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Nano-Engineered Cementitious Composites - Baoguo Han, Siqi Ding, Jialiang Wang, Jinping Ou

Nano-Engineered Cementitious Composites (eBook)

Principles and Practices
eBook Download: PDF
2019 | 1st ed. 2019
XXIV, 731 Seiten
Springer Singapore (Verlag)
978-981-13-7078-6 (ISBN)
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This book focuses on civil engineering materials and nanotechnology. Highlighting recent advances in the field of nano-engineered cementitious composites, it discusses their key principles, design and fabrication, testing and characterization, performance and mechanisms, as well as applications. Future developments and remaining challenges are also outlined. 

Nano-engineered cementitious composites are exceptionally strong, durable and offer multifunctional/smart performance that differs considerably from that of normal cementitious composites. Providing valuable insights into these composites' future development, the book offers an essential source of information, inspiration, theory and practical guidance for developing sustainable cementitious composites. As such, it will benefit researchers, scientists and engineers in the fields of civil engineering materials and nanotechnology alike.   





Baoguo Han received his PhD degree in the field of smart materials and structures from the Harbin Institute of Technology, China, in 2005. He is currently working as a professor of civil engineering at Dalian University of Technology, China. His main research interests include cement and concrete materials, nanotechnology, smart materials and structures, structural health monitoring, and traffic detection. He is a member of the editorial board of three international journals, and has published two books, ten book chapters and more than 100 technical papers. He previously spent three years as a visiting research scholar at the University of Minnesota. He also was awarded the New Century Excellent Talents in University prize by the Ministry of Education of China and the first prize in Natural Science by the Ministry of Education of China as the 3rd participant.

Siqi Ding received his M.S. degree in material science from the Dalian University of Technology, China, in 2015. He is currently pursuing his Ph.D. degree at The Hong Kong Polytechnic University, majored in structural engineering. His main research interests include cement and concrete materials, nanotechnology, smart materials and structures and structural health monitoring. He has published 5 book chapters and 14 published journal papers.

Jialiang Wang received his M.S. degree in material engineering from the Lanzhou University of Technology, China, in 2015. He is currently pursuing his Ph.D. degree at Dalian University of Technology, China. His current research interests include cement and concrete composites, smart materials and structures, and nanotechnology. He has published 1 book chapters and 5 published journal papers.

Jinping Ou received his Ph.D. degree from the Harbin Institute of Technology, China, in 1987. He is a professor at both Harbin Institute of Technology and Dalian University of Technology, China. His main research interests include structural damage, reliability and health monitoring, structural vibration and control, smart materials and structures. He has published more than 300 technical papers/reports and 6 books. He has been awarded the second-level National Awards of Science and Technology Progress twice and the first-level provincial and ministerial Awards of Science and Technology Progress five times. He has been an academician of Chinese Academy of Engineering since 2003, and was the president of the Chinese Society for Vibration Engineering, the vice-president of the Architectural Society of China, an executive board member at the International Association for Structural Control and Monitoring, as well as the vice-president and fellow of the International Society for Structural Health Monitoring of Intelligent Infrastructure.



This book focuses on civil engineering materials and nanotechnology. Highlighting recent advances in the field of nano-engineered cementitious composites, it discusses their key principles, design and fabrication, testing and characterization, performance and mechanisms, as well as applications. Future developments and remaining challenges are also outlined. Nano-engineered cementitious composites are exceptionally strong, durable and offer multifunctional/smart performance that differs considerably from that of normal cementitious composites. Providing valuable insights into these composites' future development, the book offers an essential source of information, inspiration, theory and practical guidance for developing sustainable cementitious composites. As such, it will benefit researchers, scientists and engineers in the fields of civil engineering materials and nanotechnology alike.   

