Thermodynamics of Solutions
From Gases to Pharmaceutics to Proteins
Seiten
2014
|
2009 ed.
Springer-Verlag New York Inc.
978-1-4899-8301-5 (ISBN)
Springer-Verlag New York Inc.
978-1-4899-8301-5 (ISBN)
This book consists of a number of papers regarding the thermodynamics and structure of multicomponent systems that we have published during the last decade. , hyd- gen bonding) between components or systems with large differences in the partial molar v- umes of the components (e.
This book consists of a number of papers regarding the thermodynamics and structure of multicomponent systems that we have published during the last decade. Even though they involve different topics and different systems, they have something in common which can be considered as the “signature” of the present book. First, these papers are concerned with “difficult” or very nonideal systems, i. e. systems with very strong interactions (e. g. , hyd- gen bonding) between components or systems with large differences in the partial molar v- umes of the components (e. g. , the aqueous solutions of proteins), or systems that are far from “normal” conditions (e. g. , critical or near-critical mixtures). Second, the conventional th- modynamic methods are not sufficient for the accurate treatment of these mixtures. Last but not least, these systems are of interest for the pharmaceutical, biomedical, and related ind- tries. In order to meet the thermodynamic challenges involved in these complex mixtures, we employed a variety of traditional methods but also new methods, such as the fluctuation t- ory of Kirkwood and Buff and ab initio quantum mechanical techniques. The Kirkwood-Buff (KB) theory is a rigorous formalism which is free of any of the - proximations usually used in the thermodynamic treatment of multicomponent systems. This theory appears to be very fruitful when applied to the above mentioned “difficult” systems.
This book consists of a number of papers regarding the thermodynamics and structure of multicomponent systems that we have published during the last decade. Even though they involve different topics and different systems, they have something in common which can be considered as the “signature” of the present book. First, these papers are concerned with “difficult” or very nonideal systems, i. e. systems with very strong interactions (e. g. , hyd- gen bonding) between components or systems with large differences in the partial molar v- umes of the components (e. g. , the aqueous solutions of proteins), or systems that are far from “normal” conditions (e. g. , critical or near-critical mixtures). Second, the conventional th- modynamic methods are not sufficient for the accurate treatment of these mixtures. Last but not least, these systems are of interest for the pharmaceutical, biomedical, and related ind- tries. In order to meet the thermodynamic challenges involved in these complex mixtures, we employed a variety of traditional methods but also new methods, such as the fluctuation t- ory of Kirkwood and Buff and ab initio quantum mechanical techniques. The Kirkwood-Buff (KB) theory is a rigorous formalism which is free of any of the - proximations usually used in the thermodynamic treatment of multicomponent systems. This theory appears to be very fruitful when applied to the above mentioned “difficult” systems.
Eli Ruckenstein has won many notable awards, including the Foundes Award from the American Institue of Chemical Engineers, the National Academy of Engineering Founders Award, and the National Medal of Science. His interests include transport phenomena, catalysis, colloids and interfces, phase transformations, thermodynamics, and materials.
The Kirkwood–Buff integrals and their applications to binary and ternary solutions.- Supercritical mixtures.- Solubility of gases in mixed solvents.- Solubility of pharmaceuticals and environmentally important compounds.- Aqueous solutions of biomolecules.- Water and dilute aqueous solutions.
Erscheint lt. Verlag | 26.11.2014 |
---|---|
Zusatzinfo | VII, 346 p. |
Verlagsort | New York |
Sprache | englisch |
Maße | 210 x 279 mm |
Themenwelt | Naturwissenschaften ► Chemie ► Physikalische Chemie |
Naturwissenschaften ► Chemie ► Technische Chemie | |
Naturwissenschaften ► Physik / Astronomie ► Thermodynamik | |
Technik | |
ISBN-10 | 1-4899-8301-5 / 1489983015 |
ISBN-13 | 978-1-4899-8301-5 / 9781489983015 |
Zustand | Neuware |
Haben Sie eine Frage zum Produkt? |
Mehr entdecken
aus dem Bereich
aus dem Bereich
Quantenmechanik | Spektroskopie | Statistische Thermodynamik
Buch | Softcover (2024)
De Gruyter (Verlag)
CHF 83,90
Set aus Lehrbuch und Arbeitsbuch
Buch | Hardcover (2022)
Wiley-VCH (Verlag)
CHF 149,95
Thermodynamik | Kinetik | Elektrochemie
Buch | Softcover (2024)
De Gruyter (Verlag)
CHF 83,90