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Elements of Chemical Reaction Engineering, Global Edition

(Autor)

Buch | Softcover
1080 Seiten
2022 | 6th edition
Pearson Education Limited (Verlag)
978-1-292-41666-3 (ISBN)
CHF 129,95 inkl. MwSt
The Definitive Guide to Chemical Reaction Engineering Problem-Solving -- With Updated Content and More Active Learning

For decades, H. Scott Fogler's Elements of Chemical Reaction Engineering has been the world's dominant chemical reaction engineering text. This Sixth Edition and integrated Web site deliver a more compelling active learning experience than ever before. Using sliders and interactive examples in Wolfram, Python, POLYMATH, and MATLAB, students can explore reactions and reactors by running realistic simulation experiments.

Writing for today's students, Fogler provides instant access to information, avoids extraneous details, and presents novel problems linking theory to practice. Faculty can flexibly define their courses, drawing on updated chapters, problems, and extensive Professional Reference Shelf web content at diverse levels of difficulty.

The book thoroughly prepares undergraduates to apply chemical reaction kinetics and physics to the design of chemical reactors. And four advanced chapters address graduate-level topics, including effectiveness factors. To support the field's growing emphasis on chemical reactor safety, each chapter now ends with a practical safety lesson.



Updates throughout the book reflect current theory and practice and emphasize safety
New discussions of molecular simulations and stochastic modeling
Increased emphasis on alternative energy sources such as solar and biofuels
Thorough reworking of three chapters on heat effects
Full chapters on nonideal reactors, diffusion limitations, and residence time distribution

About the Companion Web Site (umich.edu/~elements/6e/index.html)



Complete PowerPoint slides for lecture notes for chemical reaction engineering classes
Links to additional software, including POLYMATHTM, MATLABTM, Wolfram MathematicaTM, AspenTechTM, and COMSOLTM
Interactive learning resources linked to each chapter, including Learning Objectives, Summary Notes, Web Modules, Interactive Computer Games, Solved Problems, FAQs, additional homework problems, and links to Learncheme
Living Example Problems -- unique to this book -- that provide more than 80 interactive simulations, allowing students to explore the examples and ask "what-if" questions
Professional Reference Shelf, which includes advanced content on reactors, weighted least squares, experimental planning, laboratory reactors, pharmacokinetics, wire gauze reactors, trickle bed reactors, fluidized bed reactors, CVD boat reactors, detailed explanations of key derivations, and more
Problem-solving strategies and insights on creative and critical thinking

Register your book for convenient access to downloads, updates, and/or corrections as they become available. See inside book for details.

H. Scott Fogler is the Ame and Catherine Vennema Professor of Chemical Engineering and the Arthur F. Thurnau Professor at the University of Michigan. He has been research advisor to forty-five Ph.D. students, and has more than two hundred thirty-five refereed publications. He was 2009 President of the American Institute of Chemical Engineers. Fogler has chaired ASEE's Chemical Engineering Division, served as director of the American Institute of Chemical Engineers, and earned the Warren K. Lewis Award from AIChE for contributions to chemical engineering education. He has received the Chemical Manufacturers Association's National Catalyst Award and the 2010 Malcom E. Pruitt Award from the Council for Chemical Research.

Mole Balances 1

The Rate of Reaction, –r_A
The General Mole Balance Equation (GMBE)
Batch Reactors (BRs)
Continuous-Flow Reactors
Industrial Reactors
And Now . . . A Word from Our Sponsor—Safety 1 (AWFOS - S1 Safety)


Conversion and Reactor Sizing

Definition of Conversion
Batch Reactor Design Equations
Design Equations for Flow Reactors
Sizing Continuous-Flow Reactors
Reactors in Series
Some Further Definitions
And Now . . . A Word from Our Sponsor—Safety 2


Rate Laws 75

Basic Definitions
The Rate Law
The Reaction-Rate Constant
Molecular Simulations
Present Status of Our Approach to Reactor Sizing and Design
And Now . . . A Word from Our Sponsor—Safety 3 (AWFOS - S3 The GHS Diamond)


Stoichiometry

Batch Reactors (BRs)
Flow Systems
Reversible Reactions and Equilibrium Conversion
And Now . . . A Word from Our Sponsor—Safety 4 (AWFOS - S4 The Swiss Cheese Model


