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Synthetic and Biophysical Studies on the Tridachiahydropyrone Family of Natural Products

Buch | Hardcover
XIX, 136 Seiten
2015 | 1st ed. 2016
Springer International Publishing (Verlag)
978-3-319-22068-0 (ISBN)

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Synthetic and Biophysical Studies on the Tridachiahydropyrone Family of Natural Products - Kimberley Jade Powell
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This thesis addresses fundamental scientific questions such as:
How are complex natural products synthesized in vivo?
Can we replicate these conditions in a laboratory environment?
What is the biological function of such secondary metabolites?
What are the biological origins of chirality?
These issues are explored in an accessible manner using a multidisciplinary approach spanning chemistry, biology and physics to investigate an interesting family of complex natural products isolated from marine molluscs - the tridachiahydropyrones.

The work has achieved:
Elegant biomimetic syntheses of a number of the tridachiahydropyrone compounds in vitro using organic synthesis techniques
The characterization of the interactions between these compounds and a range of model membrane systems using a series of fluorescence spectroscopic studies
The investigation of the antioxidant and photoprotective properties of the compounds by means of biophysical assay techniques
The synthesis of tridachiahydropyrone utilizing the model membrane systems as biomimetic reaction media.

Introduction.- Synthesis of the Tridachiahydropyrones and their Biomimetic Precursors.- Interactions of the Tridachiahydropyrones with Model Membrane Systems: Biophysical Studies.- Investigations into the Photoprotective and Antioxidant Properties of the Tridachiahydropyrones.- Summary and Conclusions.- Experimental.- Synthesis of Alkenyl Nitriles by the Palladium-Catalysed Cyanation of Vinyl Halides with Acetone Cyanohydrin.

Erscheint lt. Verlag 22.8.2015
Reihe/Serie Springer Theses
Zusatzinfo XIX, 136 p. 151 illus., 17 illus. in color.
Verlagsort Cham
Sprache englisch
Maße 155 x 235 mm
Themenwelt Naturwissenschaften Chemie Analytische Chemie
Naturwissenschaften Chemie Organische Chemie
Naturwissenschaften Physik / Astronomie Angewandte Physik
Schlagworte Asymmetric electrocyclisation • Biomimetic electrocyclisation • Biomimetic synthesis • Cyanation of vinyl halides/cyanation of alkenyl ha • Cyanation of vinyl halides/cyanation of alkenyl halides • Fluorescence spectroscopy • Lipid peroxidation • marine natural products • Membrane antioxidants • Natural Product Synthesis • Palladium catalysed cyanation
ISBN-10 3-319-22068-3 / 3319220683
ISBN-13 978-3-319-22068-0 / 9783319220680
Zustand Neuware
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