Organosilicon Compounds
Academic Press Inc (Verlag)
978-0-12-801981-8 (ISBN)
Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon–silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds’ structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry.
Dr. Lee has more than 30 years in experimental organometallic chemistry, specializing in the field of Main Group elements chemistry, primarily the heavier Group 14 elements (Si, Ge, Sn, Pb). In addition to his background and career as a synthetic organometallic chemist, he has extensive experience of the scientific writing and publishing processes as the author and co-author of more than 100 peer-reviewed research papers, published predominantly in high-ranking international journals (JACS, Angew. Chem., Organometallics, Inorg. Chem., etc.). He has also written scientific books contributions and co-authored six book chapters and one monograph, the latest of which are the following: (a) V. Ya. Lee and A. Sekiguchi. Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb: From Phantom Species to Stable Compounds, Wiley, Chichester, 2010 [monograph]; (b) V. Ya. Lee and A. Sekiguchi. Multiply Bonded Compounds of the Heavy Group 14 Elements. In Comprehensive Inorganic Chemistry II (Eds. J. Reedijk and K. Poeppelmeier), Elsevier, Oxford, 2013, Vol. 1 (Vol. Ed.: T Chivers), Chapter 1.11.
I. Theory
Chapter I.1 Nonclassical Organosilicon Compounds
II. Experiment
II.1. Synthesis
II.1.1. Organosilicon Compounds of Tetracoordinate Silicon
Chapter II.1.1.1. Transition Metal Complexes of Silicon (excluding silylene complexes)
Chapter II.1.1.2. Silicon Cages and Clusters
Chapter II.1.1.3. Chiral Organosilicon Compounds
II.1.2. Organosilicon Compounds of Low-Coordinate Silicon
Chapter II.1.2.1. Silicon-Centered Cations
Chapter II.1.2.2. Silicon-Centered Radicals
Chapter II.1.2.3. Silicon-Centered Anions
Chapter II.1.2.4. Silylenes and Their Transition Metal Complexes
Chapter II.1.2.5. Multiple Bonds to Silicon
Chapter II.1.2.6. Silaaromatics and Related Compounds
II.1.3. Organosilicon Compounds of Hypercoordinate Silicon
Chapter II.1.3.1. Penta - and Hexacoordinated Silicon (IV) Compounds
II.2. Physico-Chemical Studies
Chapter II.2.1. X-Ray Crystallography of Organosilicon Compounds
Chapter II.2.2. 29Si NMR Spectroscopy
Chapter II.2.3. Thermochemistry of Organosilicon Compounds
Chapter II.2.4. Photoelectron Spectroscopy of Organosilicon Compounds
III. Applications
Chapter III.1. Hydrosilylation of the Carbon–Carbon Multiple Bonds
Chapter III.2. Polysilanes
Chapter III.3. Siloxanes and Silicones
Chapter III.4. Silicon-Based Dendrimers and Irregular Hyperbranched Polymers
| Erscheinungsdatum | 13.08.2017 |
|---|---|
| Verlagsort | San Diego |
| Sprache | englisch |
| Maße | 191 x 235 mm |
| Gewicht | 1520 g |
| Themenwelt | Naturwissenschaften ► Chemie ► Anorganische Chemie |
| ISBN-10 | 0-12-801981-6 / 0128019816 |
| ISBN-13 | 978-0-12-801981-8 / 9780128019818 |
| Zustand | Neuware |
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