Coordination Chemistry of Aluminium
John Wiley & Sons Inc (Verlag)
978-0-471-18795-0 (ISBN)
- Titel ist leider vergriffen;
keine Neuauflage - Artikel merken
Documenting the many important discoveries of the past decade, this text serves as a timely compendium of illuminating research on the contemporary aspects of synthesis and structure in organoaluminum coordination chemistry, as described by recognized experts in the field.
1. Normal and Dative Bonding in Neutral Aluminum Compounds; Arne Haaland; 1.1. Introduction; 1.2 Normal and Dative Bonds; 1.3 Dative Bonds and the VSEPR Model; 1.4 Failures of the VSEPR Model and Geminal Repulsion Radii; 1.5 Some Mean Bond Enthalpies; 1.6 Normal Bond Distances in Compounds with Three--coordinate Aluminum; 1.7 The Dissociation Enthalpies of Simple Adducts of Alanes with Electron Donors; 1.8 Aluminum--Nitrogen Compounds; 1.9. Aluminum--Phosphorus Compounds; 1.10. Aluminum--Oxygen Compounds; 1.11. Aluminum--Sulfur Compounds; 1.12. Aluminum--Halogen Compounds; 1.13. Conclusions; Acknowledgments; References; 2. Organoaminoalanes: Unusual Al--N Systems; Gregory H. Robinson; 2.1. Introduction; 2.2. Interaction of Aluminum Alkyls with Simple Amines: Al--N Cages; 2.3. Dimers, Trimers, and Tetramers: Organoaluminum Chemistry of Sterically Demanding Aryl Amines; 2.4. Reaction of Organoaluminum Moieties with Multidentate Open--chain Amines: High Coordination Number Aluminum Complexes; 2.5. Organoaluminum Chemistry of Macrocyclic Amines; 2.6. Conclusions; Acknowledgments; References; 3. The Aqueous Coordination Chemistry of Aluminum; Chris Orvig; 3.1. Introduction; 3.2. Reaction Kinetics; 3.3. Complexation in Water; 3.4. Schiff Base Complexes of Aluminum; 3.5. Applications and Implications; Acknowledgments; References; 4. Low Valent and Paramagnetic Compounds of Aluminum; Andrew R. Barron; 4.1. Introduction; 4.2. Aluminum--Carbonyl Complexes; 4.3. Unsaturated Hydrocarbons; 4.3.1. Alkenes; 4.3.2. Alkynes; 4.4. Hydrides; 4.5. Alkyls; 4.6. Clusters; 4.7. Paramagnetic Compounds of Al(III); Acknowledgments; References; 5. The Chemistry of Alkoxides, Thiolates, and the Heavier Group 16 Derivatives of Aluminum and Gallium; John P. Oliver , Rajesh Kumar, Majid Taghiof; 5.1 Introduction; 5.2. Syntheses; 5.3. Structure and Bonding; 5.4. NMR Studies; 5.5. R n (ER) 3--n Al Base Addition Compounds; 5.6. Bidentate and Polydentate Ligands; References; 6. Anionic and Cationic Organoaluminum Compounds; Jerry L. Atwood; 6.1. Introduction; 6.2. Liquid Clathrates Based on Anionic Organoaluminum
| Erscheint lt. Verlag | 16.3.1993 |
|---|---|
| Zusatzinfo | illustrations |
| Verlagsort | New York |
| Sprache | englisch |
| Maße | 153 x 236 mm |
| Gewicht | 392 g |
| Einbandart | Paperback |
| Themenwelt | Naturwissenschaften ► Chemie ► Anorganische Chemie |
| Naturwissenschaften ► Chemie ► Physikalische Chemie | |
| ISBN-10 | 0-471-18795-X / 047118795X |
| ISBN-13 | 978-0-471-18795-0 / 9780471187950 |
| Zustand | Neuware |
| Haben Sie eine Frage zum Produkt? |
aus dem Bereich
