Organic Transformations in Water (eBook)

Principles and Applications

Gopinathan Anilkumar, Nissy Ann Harry, Sankuviruthiyil M. Ujwaldev (Herausgeber)

eBook Download: EPUB

2024
670 Seiten
Wiley-VCH (Verlag)
978-3-527-84682-5 (ISBN)

Infos

Harness sustainable, environmentally friendly chemical processes with this timely volume

Green chemistry has played a leading role in the broader search for environmentally sustainable industry. One of its most important goals is the shift from volatile, hazardous organic solvents to environmentally friendly ones, of which by far the most promising is water. Cultivating organic transformations using water as a solvent is one of the most crucial steps towards the creation of green, sustainable chemical production processes.

Organic Transformations in Water provides a cutting-edge overview of water as a reaction medium for synthesis and catalysis. After a brief introduction, the book moves through each of the most important classes of organic transformation before concluding with a survey of industrial applications.

The book will also cover:

• Chemistry and physicochemical aspects of 'on-water' and 'in-water' reactions
• C-H activation, metathesis, nucleophilic addition and substitution, oxidation and reduction, and many more
• Asymmetric organic reactions in water
• Applications in organocatalysis, electrocatalysis, and photocatalysis

Timely and comprehensive, Organic Transformations in Water is a must-own volume for researchers and industry professionals looking to revolutionize their work in a sustainable way.

Gopinathan Anilkumar is a Professor of Organic Chemistry at the School of Chemical Sciences, Mahatma Gandhi University in Kerala, India. His research interests lie in the areas of organic synthesis, medicinal chemistry, heterocycles, and catalysis. He has published more than 215 papers in peer-reviewed journals, 7 patents, 11 book chapters, and edited two books.

Nissy Ann Harry is an Assistant Professor in the Department of Chemistry at Catholicate College in Pathanamthitta, Kerala, India, since 2021. Her research interests include organic synthesis, catalysis, and green chemistry.

Sankuviruthiyil M. Ujwaldev is an Assistant Professor in the Department of Chemistry at Sree Kerala Varma College in Thrissur, Kerala, India, since 2022. His research interests include synthetic organic chemistry and transition metal catalysis.

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List of Abbreviations

A3	aldehyde-alkyne-amine

ABNO	9-azabicyclo[3.3.1]nonane N-oxyl

ADH	alcohol dehydrogenase

API	active pharmaceutical ingredient

ATRP	atom transfer radical polymerization

BIMs	bis(indolyl)methanes

BMIDA

boronic acid N-methyliminodiacetic acid

Bpy	bipyridine

BVMs	Baeyer–Villiger monooxygenases

C-H	carbon–hydrogen

C4A4	calix[4]arene tetracarboxylic acid

cBRIDP

di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine

CDC	cross dehydrogenative coupling

CE	coulombic efficiency

CFP	carbon fiber paper

COMU	1-cyano-2-ethoxy-2-oxoethylidenaminooxy)dimethylamino-morpholinocarbenium hexafluorophosphate

Cryo-TEM

cryogenic transmission electron microscopy

CSTR	continuously stirred tank reactor

CTAB	cetrimonium bromide

CTAC	cetyltrimethylammonium chloride

CTF	covalent triazine framework

β-CD	β-cyclodextrin

CZA	citrazinic acid

CoQ10

coenzyme Q10

D-A	Diels–Alder

DABCO

1,4-diazabicyclo[2.2.2]octane

DBPNA

2,6-dibromo-4-nitroaniline

DBSA	4-dodecylbenzene sulfonic acid

DBU	1,8-diazabicyclo[5.4.0]undec-7-ene

DCGS	diester cationic gemini surfactant

DCILs

dicationic ionic liquids

DCM	dichloromethane

DEAD	diethyl azodicarboxylate

DELs	DNA-encoded libraries

DEPO	diethylphosphine oxide

DFT	density functional theory

DG	directing group

DIPEA

N,N-di-isopropylethylamine

DLS	dynamic light scattering

DMAD	dimethyl azodicarboxylate

DMC	dimethyl carbonate

DMF	dimethylformamide

DmgH	dimethylglyox

DPBS	Dulbecco’s phosphate buffered saline

DPEN	1,2-diphenyl-1,2-ethylenediamine

DTBP	di-tert-butyl peroxide

DTMs	dithiomalonates

E factor

environmental factor

EAN	ethyl ammonium nitrate

ECH	electrocatalytic hydrogenation

EDA	electron donor–acceptor

EDA	ethylenediamine

EDC	1-ethyl-3-(3-(dimethylamino)propyl) carbodiimide

EDTA	ethylenediaminetetraaceticacid

EHS	environment health safety

ERED	Ene-reductase

et al.