Preface 6
Acknowledgements 10
Contents 11
About the Authors 19
Abbreviations 21
1 Basic Principles of Nano-Engineered Cementitious Composites 23
Abstract 23
1.1 Introduction 23
1.2 Fundamental of Cementitious Composites 25
1.2.1 General Introduction of Compositions of Cementitious Composites 25
1.2.2 General Introduction of Structures of Cementitious Composites 70
1.2.3 Hierarchy of Science and Technology of Cementitious Composites 96
1.3 Fundamental of Nano-Engineered Cementitious Composites 98
1.3.1 Significance of Nanoscience and Nanotechnology of Cementitious Composites 98
1.3.2 Thermodynamic and Kinetic Principles of Nano-Engineered Cementitious Composites 98
1.3.3 Nano-core Effect in Nano-Engineered Cementitious Composites 101
1.4 Summary 115
References 116
2 Current Progress of Nano-Engineered Cementitious Composites 119
Abstract 119
2.1 Introduction 119
2.2 General Overview of Current Progress of Nano-Engineered Cementitious Composites 121
2.2.1 Nano-Engineered Composition Materials of Cementitious Composites 121
2.2.2 Fabrication/Processing of Nano-Engineered Cementitious Composites 123
2.3 Current Progress of Specific Type of Nano-Engineered Cementitious Composites 126
2.3.1 Current Progress of Nano-Cement-Engineered Cementitious Composites 126
2.3.2 Current Progress of Nano-Silica Fume-Engineered Cementitious Composites 129
2.3.3 Current Progress of Nano-Fly Ash-Engineered Cementitious Composites 131
2.3.4 Current Progress of Nano-Carbon Black-Engineered Cementitious Composites 138
2.3.5 Current Progress of Carbon Nanotube-Engineered Cementitious Composites 146
2.3.6 Current Progress of Carbon Nanofiber-Engineered Cementitious Composites 162
2.3.7 Current Progress of Graphene-Engineered Cementitious Composites 169
2.3.8 Current Progress of Nano-SiO2-Engineered Cementitious Composites 181
2.3.9 Current Progress of Nano-TiO2-Engineered Cementitious Composites 203
2.3.10 Current Progress of Nano-ZrO2-Engineered Cementitious Composites 225
2.3.11 Current Progress of Nano-Al2O3-Engineered Cementitious Composites 236
2.3.12 Current Progress of Nano-MgO-Engineered Cementitious Composites 260
2.3.13 Current Progress of Nano-ZnO-Engineered Cementitious Composites 265
2.3.14 Current Progress of Nano-ZnO2-Engineered Cementitious Composites 275
2.3.15 Current Progress of Nano-CuO-Engineered Cementitious Composites 283
2.3.16 Current Progress of Nano-Fe2O3-Engineered Cementitious Composites 293
2.3.17 Current Progress of Nano-Fe3O4-Engineered Cementitious Composites 298
2.3.18 Current Progress of Nano-Cr2O3-Engineered Cementitious Composites 304
2.3.19 Current Progress of Nano-SiC-Engineered Cementitious Composites 309
2.3.20 Current Progress of Nano-Ti3C2-Engineered Cementitious Composites 310
2.3.21 Current Progress of Nano-BN-Engineered Cementitious Composites 312
2.3.22 Current Progress of Nano-CaCO3-Engineered Cementitious Composites 315
2.3.23 Current Progress of Nano-BaSO4-Engineered Cementitious Composites 326
2.3.24 Current Progress of Al2SiO5 Nanotube-Engineered Cementitious Composites 332
2.3.25 Current Progress of Nano-Ferrite-Engineered Cementitious Composites 336
2.3.26 Current Progress of Nano C–S–H Seed-Engineered Cementitious Composites 340
2.3.27 Current Progress of Nano-Clay-Engineered Cementitious Composites 348
2.3.28 Current Progress of Nano-Perovskite-Engineered Cementitious Composites 365
2.3.29 Current Progress of Nanocellulose-Engineered Cementitious Composites 367
2.3.30 Current Progress of Nano-Carbonized Bagasse Fiber-Engineered Cementitious Composites 382
2.3.31 Current Progress of Hybrid Nanomaterial-Engineered Cementitious Composites 384
2.3.32 Current Progress of In-Situ Growing Carbon Nanotubes/Carbon Nanofiber-Engineered Cementitious Composites 385
2.3.33 Current Progress of Carbon Nanotube-Latex Thin Film Coating Aggregate-Engineered Cementitious Composites 393
2.4 Summary 397
References 397
3 Carbon Nanotubes-Engineered Cementitious Composites 421
Abstract 421
3.1 Introduction 421
3.2 Rheology of Carbon Nanotubes-Engineered Cementitious Composites 422
3.2.1 Preparation of Fresh Cement Pastes with Carbon Nanotubes 422
3.2.2 Effect of Carbon Nanotube Dosage on Rheology 423
3.2.3 Effect of Water to Cement Ratio on Rheology 424
3.2.4 Effect of Superplasticizer Dosage on Rheology 425
3.3 Mechanical Properties/Performances of Carbon Nanotubes-Engineered Cementitious Composites 426
