Advances in Heterocyclic Chemistry (eBook)

eBook Download: PDF

1966 | 1. Auflage
467 Seiten
Elsevier Science (Verlag)
978-0-08-057593-3 (ISBN)

Infos

ADVANCES IN HETEROCYCLIC CHEMISTRY V 6

Inhalt

Cover 1
Advances in Hetrocyclic Chemistry, Volume 6 4
Copyright Page 5
Contents 10
Contributors 6
Preface 8
Contents of Volume 1– 5 12
Chapter 1. Physicochemical Aspects of the Chemistry of Purines 18
I. Introduction 18
ll. Molecular Structure of Purines 19
III. Nucleophilic and Electrophilic Substitution 28
Chapter 2. The Reduction of Nitrogen Heterocycles with Complex Metal Hydrides 62
I. Mechanism 63
II. Reductions of Pyridines and Pyridinium Ions 72
III. Complex Metal Hydride Reduction of Isoquinolines and Isoquinolinium Ions 85
IV. Complex Metal Hydride Reduction of Quinolines and Quinolinium Salts 90
V. Reduction of Non-aromatic Heterocycles Containing the C = N Function 92
VI. Reductions of Other Heterocycles Containing One Nitrogen Atom 94
VII. Reduction of Heterocycles Containing Two Nitrogen Atoms 97
VIII. Reductions of Azoles 103
IX. Reduction of Heterocycles Containing Three Nitrogen Atoms 106
X. Reduction of Pteridines with Complex Metal Hydrides 108
XI. Summary 110
Chapter 3. Heterocyclic Syntheses Involving Nitrilium Salts and Nitriles under Acidic Conditions 112
I. Introduction 112
II. Ring Formation Involving a Mononitrile Component 113
III. Ring Formation Involving Cyclization of an a,.-Dinitrile 145
Chapter 4. Cyclic Enamines and Imines 164
I. Introduction 164
II. Structure and Physicochemical Properties 165
III. Preparation of Enamines 183
IV. Reactions of Enamines 199
Chapter 5. Substitution in the Pyridine Series: Effect of Substituents 246
I. Introduction„Scope and Limitations 246
II. Theoretical Considerations 247
III. Electrophilic Substitution 253
IV. Nucleophilic Substitution 291
V. Homolytic Substitution 337
VI. Intramolecular Cyclizations 350
Chapter 6. Progress in Pyrazole Chemistry 364
I. Introduction 364
II. The General Character of Pyrazoles 367
III. The Synthesis of Pyrazoles 375
IV. Chemical Properties of the Pyrazole Nucleus 406
Author Index 448
Subject Index 480

Produkt-Details

• Erscheint lt. Verlag: 1.1.1966
• Mitarbeit: Herausgeber (Serie): A.J. Boulton, A. R. Katritzky
• Sprache: englisch
• Themenwelt: Sachbuch/Ratgeber ► Beruf / Finanzen / Recht / Wirtschaft ► Bewerbung / Karriere
• Themenwelt: Naturwissenschaften ► Chemie ► Organische Chemie
• Themenwelt: Recht / Steuern ► Privatrecht / Bürgerliches Recht ► Zivilverfahrensrecht
• Themenwelt: Technik
• ISBN-10: 0-08-057593-5 / 0080575935
• ISBN-13: 978-0-08-057593-3 / 9780080575933