Isothermal Reactor Design: Conversion

Design Structure for Isothermal Reactors
Batch Reactors (BRs)
Continuous-Stirred Tank Reactors (CSTRs)
Tubular Reactors
Pressure Drop in Reactors
Synthesizing the Design of a Chemical Plant
And Now . . . A Word from Our Sponsor—Safety 5 (AWFOS - S5 A Safety Analysis of the Incident Algorithm)


Isothermal Reactor Design: Moles and Molar Flow Rates

The Moles and Molar Flow Rate Balance Algorithms
Mole Balances on CSTRs, PFRs, PBRs, and Batch Reactors
Application of the PFR Molar Flow Rate Algorithm to a Microreactor
Membrane Reactors
Unsteady-State Operation of Stirred Reactors
Semibatch Reactors
And Now . . . A Word from Our Sponsor—Safety 6 (AWFOS - S6 The BowTie Diagram)


Collection and Analysis of Rate Data

The Algorithm for Data Analysis
Determining the Reaction Order for Each of Two Reactants Using the Method of Excess
Integral Method
Differential Method of Analysis
Nonlinear Regression
Reaction-Rate Data from Differential Reactors
Experimental Planning
And Now . . . A Word from Our Sponsor—Safety 7 (AWFOS - S7 Laboratory Safety)


Multiple Reactions

Definitions
Algorithm for Multiple Reactions
Parallel Reactions
Reactions in Series
Complex Reactions
Membrane Reactors to Improve Selectivity in Multiple Reactions
Sorting It All Out
The Fun Part
And Now . . . A Word from Our Sponsor—Safety 8 (AWFOS - S8 The Fire Triangle)


Reaction Mechanisms, Pathways, Bioreactions, and Bioreactors

Active Intermediates and Nonelementary Rate Laws
Enzymatic Reaction Fundamentals
Inhibition of Enzyme Reactions
Bioreactors and Biosynthesis
And Now . . . A Word from Our Sponsor—Safety 9 (AWFOS - S9 Process Safety Triangle)


Catalysis and Catalytic Reactors

Catalysts
Steps in a Catalytic Reaction
Synthesizing a Rate Law, Mechanism, and Rate-Limiting Step
Heterogeneous Data Analysis for Reactor Design
Reaction Engineering in Microelectronic Fabrication
Model Discrimination
Catalyst Deactivation
Reactors That Can Be Used to Help Offset Catalyst Decay
And Now . . . A Word from Our Sponsor—Safety 10 (AWFOS - S10 Exxon Mobil Torrance Refinery Explosion Involving a Straight-Through Transport Reactor [STTR])


Nonisothermal Reactor Design: The Steady-State Energy Balance and Adiabatic PFR Applications

Rationale
The Energy Balance
The User-Friendly Energy Balance Equations
Adiabatic Operation
Adiabatic Equilibrium Conversion
Reactor Staging with Interstage Cooling or Heating
Optimum Feed Temperature
And Now . . . A Word from Our Sponsor—Safety 11 (AWFOS - S11 Acronyms)


Steady-State Nonisothermal Reactor Design: Flow Reactors with Heat Exchange

Steady-State Tubular Reactor with Heat Exchange
Balance on the Heat-Transfer Fluid
Examples of the Algorithm for PFR/PBR Design with Heat Effects
CSTR with Heat Effects
Multiple Steady States (MSS)
Nonisothermal Multiple Chemical Reactions
Radial and Axial Temperature Variations in a Tubular Reactor
And Now . . . A Word from Our Sponsor—Safety 12 (AWFOS - S12 Safety Statistics)


Unsteady-State Nonisothermal Reactor Design

The Unsteady-State Energy Balance
Energy Balance on Batch Reactors (BRs)
Batch and Semibatch Reactors with a Heat Exchanger
Nonisothermal Multiple Reactions
And Now . . . A Word from Our Sponsor—Safety 13 (AWFOS - S13 Safety Analysis of the T2 Laboratories Incident)


Mass Transfer Limitations in Reacting Systems

Diffusion Fundamentals
Binary Diffusion
Modeling Diffusion with Chemical Reaction
The Mass Transfer Coefficient
Mass Transfer to a Single Particle
The Shrinking Core Model
Mass Transfer-Limited Reactions in Packed Beds
Robert the Worrier
What If . . . ? (Parameter Sensitivity)
And Now . . . A Word from Our Sponsor—Safety 14 (AWFOS - S14 Sugar Dust Explosion)


