Organosilicon Chemistry

From Molecules to Materials

Norbert Auner, Johann Weis (Herausgeber)

XXII, 349 Seiten

1993
Wiley-VCH (Hersteller)
978-3-527-29061-1 (ISBN)

Infos

An introduction to organosilicon chemistry, focusing on applications in materials and polymer science, written by experts from industry and academia. Owing to its interdisciplinary approach this work should be of interest to industrial, organometallic, inorganic, materials and polymer chemists.

Inhalt

Part 1 Tetravalent Organosilicon Compounds: Chemistry and Structure: Introduction, N. Auner, J. Weis; structures of small silicon containing compounds - why and how?, D.W.H. Rankin; sterically overcrowded organosilicon compounds and their properties, H. Bock, J. Meuret, et al; synthesis of functionally substituted oligosilanes based on silyltriflate derivatives, W. Uhlig; electroreductive formation of Di- and polysilanes, E. Hengge, Ch. Jammegg; linear tetrasilanes with internal substituents: oligosilanes with optical activity, H. Stuger; a new way to Si-Ge and Si-Sn bonds - hexachlorodisilane cleavage of organometal phosphanes, R. Martens, W.W. du Mont; 29Si29Si coupling constants of bromo-and iododisilanes and -trisilanes - XnSi2H6n and XnSi3H8n (X = Br,1), U. Katzenbeisser, K. Hassler; calculation of the 29Si NMR chemical shifts in molecules with SiN, SiCl, and SiSi Bonds, R. Wolff, R. Radeglia; reactivity of very electron-rich organosilyl amines, W. Kaim, A. Lichtblau, et al; lithiated aminofluorosilanes as precursors for monometic and dimeric iminosilanes, K. Dippel, U. Klingebiel, et al; fluorofunctional silylamines and -hydrazines - precursors for (Si-N) ring systems, C. Drost, I. Hemme, et al; new approaches to (fluoromethyl) silanes, H. Burger, P. Moritz; homo- and heterocyclic Si-O systems - rings and cages, U. Klingebiel; silaheterocycles from intramolecular reactions of silicon-functionalized diazoacetic esters, F. Krebs, S. Bender, et al; synthesis and reaction behaviour of organoalkoxysilylphenols, E. Nietzschmann, O. Boge, et al; n-silylation: new possibilities for long-known amines, K. Paulini, H. -U Reibig; on the acid-catalyzed reaction of siloxanes with alcohols, H. Kelling, D. Lange, et al; on the reactivity of chlorosiloxanes, K. Kappler, U. Scheim, et al; chlorosilanols - more stable than you think - shown with 29Si NMR, R. Lehnert; diorganosilyl-bis (o-alkylphosphonates), K. Kellner, L. Rodewald. Part 2 Subvalent and unsaturated organosilicon compounds - formation and reactivity: introduction, N. Auner, J. Weis; basic principles of the theory of bonding in silicon compounds, R. Janoschek; expectations from an unusual compound - the chemistry of decamethylsilicocene, P. Jutzi; Cp2Si (CO) and Cp2Si(N2): complexes of decamethylsilicocene, M. Tacke, Ch. Klein, et al; silicon and phosphinomethanides - a novel entry to hypervalent and low valent organosilicon chemistry, H.H. Karsch. Part contents.

Produkt-Details

• Zusatzinfo: 78 Abb., 31 Tab.
• Verlagsort: Weinheim
• Sprache: englisch
• Gewicht: 812 g
• Einbandart: gebunden
• Themenwelt: Naturwissenschaften ► Chemie ► Anorganische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Organische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Physikalische Chemie
• Schlagworte: Organische Stoffe/Verbindungen • Siliciumverbindungen • Silicone / Silikone
• ISBN-10: 3-527-29061-3 / 3527290613
• ISBN-13: 978-3-527-29061-1 / 9783527290611
• Zustand: Neuware