3.3.1 Fabrication of Cement Pastes with Carbon Nanotubes 426
3.3.2 Effect of Size of Untreated Carbon Nanotubes on Mechanical Properties/Performances 428
3.3.3 Effect of Surface Functionalization of Carbon Nanotubes on Mechanical Properties/Performances 435
3.3.4 Effect of Special Structure and Surface Modification of Carbon Nanotubes on Mechanical Properties/Performances 444
3.4 Transport Properties of Carbon Nanotubes-Engineered Cementitious Composites 451
3.4.1 Fabrication of Cement Mortars with Carbon Nanotubes 451
3.4.2 Water Sorptivity 451
3.4.3 Water Permeability 451
3.4.4 Gas Permeability 454
3.5 Electrical Properties/Performances of Carbon Nanotubes-Engineered Cementitious Composites 456
3.5.1 Effect of Carbon Nanotube Size on Electrical Properties/Performances 456
3.5.2 Effect of Surface Functionalization of Carbon Nanotubes on Electrical Properties/Performances 461
3.5.3 Effect of Surface Modification and Special Structure of Carbon Nanotubes on Electrical Properties/Performances 465
3.6 Self-sensing Properties/Performances of Carbon Nanotubes-Engineered Cementitious Composites 469
3.6.1 Self-sensing Properties/Performances of Cement Pastes with Carbon Nanotubes 469
3.6.2 Self-sensing Properties/Performances of Cement Mortars with Carbon Nanotubes 471
3.6.3 Mechanisms of Self-sensing Properties/Performances 472
3.7 Case Study of Applications of Carbon Nanotubes-Engineered Cementitious Composites 474
3.8 Summary 476
References 478
4 Graphene-Engineered Cementitious Composites 481
Abstract 481
4.1 Introduction 481
4.2 Preparation of Graphene-Engineered Cementitious Composites 482
4.3 Rheology of Graphene-Engineered Cementitious Composites 483
4.4 Mechanical Properties/Performances of Graphene-Engineered Cementitious Composites 486
4.4.1 Compressive Properties/Performances 486
4.4.2 Flexural Properties/Performances 490
4.4.3 Nano-Hardness 490
4.4.4 Reinforcement Mechanisms 492
4.5 Durability of Graphene-Engineered Cementitious Composites 500
4.5.1 Wear Resistance 500
4.5.2 Chloride Penetration Resistance 503
4.6 Functional/Smart Properties/Performances of Graphene-Engineered Cementitious Composites 504
4.6.1 Damping Properties/Performances 504
4.6.2 Electrically Conductive Properties/Performances 506
4.6.3 Thermal Properties/Performances 515
4.6.4 Electromagnetic Properties/Performances 517
4.6.5 Smart Properties/Performances of Graphene-Engineered Cementitious Composites 528
4.7 Summary 537
References 538
5 Nano-SiO2-Engineered Cementitious Composites 541
Abstract 541
5.1 Introduction 541
5.2 Rheology of Nano-SiO2-Engineered Cementitious Composites 542
5.2.1 Preparation of Fresh Cement Paste with Nano-SiO2 542
5.2.2 Effect of Nano-SiO2 Dosage on Rheology 542
5.2.3 Effect of Water-to-Cement Ratio on Rheology 544
5.2.4 Effect of Superplasticizer Dosage on Rheology 546
5.2.5 Effect of Ultrasonic Time on Rheology 547
5.2.6 Effect of Mixing Rate on Rheology 548
5.3 Mechanical Properties/Performances of Nano- SiO2-Engineered Cementitious Composites 549
5.3.1 Fabrication of Cement Mortars/Powder Reactive Concrete with Nano-SiO2 549
5.3.2 Compressive and Flexural Properties/Performances of Cement Mortars with Nano-SiO2 and Reinforcement Mechanisms 549
5.3.3 Impact Properties/Performances of Reactive Powder Concrete with Nano-SiO2 and Reinforcement Mechanisms 564
5.4 Durability of Nano-SiO2-Engineered Cementitious Composites 573
5.4.1 Wear Resistance 573
5.4.2 Chloride Penetration Resistance 574
5.4.3 Modification Mechanisms 575
5.5 Summary 579
References 581
6 Nano-TiO2-Engineered Cementitious Composites 583
Abstract 583
6.1 Introduction 583
6.2 Rheological Properties/Performances of Nano- TiO2-Engineered Cementitious Composites 584
6.3 Mechanical Properties/Performances of Nano- TiO2-Engineered Cementitious Composites 587
6.3.1 Preparation of Nano-TiO2-Engineered Cementitious Composites 587
6.3.2 Mechanical Properties/Performances of Anatase Phase Nano-TiO2-Engineered Cementitious Composites 587
6.3.3 Mechanical Properties/Performances of Rutile Phase Nano-TiO2-Engineered Cementitious Composites 599
6.3.4 Mechanical Properties/Performances of Nano-SiO2@TiO2-Engineered Cementitious Composites 603
6.4 Durability of Nano-TiO2-Engineered Cementitious Composites 616
6.4.1 Wear Resistance 616
6.4.2 Chloride Penetration Resistance 616
6.5 Electrical Properties of Nano-TiO2-Engineered Cementitious Composites 617
6.6 Summary 618
