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Non-Aqueous Solvents - John R. Chipperfield

Non-Aqueous Solvents

Buch | Softcover
94 Seiten
1999
Oxford University Press (Verlag)
978-0-19-850259-3 (ISBN)
CHF 37,90 inkl. MwSt
Solvents other than water are used in chemical analysis, manufacturing and specialist syntheses. This book, written for undergraduate chemistry students, covers the necessary theory required to understand how to choose appropriate solvents for different applications. It includes details for the common solvents used in contemporary chemistry.
Solvents other than water are used in chemical analysis, chemical manufacturing, and in specialist syntheses. This book covers the principles and uses of non-aqueous solvents at a level suitable for first or second-year undergraduates. The book first discusses the general properties of solvents, and introduces the necessary concepts for making rational choices of solvents for different applications. There is a discussion of the various chemical interactions between solvents and the substances dissolved in them, and how solvents change the course of reactions. The chemistry of 16 common solvents is discussed, emphasising the advantages and disadvantages of each. The book concludes with an account of the chemistry of molten salts and discusses the use of low melting temperature compounds as synthetic media. The book expands on the brief treatment of non-aqueous solvents given in many textbooks, but avoids the complexities introduced in research treatises. There is no such book currently available to help students.

Chapter 1: General properties ; 1.1 Introduction ; 1.2 Polarity, Polarization, and Polarizability ; 1.3 Assessment of solvent polarity ; 1.4 Polarity assessment from physical properties ; 1.5 Polarity assessment from chemical properties ; 1.6 Correlation of Solute properties with solvent ; 1.7 Classification of molecular solvents ; 1.8 Problems ; Chapter 2: Chemistry in non-aqueous solvents ; Introduction ; 2.1 Acid-base reactions ; 2.2 Redox reactions ; 2.3 Solvation, solvolysis, solubility, and solvates ; 2.4 Problems ; Chapter 3: Some molecular solvents ; 3.1 Acetic acid ; 3.2 Acetonitrile ; 3.3 Ammonia metals in liquid ammonia; reactions of ammoniated electrons; electrides and alkalides; acid-base reactions in liquid ammonia ; 3.4 Bromine trifluoride ; 3.5 N, N'-Dimethylformamide ; 3.6 Dimethyl sulfoxide ; 3.7 Dinitrogen tetroxide ; 3.8 Ethanol ; 3.9 Ethylenediamine ; 3.10 Hexamethyphosphoramide ; 3.11 Hydrogen fluoride ; 3.12 Sulfur dioxide ; 3.13 Sulfuric acid ; 3.14 Superacides ; 3.15 Tetrahydrofuran ; 3.16 Supercritical fluids ; 3.17 Problems ; Chapter 4: Molten framework solids ; 4.1 Molten salts and oxides ; 4.2 Molten halides ; 4.3 Metals in molten salts ; 4.4 Low melting salts ; 4.5 Group 1 metal nitrate melts ; 4.6 Hydroxide melts as solvents ; 4.7 Oxides as solvents ; Glossary ; Table of molecular solvents ; Bibliography ; Answers to problems

Erscheint lt. Verlag 4.3.1999
Reihe/Serie Oxford Chemistry Primers ; 69
Zusatzinfo numerous line figures
Verlagsort Oxford
Sprache englisch
Maße 188 x 245 mm
Gewicht 206 g
Themenwelt Naturwissenschaften Chemie Analytische Chemie
Naturwissenschaften Chemie Anorganische Chemie
Naturwissenschaften Chemie Physikalische Chemie
ISBN-10 0-19-850259-1 / 0198502591
ISBN-13 978-0-19-850259-3 / 9780198502593
Zustand Neuware
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