Fundamentals of Adsorption (eBook)

M Suzuki (Herausgeber)

eBook Download: PDF

1993 | 1. Auflage
798 Seiten
Elsevier Science (Verlag)
978-0-08-088772-2 (ISBN)

Infos

Fundamentals of Adsorption contains 2 plenary lectures and 96 selected papers from the IVth International Conference, Kyoto, May, 1992. The topics cover a wide range of studies from fundamentals to applications: characterization of porous adsorbents, molecular simulation, adsorption isotherms, diffusion in adsorbents, breakthrough detection, chromatography, pressure swing operation, etc. Model studies on adsorption, surface characterization, microporosimetry, molecular simulations of equilibrium and diffusion, computer simulation of adsorption beds, and many theoretical studies are also included. Special attention is given to: bulk gas separation and purification, solvent recovery, bioproduct separation, environmental pollution control, methane storage, adsorption cooling and resources recovery.

Inhalt

Front Cover 1
Fundamentals of Adsorption 4
Copyright Page 5
Contents 8
Editor's Biography 6
Preface 14
Chapter 1. Plenary Lecture: Novel Applications of Adsorption Technology 18
Chapter 2. Plenary Lecture: Roles of Capillary Condensation in Adsorption 28
Chapter 3. Theoretical Interpretation and Classification of Adsorption Isotherms for Simple Fluids 42
Chapter 4. Simulated Counter-Current Chromatographic Bioreactor-Separators 50
Chapter 5. Diffusion in Zeolite Adsorbents: Measurement, Modelling and Structure - Performance Relation 60
Chapter 6. Computer Simulation Studies of the Adsorption of Kr in a Pore of Triangular Cross-Section 66
Chapter 7. Synthesis, Sorptive Properties and Application of Spherically Granulated Titanium and Zirconium Hydroxophosphates 74
Chapter 8. Evaluation of the Micropore-Size Distribution Function from Gas Adsorption Data by Using a Simple Molecular Model 82
Chapter 9. Radial Anisotropy of the Active Carbon Particles 90
Chapter 10. Adsorption of Multicomponent Aromatics on Y Zeolite and Silicalite 96
Chapter 11. Evaluation of Adsorbents for Volatile Organic Chemicals 104
Chapter 12. Electrosorption an Activated Carbon Bed 112
Chapter 13. Molecular Simulation of Adsorption and Diffusion in VPI-5 and Other Aluminophosphates 120
Chapter 14. Direct Determination and Multiplicity of Periodic States of Adsorption Cycles 128
Chapter 15. Adsorption of Water Vapours in Natural and Modified Zeolites 136
Chapter 16. Prediction of Zeolites Diffusivities 144
Chapter 17. A Molecular Dynamics Study of Adsorption and Transport of Fluid in Model Micropores 152
Chapter 18. Adsorption and Desorption Dynamics of Hydrocarbons, SO2 and CO2 onto Activated Carbon - Rate Mechanisms 160
Chapter 19. Characteristics of Pore Structure of Adsorbents by Macromolecules Adsorption 168
Chapter 20. Multilayer Adsorption and Pore Condensation in Controlled-Pore Glass: A Test of the Saam- Cole Theory of Mesopore Filling 176
Chapter 21. PSA for Air Purification: Experiments and Modeling 184
Chapter 22. Measurement and Prediction of Adsorption Equilibria of Quaternary Organic Solutes from Dilute Aqueous Solutions on Activated Carbon 192
Chapter 23. Effect of Functional Groups on Adsorption of Organics Dissolved in Water onto Macroreticular Resin Particles 200
Chapter 24. Adsorption of Organics onto High Silica Zeolite 208
Chapter 25. Adsorption of Human Immunoglobulins on Activated Supports 216
Chapter 26. Molecular Statistical Calculations of the Adsorption Equilibria of Single and Double Component Gaseous Systems in NaX Zeolites 224
Chapter 27. Nonlinear Interaction of Laser Radiation with Chromatanions (CrO42-) Adsorbed on Dispersed Silica Surface 232
Chapter 28. Purification of Enzyme by Affinity Separation with Magnetic Adsorbent 242
