Handbook of Inorganic and Organometallic Chemistry / S. Schwefel. Sulfur. (System-Nr. 9) / S-Sulphur-Nitrogen Compounds. S-N-Verbindungen / Compounds with Sulfur of Oxidation Number II

Norbert Baumann, Hans J. Fachmann, Reimund Jotter, Gmelin (Autoren)

Norbert Baumann, Hans J. Fachmann, Reimund Jotter, Alfons Kubny (Herausgeber)

Buch | Hardcover

XXV, 297 Seiten

1994 | 8., Aufl.
Springer Berlin (Verlag)
978-3-540-93707-4 (ISBN)

Infos

This volume continues the description of acyclic sulfur(II)-nitrogen compounds with two-coordinate sulfur. N,N,N',N'-Tetraorganyl-substituted diaminosulfanes are generally prepared by reacting secondary amines with SCl2. N,N,N',N'-Tetraalkyl-diamino-sulfanes form adducts with boron compounds and complexes with transition metals. Carbon disulfide and various reagents of the X=C=Y type can be readily inserted into the S-N bonds. R2NSNR2 is reacted with CS2 to give R2NC(S)-Sn-C(S)NR2, n z 2. Reactions of R2NSNR2 with isocyanate and isothiocyanate, R'N=C=Y (Y = O,S), produce R2NSN(R')C(Y)NR2. The biological activity of diaminosulfanes with the appropriate substituents (e.g., R-OC(O), R = 2,2-dimethyl-2,3-dihydro-7-yl-benzofuran) has been explored.

Produkt-Details

• Reihe/Serie: Handbook of Inorganic and Organometallic Chemistry ; Part 10 / Part b | 1.1310
• Mitarbeit: Index von: U. Hettwer; Chef-Herausgeber: Alfons Kubny
• Sprache: englisch
• Gewicht: 900 g
• Einbandart: gebunden
• Themenwelt: Naturwissenschaften ► Chemie ► Anorganische Chemie
• Schlagworte: HC/Chemie/Anorganische Chemie • Schwefeloxide
• ISBN-10: 3-540-93707-2 / 3540937072
• ISBN-13: 978-3-540-93707-4 / 9783540937074
• Zustand: Neuware