Metal Dihydrogen and &Sgr;-Bond Complexes

Structure, Theory, and Reactivity

Gregory J. Kubas (Autor)

Online Resource

489 Seiten

2001
Kluwer Academic / Plenum Publishers (Hersteller)
978-0-306-47597-9 (ISBN)

Infos

This volume is an account of 20th-century work in the area of sigma complexation. It covers not only Kubas' discovery of dihydrogen coordination and the study of its structure and general properties, but also discusses both the theoretical beliefs and experimental results of bonding and activation of dihydrogen on metal centres and the co-ordination and activation of C--H, B--H, X--H, and X--Y bonds.

Inhalt

Preface. 1. Introduction. 2. Background and Discovery of Dihydrogen Coordination. 3. Synthesis and General Properties of Dihydrogen Complexes. 4. Bonding and Activation of Dihydrogen on Metal Centers: Theory Versus Experiment. 5. Structural and NMR Studies of Dihydrogen Complexes. 6. Intramolecular Dynamics of H2/Hydride Ligand Systems. Hydrogen Rotation, Exchange, and Quantummechanical Effects. 8. Vibrational Studies of Coordinated H2. 9. Reactions and Acidity of H2 Complexes. 10. Activation of Hydrogen and Related Small Molecules by Metalloenzymes and Sulfur Ligand Systems. 11. Coordination and Activation of Si-H, Ge-H, and Sn-H Bonds. 12. C-H Bond Coordination and Activation. 13. Coordination and Activation of B-H and Other X-H and X-Y Bonds.

Produkt-Details

• Reihe/Serie: Modern Inorganic Chemistry
• Verlagsort: Dordrecht
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Organische Chemie
• ISBN-10: 0-306-47597-9 / 0306475979
• ISBN-13: 978-0-306-47597-9 / 9780306475979
• Zustand: Neuware