S Sulfur-Nitrogen Compounds
Compounds with Sulfur of Oxidation Number IV
Seiten
1990
|
8. Softcover reprint of the original 8th ed. 1989
Springer Berlin (Verlag)
978-3-662-06359-0 (ISBN)
Springer Berlin (Verlag)
978-3-662-06359-0 (ISBN)
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The present volume is the first of a series describing acyclic sulfur-nitrogen compounds with sulfur of oxidation number IV. The acyclic sw-N compounds are arranged according to the coordination number of the sulfur. Neutral compounds are described before ions and complex compounds. The preceding series "Sulfur-Nitrogen Compounds" Parts 2, 3, and 4 covers the cyclic sw-N compounds. In this volume, the first section deals with sulfur-nitrogen compounds with 1-coordinate sulfur and begins with the sulfur nitride {thiazyl) radical, SN. This transient molecule was observed in its electronic ground state and several electronically excited states. The descrip tions of the sulfur nitride (thiazyl) ions SN+ and SW follow. The SN+ ionwas studied in the gas phase as weil as in the solid state where it forms salts. Thionitrosyl complexes containing the SN Iigand as a terminal linear unit are described at the end of the first section. The second section concerns Sulfur-nitrogen compounds with 2-coordinate sulfur and starts with the description of poly(sulfur nitride), (SNlx· The preparation, crystal structure, and metallic and superconducting properties of (SN)x, which were extensively studied, fill a !arge part of the volume. Halogen-modified poly(sulfur nitride) such as the widely studied (SNBr )x 04 and Na-modified poly(sulfur nitride) are dealt with in the following chapters.
1 Sulfur-Nitrogen Compounds with 1-Coordinate Sulfur.- 2 Sulfur-Nitrogen Compounds with 2-Coordinate Sulfur.- Physical Constants and Conversion Factors.
| Erscheinungsdatum | 19.12.2018 |
|---|---|
| Reihe/Serie | Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition ; S / S-N / 5 | S. Schwefel. Sulfur (System-Nr. 9) |
| Mitarbeit |
Chef-Herausgeber: Alfons Kubny |
| Zusatzinfo | XVI, 276 p. 58 illus., 1 illus. in color. |
| Verlagsort | Berlin |
| Sprache | englisch |
| Maße | 178 x 254 mm |
| Themenwelt | Naturwissenschaften ► Chemie ► Anorganische Chemie |
| Schlagworte | Chemistry • metals • Oxidation |
| ISBN-10 | 3-662-06359-X / 366206359X |
| ISBN-13 | 978-3-662-06359-0 / 9783662063590 |
| Zustand | Neuware |
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