Nicht aus der Schweiz? Besuchen Sie lehmanns.de
Für diesen Artikel ist leider kein Bild verfügbar.

Modern Aspects of Diffusion-Controlled Reactions

Cooperative Phenomena in Bimolecular Processes

, (Autoren)

Buch | Hardcover
611 Seiten
1996
Elsevier Science Ltd (Verlag)
978-0-444-82472-1 (ISBN)
CHF 418,95 inkl. MwSt
  • Titel ist leider vergriffen;
    keine Neuauflage
  • Artikel merken
This monograph deals with the effects of reactant spatial correlations arising in the course of basic biomolecular reactions describing defect recombination, energy transfer and exciton annihilation in condensed matter. These effects lead to the kinetics being considered "abnormal".
This monograph deals with the effects of reactant spatial correlations arising in the course of basic bimolecular reactions describing defect recombination, energy transfer and exciton annihilation in condensed matter. These effects lead to the kinetics considered abnormal from the standard chemical kinetics point of view. Numerous bimolecular reaction regimes and conditions are analysed in detail. Special attention is paid to the development and numerous applications of a novel, many-point density (MPD) formalism, which is based on Kirkwood's superposition approximation used for decoupling three-particle correlation functions.The book demonstrates that incorporation of the reaction-induced spatial correlations of similar reactants (e.g., vacancy-vacancy) leads to the development of an essentially non-Poisson spectrum of reactant density fluctuations. This can completely change the kinetics at longer times since it no longer obeys the law of mass action. The language of the correlation lengths and critical exponents similar to physics of critical phenomena is used instead. A relation between MPD theory and synergistics is discussed. The validity of the theorem giving a critical complexity for the two-step reactions exhibiting self-organization phenomena is questioned. Theoretical results are illustrated by numerous experimental data.

Preface. 1. Guide to the book. 2. Basic methods for describing chemical kinetics in condensed media: continuum models. 3. From pair kinetics toward the many–reactant problem. 4. The linear approximation in bimolecular reaction kinetics. 5. The fluctuation–controlled kinetics: the basic formalism of many–point particle densities. 6. The many–particle effects in irreversible A + B → 0 reaction. 7. The many–particle effects in A + B → 0 reaction with particle generation. 8. Systems under birth and death conditions: Lotka and Lotka–Volterra models. 9. Catalytic reactions on solid surfaces. 10. General conclusion. Author Index. Subject Index.

Erscheint lt. Verlag 24.10.1996
Reihe/Serie Comprehensive Chemical Kinetics
Verlagsort Oxford
Sprache englisch
Gewicht 1280 g
Themenwelt Naturwissenschaften Chemie Physikalische Chemie
ISBN-10 0-444-82472-3 / 0444824723
ISBN-13 978-0-444-82472-1 / 9780444824721
Zustand Neuware
Haben Sie eine Frage zum Produkt?
Mehr entdecken
aus dem Bereich
Quantenmechanik | Spektroskopie | Statistische Thermodynamik

von Sebastian Seiffert; Wolfgang Schärtl

Buch | Softcover (2024)
De Gruyter (Verlag)
CHF 83,90
Thermodynamik | Kinetik | Elektrochemie

von Sebastian Seiffert; Wolfgang Schärtl

Buch | Softcover (2024)
De Gruyter (Verlag)
CHF 83,90