et alia

EnT	energy transfer

FAD	flavin adenine dinucleotide

FAP	fatty acid photodecarboxylase

FDCA	2,5-furan dicarboxylic acid

FMO	frontier molecular orbital

G1	Grubbs first-generation catalyst

G2	Grubbs second-generation catalyst

GBB	Groebke–Blackburn–Bienayme

HAT	hydrogen atom transfer

HATU	hexafluorophosphate azabenzotriazole tetramethyl uronium

HBD	hydrogen bond donors

HE	Hantzsch ester

HER	hydrogen evolution reaction

HFIP	1,1,1,3,3,3-hexafluoroisopropanol

HG	Hoveyda–Grubbs

HMPC	hydroxypropyl methylcellulose

i-GAL

innovation green aspiration level

I-MCRs

isocyanide-based multicomponent reaction

KREDs

ketoreductases

LUMO	lowest unoccupied molecular orbital

MCCA	medium-chain carboxylic acids

MCR	multicomponent reaction

MNPs	magnetic nanoparticles

MO	molecular orbital

MOF	metal-organic framework

Mpg-CN

mesoporous graphitic carbon nitride

MVK	methyl vinyl ketone

MVS	methyl vinyl sulfone

MWCNTs MNCs

multiwalled carbon nanotubes magnetic nanocomposites

MWI	microwave irradiation

NADPH

nicotinamide adenine dinucleotide phosphate hydrogen

NGO	N-doped graphene oxide

NHC	N-heterocyclic carbene

Ni-MPA

NiII-3-mercaptopropionic acid

NMP	N-methylpyrrolidone

NMR	nuclear magnetic resonance

NP	nanoparticle

OBBD	B-alkyl-9-oxa-10-borabicyclo[3.3.2]decane

oCB	oxidised carbon black

OEOMA

oligo(ethylene oxide) methyl ether methacrylate

OER	oxygen evolution reaction

OFRs	oscillatory plug flow reactor

o-QMs

ortho-quinone methides

ORR	oxygen reduction reaction

PAA	polyacrylic acid

PBAM-ran-PHPAM

poly(N-(benzyl acrylamide))-ran-poly(N-(2-hydroxypropyl)acrylamide)

PCET	proton-coupled-electron-transfer

PChlide

protochlorophyllide

pDApr

polydiacetylene-proline

PEG	polyethylene glycol

pH	potential of hydrogen

PHU	1-(3,5-bis(trifluoromethyl)phenyl)-3-((R)-phenyl((S)-pyrrolidin-2-yl)methyl)urea

PIDA	poly(diiododiacetylene)

PIL	polymer ionic liquid

PILs	protic ionic liquids

PMI	process mass intensity

ppm	parts per million

PQS	polyethyleneglycol ubiquinol succinate

PTC	phase transfer catalysis

PTS	polyoxyethanyl-α-tocopheryl sebacate

RCM	ring-closing metathesis

RDS	rate determining step

ROMP	ring-opening metathesis polymerization

RT	room temperature

SCF	supercritical fluids

SDOSS

sodium dioctyl sulfosuccinate

SDS	sodium dodecyl sulfate

SERS	surface-enhanced Raman spectroscopy

SET	single electron...

Produkt-Details

• Erscheint lt. Verlag: 30.10.2024
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Organische Chemie
• Schlagworte: asymmetric synthesis • carbene reaction • C-H Activation • electrocatalysis • Green chemistry • green solvents • Industrial Applications • in-water • micellar catalysis • multicomponent reactions • Nucleophilic addition • Nucleophilic substitution • Olefin Metathesis • on-water • organic synthesis, catalysis • Organocatalysis • Oxidation • Pericyclic Reactions • phase-transfer catalysis • radical reaction • reduction • Sustainable chemistry • Visible light photocatalysis • Water
• ISBN-10: 3-527-84682-4 / 3527846824
• ISBN-13: 978-3-527-84682-5 / 9783527846825