Nicht aus der Schweiz? Besuchen Sie lehmanns.de

Steric and Stereoelectronic Effects in Organic Chemistry (eBook)

eBook Download: PDF
2016 | 1st ed. 2016
XI, 211 Seiten
Springer Singapore (Verlag)
978-981-10-1139-9 (ISBN)

Lese- und Medienproben

Steric and Stereoelectronic Effects in Organic Chemistry -  Veejendra K. Yadav
Systemvoraussetzungen
106,99 inkl. MwSt
(CHF 104,50)
Der eBook-Verkauf erfolgt durch die Lehmanns Media GmbH (Berlin) zum Preis in Euro inkl. MwSt.
  • Download sofort lieferbar
  • Zahlungsarten anzeigen

The steric and stereoelectronic effects control the rate and stereochemical outcome of reactions. Hence, a decent understanding of the related concepts is essential for successful synthetic planning. The book attempts to address several important issues related to these concepts in a simplified manner, and is intended for graduate students. It lays stress on the important aspects of steric and stereoelectronic effects and their control on the conformational profile and reactivity features. The book covers the geometrical requirements for reactions at saturated and unsaturated carbons in both cyclic and acyclic systems, and the resultant stereochemical features. The aspect of geometrical flexibility is also covered with a few examples involving intramolecular reactions. It deals with the facial selectivity of nucleophilic additions to acyclic and cyclic carbonyl compounds, and explains how the steric and stereoelectronic effects control the same. The work comments on allylic strains and their stereochemical control on different reactions with the related conformational control. It is a must read to understand the control elements, the prominent among these elements are spiro-conjugation, periselectivity, torquoselectivity, a-effect, Hammett's substituent constants, Hammond postulate, and Curtin-Hammett principle.



Veejendra K. Yadav earned his PhD under the mentorship of Dr. Sukh Dev in 1982. He has carried out his postdoctoral research at University of Calgary, Memorial University of Newfoundland, University of Ottawa, and University of Southern California over the years 1983-1990 before joining Indian Institute of Technology Kanpur (IITK) as Assistant Professor in late 1990. Over the years, he rose through ranks and became full Professor in 2001. He has taught both undergraduate and postgraduate students at IITK over the past twenty five years, and has remained a popular teacher among the students throughout. His research focuses on development of new reactions with emphasis on the construction of pharmacophores, synthesis of biologically active molecules, and computational-cum-experimental investigation of facial selectivity. He has two international patents and 80 research papers in peer reviewed journals to his credit. 

 


The steric and stereoelectronic effects control the rate and stereochemical outcome of reactions. Hence, a decent understanding of the related concepts is essential for successful synthetic planning. The book attempts to address several important issues related to these concepts in a simplified manner, and is intended for graduate students. It lays stress on the important aspects of steric and stereoelectronic effects and their control on the conformational profile and reactivity features. The book covers the geometrical requirements for reactions at saturated and unsaturated carbons in both cyclic and acyclic systems, and the resultant stereochemical features. The aspect of geometrical flexibility is also covered with a few examples involving intramolecular reactions. It deals with the facial selectivity of nucleophilic additions to acyclic and cyclic carbonyl compounds, and explains how the steric and stereoelectronic effects control the same. The work comments on allylic strains and their stereochemical control on different reactions with the related conformational control. It is a must read to understand the control elements, the prominent among these elements are spiro-conjugation, periselectivity, torquoselectivity, a-effect, Hammett's substituent constants, Hammond postulate, and Curtin-Hammett principle.

Veejendra K. Yadav earned his PhD under the mentorship of Dr. Sukh Dev in 1982. He has carried out his postdoctoral research at University of Calgary, Memorial University of Newfoundland, University of Ottawa, and University of Southern California over the years 1983–1990 before joining Indian Institute of Technology Kanpur (IITK) as Assistant Professor in late 1990. Over the years, he rose through ranks and became full Professor in 2001. He has taught both undergraduate and postgraduate students at IITK over the past twenty five years, and has remained a popular teacher among the students throughout. His research focuses on development of new reactions with emphasis on the construction of pharmacophores, synthesis of biologically active molecules, and computational-cum-experimental investigation of facial selectivity. He has two international patents and 80 research papers in peer reviewed journals to his credit.   

Steric and Stereoelectronic Control of Organic Molecular Structures and Organic Reactions.- Reactions at Saturated and Unsaturated Carbons.- Diastereoselectivity in Organic Reactions.- A(1,2) and A(1,3) Strains.- The Conservation of Orbital Symmetry (Woodward-Hoffmann Rules).- The Overlap Component of the Stereoelectronic Factor vis-à-vis the Conservation of Orbital Symmetry Rules.- Miscellaneous.

Erscheint lt. Verlag 6.6.2016
Zusatzinfo XI, 211 p. 300 illus., 83 illus. in color.
Verlagsort Singapore
Sprache englisch
Themenwelt Naturwissenschaften Chemie Organische Chemie
Naturwissenschaften Chemie Physikalische Chemie
Technik
Schlagworte Orbital Symmetry and Orbital Overlap Effects • Stereoelectronic Effects • Stereoelectronic Effects on Diastereoselectivity • Stereoelectronic Effects on Reaction Rates • Steric Effects
ISBN-10 981-10-1139-7 / 9811011397
ISBN-13 978-981-10-1139-9 / 9789811011399
Haben Sie eine Frage zum Produkt?
PDFPDF (Wasserzeichen)
Größe: 15,1 MB

DRM: Digitales Wasserzeichen
Dieses eBook enthält ein digitales Wasser­zeichen und ist damit für Sie persona­lisiert. Bei einer missbräuch­lichen Weiter­gabe des eBooks an Dritte ist eine Rück­ver­folgung an die Quelle möglich.

Dateiformat: PDF (Portable Document Format)
Mit einem festen Seiten­layout eignet sich die PDF besonders für Fach­bücher mit Spalten, Tabellen und Abbild­ungen. Eine PDF kann auf fast allen Geräten ange­zeigt werden, ist aber für kleine Displays (Smart­phone, eReader) nur einge­schränkt geeignet.

Systemvoraussetzungen:
PC/Mac: Mit einem PC oder Mac können Sie dieses eBook lesen. Sie benötigen dafür einen PDF-Viewer - z.B. den Adobe Reader oder Adobe Digital Editions.
eReader: Dieses eBook kann mit (fast) allen eBook-Readern gelesen werden. Mit dem amazon-Kindle ist es aber nicht kompatibel.
Smartphone/Tablet: Egal ob Apple oder Android, dieses eBook können Sie lesen. Sie benötigen dafür einen PDF-Viewer - z.B. die kostenlose Adobe Digital Editions-App.

Buying eBooks from abroad
For tax law reasons we can sell eBooks just within Germany and Switzerland. Regrettably we cannot fulfill eBook-orders from other countries.

Mehr entdecken
aus dem Bereich
Das Basiswissen der Chemie

von Charles E. Mortimer; Ulrich Müller

eBook Download (2019)
Georg Thieme Verlag KG
CHF 82,95