Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene
Seiten
2017
|
1st ed. 2017
Springer Verlag, Singapore
978-981-10-0772-9 (ISBN)
Springer Verlag, Singapore
978-981-10-0772-9 (ISBN)
This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd–Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.<
Introduction.- Experimental and Theoretical Methods.- Design of Pd-Ni Bimetallic Catalyst.- Effect of Oxide Supports on Pd–Ni Bimetallic Catalysts.- Replacing Precious Metals with Carbide Catalysts.- Liquid Phase Hydrogenation of Acetylene.- Conclusion.
| Erscheinungsdatum | 25.01.2017 |
|---|---|
| Reihe/Serie | Springer Theses | Springer Theses |
| Zusatzinfo | 42 Illustrations, color; 41 Illustrations, black and white; XII, 141 p. 83 illus., 42 illus. in color. |
| Verlagsort | Singapore |
| Sprache | englisch |
| Maße | 155 x 235 mm |
| Themenwelt | Naturwissenschaften ► Chemie ► Organische Chemie |
| Naturwissenschaften ► Chemie ► Physikalische Chemie | |
| Technik | |
| ISBN-10 | 981-10-0772-1 / 9811007721 |
| ISBN-13 | 978-981-10-0772-9 / 9789811007729 |
| Zustand | Neuware |
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