Chapter 29. Adsorption of Argon, Methane, Nitrogen, Carbon Monoxide and Water Vapour on Sepiolite and A1PO4-5 as Studied by Isothermal Microcalorimetry 250
Chapter 30. Optimization of the Operation Parameters for Rapid Pressure Swing Adsorption 258
Chapter 31. Adsorption of Bovine Serum Albumin onto Surface-Modified Carbon Fibers and Cellulose Derivatives 266
Chapter 32. Sorption of Ethene and Propane and Their Binary Mixtures in Zeolites 274
Chapter 33. Methods of Characterizing Sorbents for Air Sampling Purposes 282
Chapter 34. Modifications of the Dubinin-Radushkevitch Equation for Microporous Adsorption 290
Chapter 35. A New Method for Investigation of Sorption Kinetics of Volatile Multi-Component Mixtures on Porous Solids 300
Chapter 36. Hydrogen Sulfide Removal with Pressure Swing Adsorption from Process Off-gas 308
Chapter 37. Adsorption and Diffusion of Methane in Carbon Pores at Low Temperatures 316
Chapter 38. Microscopic Models for Adsorption Equilibrium in Heterogeneous Solids 324
Chapter 39. Ultramicroporosimetry of Porous Solids by He Adsorption 330
Chapter 40. The Use of High Resolution Adsorption Measurements for the Study of Porous Solids 338
Chapter 41. Dynamic Behaviors in the Diffusion of Adsorbed Molecules in the Micropore of Zeolites as Investigated by Molecular Dynamics and Computer Graphics 348
Chapter 42. Competitive Adsorption of Polymer Chains at Fractal Surfaces 356
Chapter 43. Computer Simulation and Performance Analysis of a Purged Rotary Dehumidifier 364
Chapter 44. Modeling of Equalization in Air Separation by Pressure Swing Adsorption 372
Chapter 45. Surface Geometry Effects on Adsorption-Desorption Hysteresis, Latent Adsorption and Adsorption Probability Plots 380
Chapter 46. Effect of Structural Heterogeneity on Multicomponent Adsorption: Benzene and p-Xylene Mixture on Silicalite 388
Chapter 47. Study on Treatment of Organic Wastewater with Modified Bentonite Adsorbent 396
Chapter 48. Adsorption of Proteins and Antibiotics on Porous Alumina Membranes 404
Chapter 49. Adsorb-Sim Modules for Simulation of Adsorption in Micropores: Activated Carbon, Zeolites, Silica and Random Media 412
Chapter 50. Neutron Scattering Investigations of the Structure and Adsorption Properties of Activated Carbon Fibers 420
Chapter 51. Effective Adsorption and Desorption Systems for Semimetal Hydrides 428
Chapter 52. Description of Heterogeneous Surfaces in Activated Chemisorption 436
Chapter 53. Effect of Combined Adsorption and Absorption in Migration of Soil Contaminants 444
Chapter 54. Chromatographic Study of Liquid Phase Adsorption of p-Tert-Octylphenol on Octadecylsilyl- Silica Gel 452
Chapter 55. An Estimation of Liquid Phase Adsorption Isotherms Based on the Capillary Phase Separation Concept 460
Chapter 56. Adsorption Efficiency of Seawater Uranium with Amidoxime Fiber Balls Packed in a Cage 468
Chapter 57. The Analysis of Surface and Pores of Activated Carbons by the Adsorption of Various Kinds of Gases 476
Chapter 58. Evaluation of Microporous Texture of Undecomposed and Decomposed ß-FeOOH Fine Particles by Means of Adsorption Isotherms of Nitrogen Gas and Water Vapor 482
Chapter 59. Thermodynamic and Kinetics Data of Sorption in Zeolites Determined by FTIR 490
Chapter 60. Adsorption of Laterally Interacting Mixtures on Heterogeneous Solid Surfaces: A Model Study 498
Chapter 61. Adsorption Characteristics of Organic Substances on Surface-modified Carbon Adsorbents: Effects of Surface-chemical Structure of Carbon Adsorbents on Adsorption 506
Chapter 62. Analysis of Bimodal Pore Structure from Mercury Porosimetry Using Percolation Approach 514
Chapter 63. Swelling-Shrinking Behavior in Packed Beds of Adsorbent During Column Operations 522
Chapter 64. Two-Body and Many-Body Interactions for Argon Adsorbed in Silicalite Zeolites 530
