Organo Main Group Chemistry (eBook)

Kin-ya Akiba (Autor)

eBook Download: PDF

2011 | 1. Auflage
288 Seiten
John Wiley & Sons (Verlag)
978-1-118-02587-1 (ISBN)

Infos

Forging a new association; main group elements and organic
chemistry

Covering the essentials of all main group elements in organic
chemistry, along with the synthesis and reactions of their organic
compounds in just one volume, Organo Main Group Chemistry breaks
important new ground. While main group chemistry has traditionally
been classified as part of inorganic chemistry, this book
establishes the organic chemistry of main group elements for the
first time.

The organic compounds of elements in the second period of the
periodic table, which are centered around carbon, are the major
components of animals and plants, while those in the third period
and below also play key roles worthy of discussion when studying
main group element chemistry.

The major chapters describe synthesis and reactivity of organic
compounds in the third period and below and are arranged according
to the order of the periodic table. Starting with the role of
lithium and magnesium cations, the chapters reach fluorine and
iodine compounds. The first two chapters summarize the unique and
common characteristics of main group elements in relation to
carbon. The latter chapters deal with modern topics that address
the unique characteristics of organo main group compounds.

Suitable for professional researchers, chemistry professors, and
advanced students, Organo Main Group Chemistry presents a novel new
approach to the way we view both main groups and organic chemistry
itself.

Autor

KIN-YA AKIBA, PHD, is a Professor Emeritus in the Department of Chemistry at Hiroshima University and a visiting researcher at the Advanced Research Institute for Science and Engineering at Waseda University. Among his many honors are the 1996 Humboldt Research Award, the 1997 Award by the Chemical Society of Japan, and the 2000 Medal with Purple Ribbon by the Prime Minister of Japan.

Inhalt

Chapter 1 Main Group Elements and Heteroatoms: Scope and Characteristics.

1.1 Aufbau Principle and Sign of Orbitals.

1.2 Electronic Configuration of an Atom: Main Group Elements and Heteroatoms.

1.3 Fundamental Property of Main Group Elements.

1.4 Acidity of Carboxylic Acid and Substituent Effect.

1.5 Heteroatom Effect.

Chapter 2 Main Group Element Effect.

2.1 What is Main Group Effect?

2.2 Single Bond Energy and pi-bond Energy.

2.3 Hypervalent Compound.

2.4 Effect of Hypervalent Bond (1): 3c-4e Bond and Structure.

2.5 Effect of Hypervalent Bond (2): Apicophilicity and Pseudorotation.

2.6 Effect of Hypervalent Bond: Ligand Coupling Reaction (LCR) and Edge Inversion.

2.7 Effect of sigmax c.

2.8 Effect of sigma*x c.

Chapter 3 Lithium, Magnesium, and Copper Compounds.

3.1 Synthesis.

3.2 Structure.

3.3 Reaction.

Chapter 4 Boron and Aluminum Compounds.

4.1 Synthesis.

4.2 Structure.

4.3 Reaction.

Chapter 5 Silicon, Tin, and Lead Compounds.

5.1 Synthesis.

5.2 Reaction.

5.3 Organotin and Lead Compounds.

Chapter 6 Phosphorus, Antimony, and Bismuth Compounds.

6.1 Phosphorus Compounds.

6.2 Synthesis of Organophosphorus Compounds.

6.3 Tertiary Phosphine and Its Nucleophilic Reaction.

6.4 Arbuzov Reaction.

6.5 Perkow Reaction.

6.6 Synthesis of Optically Active Phosphine.

6.7 Ylide and Wittig Reaction and Related Ones.

6.8 Reaction of Phosphonium Salt and Formation of Phosphorane.

6.9 Freezing BPR and Its Effect.

Chapter 7 Sulfur, Selenium, and Tellurium Compounds.

7.1 Sulfur Compound.

7.2 Synthesis of Organosulfur Compound.

7.3 Reaction of Organosulfur Compound.

7.4 Structure and Reaction of Hypervalent Organosulfur Compound.

7.5 Selenium and Tellurium Compounds.

Chapter 8 Organohalogen Compound: Fluorine and Iodine Compounds.

8.1 Synthesis of Chlorine and Bromine Compounds.

8.2 Fluorine Compounds.

8.3 Iodine Compounds.

Chapter 9 Atrane and Transannular Interaction: Formation of Hypervalent Bond.

9.1 Introduction.

9.2 Silatrane and Atrane.

9.3 Transannular Interaction (1).

9.4 Transannular Interaction (2).

Chapter 10 Unsaturated compound of Main Group Element of 3rd Period and Heavier.

10.1 Introduction.

10.2 Unsaturated Bonds of Group 15 Elements of 3rd Period and Heavier.

10.3 Unsaturated Bonds of Group 14 Elements of 3rd Period and Heavier.

10.4 Aromatic Compounds of Group 14 Elements.

Chapter 11 Ligand Coupling Reaction.

11.1 Introduction.

11.2 Selectivity of Ligand Coupling Reaction: Theoretical Investigation.

11.3 Ligand Coupling Reaction of Organic Compounds of Phosphorus, Antimony, and Bismuth.

11.4 Ligand Coupling Reaction of Organic Compounds of Sulfur, Selenium, and Tellurium.

11.5 Ligand Coupling Reaction of Organoiodine Compound.

Chapter 12 Hypervalent Carbon Compound: Can Hexavalent Carbon Exist?

12.1 Introduction.

12.2 Attempts for Pentacoordinate Hypervalent Carbon Species.

12.3 Synthesis of Pentacoordinate Hypervalent Carbon Species (10-C-5) and Bond Switching at Carbon and Boron.

12.4 Attempts to Hexacoordinate Hypervalent Carbon Species (12-C-6).

Rezensionen

"Summing Up: Highly recommended. Chemistry libraries
serving academic students at all levels, researchers/faculty, and
professionals." (Choice, 1 March 2012)

Produkt-Details

• Erscheint lt. Verlag: 26.7.2011
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Organische Chemie
• Themenwelt: Technik
• Schlagworte: Chemie • Chemistry • Hauptgruppenchemie • Main Group Chemistry • Methods - Synthesis & Techniques • Organische Chemie / Methoden, Synthesen, Verfahren • Physical Organic Chemistry • Physikalische Organische Chemie
• ISBN-10: 1-118-02587-3 / 1118025873
• ISBN-13: 978-1-118-02587-1 / 9781118025871