Ionic Liquids in Synthesis (eBook)

Peter Wasserscheid, Thomas Welton (Herausgeber)

eBook Download: PDF

2006 | 1. Auflage
XVI, 364 Seiten
Wiley-VCH (Verlag)
978-3-527-60544-6 (ISBN)

Infos

The demand for increasingly clean and efficient chemical syntheses is becoming more urgent from both an economic and an environmental standpoint. Many technologies rely on large quantities of hazardous even toxic solvents. A promising and now established approach is the development of new, ionic solvents that are fluid at room temperature. These solvents not only have the potential to increase chemical reactivity and thus lead to more efficient processes, but are also non-flammable and are less toxic than conventional solvents due to their low vapor pressure.
This volume brings together the latest developments in this fascinating field, supplemented by numerous practical tips, and thus provides those working in both research and industry with an indispensable source of information. Chemische Synthesen immer sauberer und effektiver zu gestalten - diese Forderung wird sowohl aus ökonomischer Sicht als auch im Hinblick auf die steigenden Umweltbelastungen immer dringlicher. "Green Technologies" sind die Alternative, wobei die in großen Mengen eingesetzten, oft recht gefährlichen und toxischen und Lösungsmittel ganz besonders im Mittelpunkt stehen. Ein vielversprechender und inzwischen etablierter Ansatz ist die Entwicklung von neuen ionischen, schon bei Raumtemperatur flüssigen Solventien. Denn diese "Designerlösungsmittel" haben nicht nur das Potential, die chemische Reaktivität zu erhöhen und damit die Menge an Ausgangsstoffen zu reduzieren. Sie sind vor allem schwer entflammbar und wirken aufgrund ihres geringen Dampfdruckes auch weniger toxisch als die üblicherweise eingesetzten Lösungsmittel.
Dieses Buch faßt die neuesten Entwicklungen auf diesem spannenden Gebiet der Synthesechemie zusammen. Ausgestattet mit vielen Hinweisen für die Durchführung wird es gleichermaßen für den Praktiker in der Forschung wie den Verfahrenschemiker in der Industrie von großem Nutzen sein und sich zu einer unentbehrlichen Informationsquelle machen!

Inhalt

Preface
INTRODUCTION
SYNTHESIS AND PURIFICATION OF IONIC LIQUIDS
Synthesis of Ionic Liquids
Quality Aspects and Other Questions Related to Commercial Ionic Liquid Production
Synthesis of Task-specific Ionic Liquids
PHYSICO-CHEMICAL PROPERTIES
Melting points and phase diagrams
Viscosity and Density of Ionic Liquids
Solubility and Solvation in Ionic Liquids
Gas Solubilities in Ionic Liquids
Polarity
Electrochemical Properties of Ionic Liquids
MOLECULAR STRUCTURE AND DYNAMICS
Order in the Liquid State and Structure
Quantum Mechanical Methods for Structure Elucidation
Molecular Dynamics Simulation Studies
Translational Diffusion
Molecular Reorientational Dynamics
ORGANIC SYNTHESIS
Stoichiometric Organic Reactions and Acid-Catalyzed Reactions in Ionic Liquids
Transition Metal Catalysis in Ionic Liquids
Ionic Liquids in Multiphasic Reactions
Multiphasic Catalysis with Ionic Liquids in Combination with Compressed CO2
INORGANIC SYNTHESIS
Directed Inorganic and Organometallic Synthesis
Making of Inorganic Materials by Electrochemical Methods
POLYMER SYNTHESIS IN IONIC LIQUIDS
BIOCATALYTIC REACTIONS IN IONIC LIQUIDS
OUTLOOK Preface
INTRODUCTION
SYNTHESIS AND PURIFICATION OF IONIC LIQUIDS
Synthesis of Ionic Liquids
Quality Aspects and Other Questions Related to Commercial Ionic Liquid Production
Synthesis of Task-specific Ionic Liquids
PHYSICO-CHEMICAL PROPERTIES
Melting points and phase diagrams
Viscosity and Density of Ionic Liquids
Solubility and Solvation in Ionic Liquids
Gas Solubilities in Ionic Liquids
Polarity
Electrochemical Properties of Ionic Liquids
MOLECULAR STRUCTURE AND DYNAMICS
Order in the Liquid State and Structure
Quantum Mechanical Methods for Structure Elucidation
Molecular Dynamics Simulation Studies
Translational Diffusion
Molecular Reorientational Dynamics
ORGANIC SYNTHESIS
Stoichiometric Organic Reactions and Acid-Catalyzed Reactions in Ionic Liquids
Transition Metal Catalysis in Ionic Liquids
Ionic Liquids in Multiphasic Reactions
Multiphasic Catalysis with Ionic Liquids in Combination with Compressed CO2
INORGANIC SYNTHESIS
Directed Inorganic and Organometallic Synthesis
Making of Inorganic Materials by Electrochemical Methods
POLYMER SYNTHESIS IN IONIC LIQUIDS
BIOCATALYTIC REACTIONS IN IONIC LIQUIDS
OUTLOOK

Rezensionen

"...provides an excellent summary of available information on ionic liquids as well as ready access to the primary literature on specific topics."
Journal of the American Chemical Society

"The book is well written by recognized experts from France, Germany, UK and USA, invited to participate in the elaboration of this volume. The two editors are outstanding scientists, authors of a large number of high level publications in ionic liquids."
Cellulose Chemistry and Technology

Produkt-Details

• Erscheint lt. Verlag: 6.3.2006
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Organische Chemie
• Themenwelt: Technik
• Schlagworte: Analytical Chemistry • Analytische Chemie • Anorganische Chemie • Chemie • Chemie / Organische Chemie • Chemische Synthese • Chemistry • Inorganic Chemistry • Methods - Synthesis & Techniques • Organic Chemistry • Organische Chemie • Organische Chemie / Methoden, Synthesen, Verfahren • Physical Chemistry • Physikalische Chemie
• ISBN-10: 3-527-60544-4 / 3527605444
• ISBN-13: 978-3-527-60544-6 / 9783527605446