References 620
7 Nano-ZrO2-Engineered Cementitious Composites 622
Abstract 622
7.1 Introduction 622
7.2 Preparation of Nano-ZrO2-Engineered Cementitious Composites 623
7.3 Mechanical Properties/Performances of Nano-ZrO2-Engineered Cementitious Composites with Standard Curing 624
7.3.1 Flexural Strength 624
7.3.2 Compressive Strength 626
7.3.3 Splitting Strength 628
7.3.4 Impact Properties/Performances 629
7.3.5 Reinforcement Mechanisms 634
7.4 Mechanical Properties/Performances of Nano-ZrO2-Engineered Cementitious Composites Under Heat Curing 639
7.4.1 Comparison of Strength of Nano-ZrO2-Engineered Cementitious Composites with Different Curing Methods 639
7.4.2 Stress–Strain Relationship Under Uniaxial Compression 643
7.4.3 Load–Deflection Relationship Under Four-Point Bending 646
7.4.4 Fracture Properties/Performances Under Three-Point Bending 647
7.4.5 Fracture Properties/Performances Under Four-Point Shear 650
7.5 Electrical Properties/Performances of Nano-ZrO2-Engineered Cementitious Composites 653
7.6 Durability of Nano-ZrO2-Engineered Cementitious Composites 654
7.6.1 Wear Resistance 654
7.6.2 Chloride Penetration Resistance 655
7.7 Summary 656
References 657
8 Nano-BN-Engineered Cementitious Composites 659
Abstract 659
8.1 Introduction 659
8.2 Preparation of Nano-BN-Engineered Cementitious Composites 660
8.3 Mechanical Properties/Performances of Nano-BN-Engineered Cementitious Composites 662
8.3.1 Effect of Nano-BN Particle Size on Mechanical Properties/Performances 662
8.3.2 Effect of Nano-BN Content on Mechanical Properties/Performances 665
8.3.3 Effect of Curing Method on Mechanical Properties/Performances 667
8.3.4 Reinforcement Mechanisms of Nano-BN to Cementitious Composites Under Standard Curing 669
8.3.5 Reinforcement Mechanisms of Nano-BN to Cementitious Composites Under Heat Curing 678
8.4 Durability of Nano-BN-Engineered Cementitious Composites 679
8.4.1 Abrasion Resistance and Modification Mechanisms 679
8.4.2 Chloride Penetration Resistance and Modification Mechanisms 681
8.5 Summary 682
References 683
9 Electrostatic Self-Assembled Carbon Nanotube/Nano-Carbon Black Fillers-Engineered Cementitious Composites 685
Abstract 685
9.1 Introduction 685
9.2 Preparation of Electrostatic Self-Assembled Carbon Nanotube/Nano-Carbon Black Fillers-Engineered Cementitious Composites/Sensors 686
9.3 Properties/Performances of Electrostatic Self-Assembled Carbon Nanotube/Nano-Carbon Black Fillers-Engineered Cementitious Composites 689
9.3.1 Mechanical Properties/Performances 689
9.3.2 Electrically Conductive Properties/Performances 693
9.3.3 Self-sensing Properties/Performances 695
9.4 Case Study of Applications of Electrostatic Self-Assembled Carbon Nanotube/Nano-Carbon Black Fillers-Engineered Cementitious Composites 715
9.4.1 Sensors Fabricated with Electrostatic Self-assembled Carbon Nanotube/Nano-Carbon Black Fillers-Engineered Cementitious Composites 715
9.4.2 Smart Concrete Columns Embedded with Sensors 718
9.5 Summary 725
References 726
10 Future Developments and Challenges of Nano-Engineered Cementitious Composites 728
Abstract 728
10.1 Introduction 728
10.2 Design of Nano-Engineered Cementitious Composites 731
10.3 Fabrication/Processing of Nano-Engineered Cementitious Composites 732
10.4 Test/Characterization and Simulation of Nano-Engineered Cementitious Composites 734
10.5 Properties/Performances of Nano-Engineered Cementitious Composites 736
10.6 Mechanisms and Models of Nano-Engineered Cementitious Composites 742
10.7 Applications of Nano-Engineered Cementitious Composites 743
10.8 Potential Risks About Nano-Engineered Cementitious Composites 746
10.9 Summary 747
References 748

Erscheint lt. Verlag 10.4.2019
Zusatzinfo XXIV, 731 p. 333 illus., 248 illus. in color.
Sprache englisch
Themenwelt Technik Bauwesen
Technik Maschinenbau
Schlagworte Applications of nano-engineered concrete • bendable concrete • Cementitious composites • Cementitious composites test and characterization • Design of ECC • Fabrication of nano-engineered cement • High-performance cement composites • Nano-concrete • Nano-engineered Cementitious Composites performances • Nanoengineered ECC • Nanoindentation • Nano modification • Nanoscale phenomenon • Optimization of ultra-high-performance concrete
ISBN-10 981-13-7078-8 / 9811370788
ISBN-13 978-981-13-7078-6 / 9789811370786
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