Oxoacidity: Reactions of Oxo-compounds in Ionic Solvents
Seiten
2005
Elsevier Science Ltd (Verlag)
978-0-444-55036-1 (ISBN)
Elsevier Science Ltd (Verlag)
978-0-444-55036-1 (ISBN)
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The generally accepted definitions of acids and bases together with the generalized definition for the solvent system introduced by the author for the description of both molecular and ionic solvents are discussed. The oxobasicity index introduced as a measure of relative oxoacidic properties of ionic melts (pIL) and methods of its determination are presented. Moreover, the oxoacidity scales of ionic melts based on alkali metal halides at different temperatures are constructed. The sequential addition method (SAM), proposed by the author to investigate the effect of oxide particle size on oxide solubilities is presented.
This book is meant for specialists developing theoretical and applied aspects of molten salt chemistry, acid-base theories and solubility phenomena. It will also be useful for those chemists who wish to extend their knowledge of physical and solution chemistry.
This book is meant for specialists developing theoretical and applied aspects of molten salt chemistry, acid-base theories and solubility phenomena. It will also be useful for those chemists who wish to extend their knowledge of physical and solution chemistry.
Chapter 1. Homogeneous acid-base equilibriaPart 1. Definitions of acids and basesPart 2. Studies of homogeneous acid-base reactions in ionic meltsPart 3. Acid-base ranges in ionic meltsEstimation of relative acidic properties of ionic melts
Chapter 2. Oxygen electrodes in ionic melts. Oxide ion donorsPart 4. Oxygen electrode reversibility in ionic meltsPart 5. Investigations of dissociation of Lux bases in ionic melts
Chapter 3. Equilibria in 'solid oxide-ionic melt' systemsPart 6. Parameters describing oxide dissolution process and methods of their determinationPart 7. Regularities of oxide solubilities in melts based on alkali and alkaline earth metal halides
| Erscheint lt. Verlag | 28.2.2005 |
|---|---|
| Reihe/Serie | Comprehensive Chemical Kinetics |
| Verlagsort | Oxford |
| Sprache | englisch |
| Themenwelt | Naturwissenschaften ► Chemie ► Organische Chemie |
| ISBN-10 | 0-444-55036-4 / 0444550364 |
| ISBN-13 | 978-0-444-55036-1 / 9780444550361 |
| Zustand | Neuware |
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