Advances in Organometallic Chemistry (eBook)

Mark J. Fink, Anthony F. Hill, Robert C. West (Herausgeber)

eBook Download: PDF

2011 | 1. Auflage
340 Seiten
Elsevier Science (Verlag)
978-0-08-055338-2 (ISBN)

Infos

Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.

* Provides an authoritative, definitive review addressing all aspects of organometallic chemistry
* Useful to researchers within this active field and is a must for every modern library of chemistry
* High quality research book within this rapidly developing field

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Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. - Provides an authoritative, definitive review addressing all aspects of organometallic chemistry- Useful to researchers within this active field and a must for every modern library of chemistry- High-quality research book within this rapidly developing field

Inhalt

Cover 1
Contents 6
Contributors 8
Preface 10
Chapter 1. A Review of Recent Progress in Catalyzed Homogeneous Hydrosilation (Hydrosilylation) 12
I. Introduction 12
II. Hydrosilation with Iron Triad Catalysts 13
III. Cobalt Triad Catalysts 16
IV. Nickel-Triad Catalysts 22
V. Group IVB, Group IIIB, Lanthanides and Actinides 27
VI. Manganese, Rhenium and Copper 31
VII. Catalysis by Acids, Bases, or Free Radicals 33
VIII. Asymmetric Hydrosilation 36
IX. Applied Aspects – Synthesis of Polymers and Materials 43
X. Mechanistic Studies 53
XI. Challenges and the Future of Hydrosilation 61
Acknowledgments 64
References 64
Chapter 2. Organotransition Metal Complexes for Nonlinear Optics 72
I. Introduction 72
II. Theory and Techniques 74
III. Molecular Second-Order Measurements 85
IV. Molecular Third-Order Measurements 119
V. Concluding Remarks 140
Acknowledgment 141
Appendix: Abbreviations 141
References 142
Chapter 3. Pentadienyl Complexes of the Group 4 Transition Metals 148
I. Introduction 148
II. Bis(.5-pentadienyl)Metal Complexes 149
III. Mono(.5-pentadienyl)Metal Complexes 163
IV. Miscellaneous Complexes 179
V. Reaction Chemistry 182
VI. Future Prospects 205
Acknowledgment 206
References 206
Chapter 4. Mixed Metal Acetylide Complexes 212
I. Introduction 212
II. Mixed Group 8 Metal Acetylide Complexes 213
III. Mixed Group 10 Metal Acetylide Complexes 218
IV. Mixed Group 11 Metal Acetylide Complexes 221
V. Mixed Group 6–9 Metal Acetylide Complexes 224
VI. Mixed Group 10–12 Metal Acetylide Complexes 261
VII. Other Mixed Metal Acetylide Complexes 266
VIII. Abbreviations 284
References 284
Chapter 5. Transition Metal Organometallic Synthesis Utilising Diorganoiodine(III) Reagents 290
I. Introduction 290
II. Mechanisms of Reactions of Diorganoiodine(III) Reagents 292
III. Organometallic Chemistry 309
IV. Summary and Emerging Opportunities in Organometallic Chemistry 318
Acknowledgments 319
References 319
Index 326
Cumulative List of Contributors for Volumes 1–36 332
Cumulative Index for Volumes 37–55 336

Produkt-Details

• Erscheint lt. Verlag: 6.9.2011
• Sprache: englisch
• Themenwelt: Sachbuch/Ratgeber
• Themenwelt: Naturwissenschaften ► Chemie ► Anorganische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Organische Chemie
• Themenwelt: Technik
• ISBN-10: 0-08-055338-9 / 0080553389
• ISBN-13: 978-0-08-055338-2 / 9780080553382