Chapter 65. Transport in Zeolites: Application of NMR and Computer Simulations to Probe Adsorption Phenomena 538
Chapter 66. Adsorptive Properties of Microporous ZrO2 Gels 546
Chapter 67. Intraparticle Diffusion and Convection in Adsorption Processes 552
Chapter 68. Adsorption of Water Vapour on Activated Alumina 560
Chapter 69. Two Surface Virial Analysis: Monoatomic Gas Adsorption on Graphite and Boron Nitride and Chlorofluorocarbon Adsorption on Microporous Carbon 568
Chapter 70. Gas Adsorption Properties of MSC by Molecular Simulations 574
Chapter 71. Prediction of Highly Nonideal Ternary Adsorption Equilibria 582
Chapter 72. Effect of Structural Heterogeneity on the Diffusion of Aromatic Hydrocarbons in Large Silicalite Crystals 590
Chapter 73. Prediction of High Pressure Multicomponent Adsorption Equilibria 598
Chapter 74. Investigation of Ion Exchange Phenomena in Frontal Anion Exchange Chromatography of a Protein 606
Chapter 75. Porosity Characteristics of Lignite Chars 614
Chapter 76. Analysis of a Six Port Simulated Moving Bed Separation Unit 622
Chapter 77. Sorption Kinetics of Benzene and p-Xylene on Template Supported Synthesized Gallosilicates 630
Chapter 78. On the Determination of Diffusion Coefficients by Uptake Rate Measurements 638
Chapter 79. Determination of Adsorption Equilibria and Bidisperse Transport Properties of Adsorbents Using a Shallow Bed-Diffusion Cell 646
Chapter 80. Continuous Separation and Concentration of Proteins Using an Annular Chromatograph 654
Chapter 81. Application of High Silica Zeolite to Remove Organic Vapors from Industrial Effluent Air 662
Chapter 82. An Overview of Adsorptive Storage of Natural Gas 670
Chapter 83. Influence of Surface Oxides of Carbonaceous Adsorbent on Liquid-phase Desorption Characteristics of Aromatic Compound 678
Chapter 84. Irreversible Adsorption in Porous Materials 686
Chapter 85. Analysis of Adsorption and Adhesion Behaviors of Modified Carbon Fibers by Means of Inverse Gas Chromatography 694
Chapter 86. Novel Application of Adsorption: Energy Recovery 700
Chapter 87. Computer Simulations of Benzene Adsorbed on Graphite. 85-298 K. 710
Chapter 88. Pressure Swing Adsorption Processes-Design and Simulation 718
Chapter 89. Industrial Application of Low-Temperature Steam Desorption System for Solvent Recovery by Activated Carbon 728
Chapter 90. Effect of Pore Structure on the Adsorption of Coagulation Factor VIII on Aminohexyl- and DEAE-Glucomannan Gel 736
Chapter 91. Adsorption of Low Molecular Weight Organic Acids on Polyvinylpyridine Resin 744
Chapter 92. Highly Efficient Adsorbent for Separation of Carbon Monoxide 752
Chapter 93. Heterogeneous Micropore Structure and Vapor Adsorption on Activated Carbons 758
Chapter 94. Development of Adsorption Refrigerator Using Silicagel-Water Pairs 766
Chapter 95. Recovery of Amine and Paints from Electrodeposition Wastewater by Adsorption on H-Form Resin: Cyclic Operation 774
Chapter 96. Breakthrough Curve for Adsorption of Acid Dye on Crosslinked Chitosan Fiber 782
Chapter 97. Improvement to the Flory-Huggins VSM 790
Chapter 98. Model for the Filling of Micropores Applicable to Adsorption of Hydrocarbons and Water by Activated Carbon 794
Chapter 99. Report of Discussion Session on Pressure Swing Adsorption 802
Author Index 809
Keyword Index 812
Studies in Surface Science and Catalysis 815

Produkt-Details

• Erscheint lt. Verlag: 23.12.1993
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Analytische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Physikalische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Technische Chemie
• Themenwelt: Naturwissenschaften ► Geowissenschaften ► Mineralogie / Paläontologie
• Themenwelt: Technik ► Bauwesen
• Themenwelt: Technik ► Umwelttechnik / Biotechnologie
• ISBN-10: 0-08-088772-4 / 0080887724
• ISBN-13: 978-0-08-088772-2 / 9780080887722