Organophosphorus Chemistry 2018

Buch | Softcover

601 Seiten

2020
MDPI (Verlag)
978-3-03928-236-4 (ISBN)

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Organophosphorus chemistry is an important discipline within organic chemistry. Phosphorus compounds, such as phosphines, trialkyl phosphites, phosphine oxides (chalcogenides), phosphonates, phosphinates and >P(O)H species, etc., may be important starting materials or intermediates in syntheses. Let us mention the Wittig reaction and the related transformations, the Arbuzov- and the Pudovik reactions, the Kabachnik–Fields condensation, the Hirao reaction, the Mitsunobu reaction, etc. Other reactions, e.g., homogeneous catalytic transformations or C-C coupling reactions involve P-ligands in transition metal (Pt, Pd, etc.) complex catalysts. The synthesis of chiral organophosphorus compounds means a continuous challenge. Methods have been elaborated for the resolution of tertiary phosphine oxides and for stereoselective organophosphorus transformations. P-heterocyclic compounds, including aromatic and bridged derivatives, P-functionalized macrocycles, dendrimers and low coordinated P-fragments, are also of interest. An important segment of organophosphorus chemistry is the pool of biologically-active compounds that are searched and used as drugs, or as plant-protecting agents. The natural analogue of P-compounds may also be mentioned. Many new phosphine oxides, phosphinates, phosphonates and phosphoric esters have been described, which may find application on a broad scale. Phase transfer catalysis, ionic liquids and detergents also have connections to phosphorus chemistry. Green chemical aspects of organophosphorus chemistry (e.g., microwave-assisted syntheses, solvent-free accomplishments, optimizations, and atom-efficient syntheses) represent a dynamically developing field. Last, but not least, theoretical approaches and computational chemistry are also a strong sub-discipline within organophosphorus chemistry.

Erscheinungsdatum	09.03.2020
Verlagsort	Basel
Sprache	englisch
Maße	170 x 244 mm
Themenwelt	Naturwissenschaften ► Chemie ► Allgemeines / Lexika
Schlagworte	1,3-azaphospholes • 1-(acylamino)alkylphosphonic acids • 1-aminoalkylphosphonic acids • 31P NMR spectra of intermediates • alcoholysis • Allylic Alkylation • Amino Acids • Aminophosphonic acids • Asymmetric catalysis • bis(phosphane) palladium complex • C-H Bond Activation • chiral phosphines • continuous flow reactor • Copper • cyclo-P5 • denufosol • DFT • DFT Calculations • dialkyl H-phosphonates • Diels-Alder Reaction • dinucleotides • diphosphines • diquafosol • dissociation constants • dry eye syndrome • dynamic and specific NMR parameters • Electronic parameters • electrophilic substitution • Hydrolysis • hydrolytic deacylation • Mechanochemistry • metallacycle • microwave • Molybdenum • N-acylimine • N-acyliminium cation • NMR-controlled titration • NORPHOS • O-derivatization • organophosphorus chemistry • Oxidation • Phosphonic acids • phosphonium salts • phosphonocarboxylic acids • phosphorylation • polycyclic compounds • Pudovik reaction • QTAIM • rearrangement • Silver • stability constants • Stereoselective Synthesis • Substitution • synergy • Transesterification • triple-decker • weakly coordinating • α-amidoalkylating agents • α-hydroxyphosphonate
ISBN-10	3-03928-236-0 / 3039282360
ISBN-13	978-3-03928-236-4 / 9783039282364
Zustand	Neuware