Diffusion and Reaction

Diffusion and Reactions in Homogeneous Systems
Diffusion and Reactions in Spherical Catalyst Pellets
The Internal Effectiveness Factor
Falsified Kinetics
Overall Effectiveness Factor
Estimation of Diffusion- and Reaction-Limited Regimes
Mass Transfer and Reaction in a Packed Bed
Determination of Limiting Situations from Reaction-Rate Data
Multiphase Reactors in the Professional Reference Shelf
Fluidized Bed Reactors
Chemical Vapor Deposition (CVD)
And Now . . . A Word from Our Sponsor—Safety 15 (AWFOS - S15 Critical Thinking Questions Applied to Safety)


Residence Time Distributions of Chemical Reactors

General Considerations
Measurement of the RTD
Characteristics of the RTD
RTD in Ideal Reactors
PFR/CSTR Series RTD
Diagnostics and TroubleshootingAnd Now . . . A Word from Our Sponsor—Safety 16 (AWFOS - S16 Critical Thinking Actions)


Predicting Conversion Directly from the Residence Time Distribution

Modeling Nonideal Reactors Using the RTD
Zero Adjustable Parameter Models
Using Software Packages Such as Polymath to Find Maximum Mixedness Conversion
Tanks-in-Series One Parameter Model, n
RTD and Multiple Reactions
And Now . . . A Word from Our Sponsor—Safety 17 (AWFOS - S17 Brief Case History on an Air Preheater)


Models for Nonideal Reactors

Some Guidelines for Developing Models
Flow and Axial Dispersion of Inert Tracers in Isothermal Reactors
Flow, Reaction, and Axial Dispersion
Flow, Reaction, and Axial Dispersion in Isothermal Laminar-Flow Reactors and Finding Meno
Tanks-in-Series Model versus Dispersion Model
Numerical Solutions to Flows with Dispersion and Reaction
Nonisothermal Flow with Radial and Axial Variations in a Tubular Reactor
Two-Parameter Models—Modeling Real Reactors with Combinations of Ideal Reactors
And Now . . . A Word from Our Sponsor—Safety 18 (AWFOS - S18 An Algorithm for Management of Change (MoC))



Appendix A: Numerical Techniques

A.1 Useful Integrals in Chemical Reactor Design
A.2 Equal-Area Graphical Differentiation
A.3 Solutions to Differential Equations
A.4 Numerical Evaluation of Integrals
A.5 Semi-Log Graphs
A.6 Software Packages

Appendix B: Ideal Gas Constant and Conversion Factors Appendix C: Thermodynamic Relationships Involving the Equilibrium Constant Appendix D: Software Packages

D.1 Polymath
D.2 Wolfram
D.3 Python
D.4 MATLAB
D.5 Excel
D.6 COMSOL (http://www.umich.edu/~elements/6e/12chap/comsol.html)
D.7 Aspen
D.8 Visual Encyclopedia of Equipment: Reactors Section
D.9 Reactor Lab

Appendix E: Rate-Law Data Appendix F: Nomenclature Appendix G: Open-Ended Problems

G.1 Chem-E-Car
G.2 Effective Lubricant Design
G.3 Peach Bottom Nuclear Reactor
G.4 Underground Wet Oxidation
G.5 Hydrodesulfurization Reactor Design
G.6 Continuous Bioprocessing
G.7 Methanol Synthesis
G.8 Cajun Seafood Gumbo
G.9 Alcohol Metabolism
G.10 Methanol Poisoning
G.11 Safety

Appendix H: Use of Computational Chemistry Software Packages

H.1 Computational Chemical Reaction Engineering

Appendix I: How to Use the CRE Web Resources

I.1 CRE Web Resources Components
Index

Erscheinungsdatum
Verlagsort Harlow
Sprache englisch
Maße 204 x 254 mm
Gewicht 1800 g
Themenwelt Naturwissenschaften Chemie
Technik Umwelttechnik / Biotechnologie
ISBN-10 1-292-41666-1 / 1292416661
ISBN-13 978-1-292-41666-3 / 9781292416663
Zustand Neuware
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