Advances in Heterocyclic Chemistry (eBook)

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1973 | 1. Auflage
349 Seiten
Elsevier Science (Verlag)
978-0-08-057602-2 (ISBN)

Infos

ADVANCES IN HETEROCYCLIC CHEMISTRY V15

Inhalt

Cover 1
Advances in Heterocyclic Chemistry, Volume 15 4
Copyright Page 5
Contents 6
Contributors 8
Preface 10
Dedication 12
Chapter 1. Heterocyclic Oligomers 24
I. Introduction 24
ll. Initiation and Termination of Oligomerization 25
lll. Classification and Discussion of Oligomers 26
IV. Conclusion 87
Chapter 2. The Oxidation of Monocyclic Pyrroles 90
I. Introduction 90
ll. Autoxidation 91
III. Photo-oxidation 95
IV. Oxidation by Chemical Reagents 102
V. Pyrrole Blacks 118
VI. Conclusions 119
Note Added in Proof 120
Chapter 3. The Chemistry of 4-Oxy- and 4-Keto-l,2,3,4-tetrahydroisoquinolines 122
I. Introduction 122
II. Synthesis of 4-Oxy-1,2,3,4-tetrahydroisoquinolines 126
III. Reactions of 4-Oxy-1,2,3,4-tetrahydroisoquinolines 139
IV. Naturally Occurring 4-Oxy- 1,2,3,4-tetrahydroisoquinolines 145
V. The State of the Art of Isoquinoline Synthesis 146
VI. Tables of Specific Compounds 151
Chapter 4. Isotopic Hydrogen Labeling of Heterocyclic Compounds by One-Step Methods 160
I. Introduction 160
II. Radiation-Induced Methods 161
III. Heterogeneous Metal-Catalyzed Exchange 172
IV. Current Trends in Labeling 197
Chapter 5. The Chemistry of 1–Pyrindines 210
I. Introduction 210
II. Preparation and Reactions 212
III. Biomedical Applications 252
Chapter 6. 3–Oxo-2,3–dihydrobenz [d] isothiazole-1,1-dioxide (Saccharin) and Derivatives 256
I. Introduction 257
II. Nomenclature 257
III. Structures and Physical Properties 258
IV. The 3-Oxo-2,3-dihydrobenz[d]isothiazole-1 ,1-dioxide System 262
V. The 3-Thioxo-2,3-dihydrobenz[d]isothiazole- 1,1 -dioxide System 283
VI. 3-Alkoxy and 3-Aryloxybenz[d]isothiazole- 1,1-dioxides 285
VII. 3-Aminobenz[d]isothiazole- 1,1-dioxide and Its Derivatives 288
VIII. 3-Imino-2,3-dihydrobenz[d]isothiazole- 1,1-dioxide and Its Derivatives 292
IX. Miscellaneous Compounds 293
X. (Benz[d]isothiazoly1-3-oximino) alkane- 1,1-dioxides 294
XI. 3-Cholorobenz[d]isothiazole- 1,1-dioxide 296
XII. Elimination Reactions with 3-Substituted Benz[d]isothiazole-1,1- dioxides 297
Chapter 7. Applications of Nuclear Magnetic Resonance Spectroscopy to Heterocyclic Chemistry : Indole and Its Derivatives 300
I. Introduction 301
II. The Spectrum of Indole 302
III. Elucidation of a and ß Substitutions 305
IV. Solvent and Concentration Dependence of the 7-Proton Resonance 307
V. Detection of a,ß,and N–H Signals 308
VI. Benzenoid Signals 309
VII. Substituted Indoles 314
VIII. Other Applications 341
IX. Conclusions 345
Author Index 348
Cumulative Index of Titles 371

Produkt-Details

• Erscheint lt. Verlag: 21.9.1973
• Mitarbeit: Herausgeber (Serie): A.J. Boulton, A. R. Katritzky
• Sprache: englisch
• Themenwelt: Sachbuch/Ratgeber ► Beruf / Finanzen / Recht / Wirtschaft ► Bewerbung / Karriere
• Themenwelt: Naturwissenschaften ► Chemie ► Organische Chemie
• Themenwelt: Recht / Steuern ► Privatrecht / Bürgerliches Recht ► Zivilverfahrensrecht
• Themenwelt: Technik
• ISBN-10: 0-08-057602-8 / 0080576028
• ISBN-13: 978-0-08-057602-2 / 9780080576022