Inorganic Syntheses, Volume 17 (eBook)

Alan G. Macdiarmid (Herausgeber)

eBook Download: PDF

2009 | 1. Auflage
224 Seiten
John Wiley & Sons (Verlag)
978-0-470-13283-8 (ISBN)

Infos

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

Autor

Alan Graham MacDiarmid, ONZ FRS was a New Zealand-born American chemist, and one of three recipients of the Nobel Prize for Chemistry in 2000.

Inhalt

Preface.

Notice to Contributors.

Chapter One METAL HYDRIDES.

I. MAIN GROUP HYDRIDE (E. C. Ashby).

1. Magnesium Dihydride.

2. Zinc Dihydride.

3. Lithium Trihydridozincate(1-) and Lithium Tetrahydridozincate(2-).

4. Sodium Trihydridodimethyldizincate(1-) and Sodium Trihydridozincate(1-).

5. Calcium Bis[tetrahydroborate(1-)].

6. Quaternary Ammonium and Phosphonium Heptahydroborates.

7. Potassium Tri(sec-butyl)hydroborate(l-).

8. Bis(dimethylamino)borane.

9. Bis-mu-(dimethylamino)-diborane(6).

10. mu-(Dimethylamino)-diborane(6).

11. Trihydrido(trimethylamine)aluminum and (Diethylamino)hydridoaluminum Complexes.

12. Trihydrido(trimethylarnine)gallium.

13. Lithium Tetrahydridogallate(1-).

14. Sodium and Potassium Tetrahydridogallate(1-).

II. TRANSITION METAL HYDRIDE COMPLEXE (Herbert D. Kaesz).

15. Hydrido Phosphine Arene Complexes of Molybdenum.

16. Bis[ethylenebis(diphenylphosphine)] hydrido(2,4-pentanedionato)molybdenum(II).

17. Tris(dimethylphenylphospline) pentahydridorhenium(V).

18. Dodecacarbonyltri-mu-hydrido-triarigulo-trirhenium(I).

19. Bis[ethylenebis (diphenylphosphine)] hydridoiron Complexes.

20. Hydridonitrosyltris (triphenylphosphine) ruthenium(I).

21. Dihydridotetrakis (triphenylphosphine) ruthenium(II).

22. Hydrido[(n¯6-phenyl) diphenylpliosphine] bis(triphenylphosphine) ruthenium(II) Tetrafluoroborate(1-).

23. (Acetato)hydridotris (triphenylphosphine) ruthenium(II).

24. Hydridobis[(+)-diop]rhodium(I).

25. Nickel and Palladium Chlorohydridobis(phosphine) Complexes.

26. Hydrido[tetrahydroborato(l-)] Nickel and Palladium Complexes.

27. Bis(n¯5-cyclopentadienyl) [tetrahydroborato(1-)]titanium.

Chapter Two CARBONYL, PHOSPHINE, OLEFIN, AND RELATED TRANSITION METAL COMPLEXES.

28. (Carbene)pentacarbonyl Complexes of Chromium and Tungsten.

29. Dicarbonyl(n¯5-cyclopentadienyl) (thiocarbonyl)iron(1+) Hexafluorophosphate(1-) and Dicarbony1 (n¯5-cyclopentadienyl) [(methylthio) thiocarbonyl] iron.

30. Tricarbonyl (n¯5-cyclopentadienyl)silyl Complexes of Chromium, Molybdenum, and Tungsten.

31. Phosphine Complexes of Rhenium.

32. pi-Cyclooctenyl-pi-1,5-cyclooctadienecobalt.

33. Dodecacarbonyltetrarhodium.

34. Olefin, Acetylene, Phosphine, Isocyanide, and Diazene Complexes of Nickel(0).

35. (Carboxylato)(triphenylphosphine) Complexes of the Platinum Metals.

36. trans-[Chloroethylbis (triethylphosphine) platinum(II)].

37. Tetrakis(t-butyl isocyanide) di-mu-chloro-dipalladium(I).

Chapter Three OTHER TRANSITION METAL COMPOUNDS.

38. Iron(II) and Cobalt(III) Clathrochelates Derived from Dioximes.

39. Potassium cis-[Diaquabis(oxalato)chromate(III)] Dihydrate and Potassium trans-[Diaquabis(oxalato)chromate(III)] Trihydrate.

40. Cobalt(III), Rhodium(III), and Iridium(III) Carbonato Complexes of the Pentaammine Type.

41. Technetium(VII) Oxide.

Chapter Four MAIN GROUP COMPOUNDS.

42. Tris(dialkylamino)boranes.

43. Tris(N-methylanilino)borane.

44. 1,3-Diaza-2-boracycloalkanes.

45. Gallium Trichloride.

46. Cyclopentadienylsilane and (Methylcyclopentadienyl)silane.

47. Cyclopentadienylgermane.

48. Cyclopentadienyltrimethylstannane.

49. Bis(trimethyltin) Oxide.

50. Methyldiphenylphosphine Oxide and Dimethylphenylphosphine Oxide.

51. Lithium Diphenylphosphide and Diphenyl(trimethylsilyl)phosphine.

52. Pentathiazyl, [S5N5]¯+, Salts.

53. Importance of Excess Base in the Synthesis of Sodium Monothiophosphate.

Correction.

Appendix.

Cautionary Note Concerning the Storing and Handling of Tetrasulfur Tetranitride, S4N4.

Index of Contributors.

Subject Index.

Formula Index.

Produkt-Details

• Erscheint lt. Verlag: 13.10.2009
• Reihe/Serie: Inorganic Syntheses
• Reihe/Serie: Inorganic Syntheses
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Anorganische Chemie
• Themenwelt: Technik
• Schlagworte: Anorganische Chemie • Chemie • Chemistry • Inorganic Chemistry
• ISBN-10: 0-470-13283-3 / 0470132833
• ISBN-13: 978-0-470-13283-8 / 9780470132838