of an irregular object: in a conventional ion beam implanter, the beam is electrically scanned and the target object is mechanically rotated and tilted to achieve uniform implantation; in plasma-immersion ion implantation (PIII), the target is immersed in a plasma, and ions from the plasma are implanted with a relatively uniform spatial distribution
  6. Figure 1.6 Schematic view of a plasma and a discharge
  7. Figure 1.7 Energy coupling between electrons and heavy particles in a low-pressure plasma
  8. Figure 1.8 Space and laboratory plasmas on a versus diagram (Source: Book (1987)/Naval Research Laboratory); the electron Debye length is defined in Section 2.4
  9. Figure 1.9 Densities and energies for various species in a low-pressure capacitive rf discharge
  10. Figure 1.10 Electron energy distribution function in a weakly ionized discharge
  11. Figure 1.11 The formation of plasma sheaths: initial ion and electron densities and potential; densities, electric field, and potential after the formation of the sheath
  12. Figure 1.12 PIC simulation of positive ion sheath formation: – electron phase space, with horizontal scale in meters; electron density ; electric field ; potential ; electron number versus time in seconds; right hand potential versus time
  13. Figure 1.13 Typical multi-wafer capacitive rf discharge in plane-parallel geometry, used for anisotropic etching. Source: Lieberman and Gottscho (1994)/with permission of Elsevier
  14. Figure 1.14 The physical model of an rf diode. Source: Lieberman and Gottscho (1994)/with permission of Elsevier
  15. Figure 1.15 Some modern capacitive discharges are used for etching and deposition; single frequency, dual frequency, and magnetically enhanced
  16. Figure 1.16 Some non-capacitive, high-density discharges used for etching and deposition; planar inductive; electron cyclotron resonance; helicon
  17. Figure 1.17 A dc planar magnetron discharge, used for thin film deposition
  18. Figure 1.18 The central problem of discharge analysis
  19. Figure 2.1 Kirchhoff’s circuit laws: the total current flowing across a nonuniform one-dimensional discharge is independent of ; the sum of the currents entering a node is zero ( ); the sum of voltages around a loop is zero ()
  20. Figure 2.2 PIC simulation of ion loss in a plasma containing ions only: () – ion phase space, showing the ion acceleration trajectories; () number of ion sheets versus , with the steps indicating the loss of a single sheet; () the potential versus during the first 10 s of ion loss
  21. Figure 2.3 One-dimensional – phase space, illustrating the derivation of the Boltzmann equation and the change in due to collisions
  22. Figure 2.4 The force density due to the pressure gradient
  23. Figure 2.5 Calculation of the electron Debye length . A negatively charged sheet is introduced into a plasma containing electrons in thermal equilibrium
  24. Figure 3.1 A flux of incident particles collides with a population of target particles in the half-space
  25. Figure 3.2 Hard-sphere scattering
  26. Figure 3.3 Definition of the differential scattering cross section
  27. Figure 3.4 The relation between the scattering angles in () the laboratory system and () the center of mass (CM) system
  28. Figure 3.5 Calculation of the differential scattering cross section for small-angle scattering. The center of mass trajectory is practically a straight line
  29. Figure 3.6 The processes that lead to large-angle Coulomb scattering: () single large-angle event; () cumulative effect of many small-angle events
  30. Figure 3.7 Polarization of an atom by a point charge
  31. Figure 3.8 Scattering in the polarization potential, showing () hyperbolic and () captured orbits
  32. Figure 3.9 Probability of collision for electrons in and He; the cross section is cm (Brown, 1959/MIT Press)
  33. Figure 3.10 Probability of collision for electrons in Ne, Ar, Kr, and Xe, showing the Ramsauer minima for Ar, Kr, and Xe; the cross section is cm (after Brown, 1959)
  34. Figure 3.11 Atomic energy levels for the central field model of an atom, showing the dependence of the energy levels on the quantum numbers and ; the energy levels are shown for sodium, without the fine structure (Thorne, 1988/Springer Nature)
  35. Figure 3.12 The energy levels of the argon atom, showing () the () configurations and () details of the and configurations, with the two metastable levels shown as heavy solid lines (Edgell, 1961/Interscience Publishers)
  36. Figure 3.13 Ionization, excitation, and elastic scattering cross sections for electrons in argon gas (Vahedi, 1993)
  37. Figure 3.14 Illustrating the calculation of ion–atom charge transfer
  38. Figure 3.15 Experimental values for elastic scattering (), charge transfer (), and the sum of the two mechanisms () for (a) helium, (b) neon, and (c) argon ions in their parent gases (McDaniel et al., 1993/John Wiley & Sons)
  39. Figure 3.16 Electron collision rate constants , , and versus in argon gas (Vahedi, 1993)
  40. Figure 3.17 Collisional energy loss per electron–ion pair created versus in argon and oxygen. Source: Adapted from Gudmundsson, 2002b.
  41. Figure 4.1 Charged particle gyration in a uniform magnetic field; is directed out of the page
  42. Figure 4.2 Motion of electrons and ions in uniform crossed and fields
  43. Figure 4.3 Plasma oscillations in a slab geometry: () displacement of electron cloud with respect to ion cloud; () calculation of the resulting electric field
  44. Figure 4.4 Rf current and electric field amplitudes and phases in the sheath and plasma regions of an rf discharge
  45. Figure 4.5 Dispersion versus for electromagnetic and electrostatic electron plasma waves in an unmagnetized plasma
  46. Figure 4.6 Calculation of the parallel force due to a magnetic field gradient
  47. Figure 4.7 Calculation of the curvature drift due to a magnetic field gradient
  48. Figure 4.8 Calculation of the perpendicular gradient drift due to a magnetic field gradient : () the magnetic field lines; () the motion viewed in the – plane
  49. Figure 4.9 Dispersion versus for the principal waves in a magnetized plasma with immobile ions for
  50. Figure 4.10 Dispersion versus for the principal waves in a magnetized plasma with mobile ions
  51. Figure 4.11 The CMA diagram for waves in a magnetized plasma. The cutoffs and resonances are indicated by the lines labeled and , respectively, where denotes the phase velocity and the subscripts label the principal waves. Source: Allis et al., 1963/MIT Press
  52. Figure 4.12 A microwave interferometer for plasma density measurement
  53. Figure 4.13 Mean electron density versus incident power at the midplane of an rf inductive discharge as measured by a microwave interferometer, compared with ion density as measured by a Langmuir probe. Source: Hopwood et al., 1993b/American Vacuum Society
  54. Figure 4.14 Design of () dc or grounded and () floating hairpin resonator probes. Source: Piejak et al. (2005). © IOP Publishing. Reproduced with permission. All rights reserved. https://doi.org/10.1088/0963-0252/14/4/012
  55. Figure 4.15 Electron density versus absorbed power in a 10 mTorr argon discharge. Data from 443 MHz cavity resonance (circles), 506 MHz cavity resonance (squares), and Langmuir probe (triangles). Source: Moroney et al., 1989/with permission of AIP Publishing
  56. Figure 5.1...

Erscheint lt. Verlag 28.8.2024
Sprache englisch
Themenwelt Technik Elektrotechnik / Energietechnik
ISBN-10 1-394-24539-4 / 1394245394
ISBN-13 978-1-394-24539-0 / 9781394245390
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