Organometallic Chemistry (eBook)

Plenary Lectures Presented at the Fourth International Conference on Organometallic Chemistry

M. I. Bruce, F. G. A. Stone (Herausgeber)

eBook Download: PDF

2013 | 1. Auflage
136 Seiten
Elsevier Science (Verlag)
978-1-4832-8468-2 (ISBN)

Infos

Organometallic Chemistry presents the synthesis and reactions of metal, particularly nickel, complexes of these novel ring systems. This book .reviews the characteristic species present in organolithium compounds under several conditions. Organized into seven chapters, this book begins with an overview of the mode of biosynthesis of the coenzyme that can be partially simulated in the laboratory. This text then presents a brief survey of the biochemical reactions controlled by the coenzyme. Other chapters consider the special molecular geometry of metallocenes, which offers several stereochemical problems. This book discusses as well the formation of free radicals from organotin compounds by radical breakdown of various bonds around the tin atom. The final chapter deals with the reactions of metal carbonyl clusters that are classified in photolysis, reduction, nucleophilic attack, and oxidation and reactions with electrophilic reagents. This book is a valuable resource for chemists, biochemists, stereochemists, scientists, students, and research workers.

Inhalt

Front Cover 1
Organometallic Chemistry 4
Copyright Page 5
Table of Contents 6
CHAPTER 1. TRANSITION METAL COMPLEXES OF PORPHINS, CORRINS AND RELATED COMPOUNDS 8
ABSTRACT 8
REFERENCES 20
CHAPTER 2. DIVALENT CARBON INSERTIONS INTO GROUP IV HYDRIDES AND HALIDES 24
ABSTRACT 24
INTRODUCTION 24
METHYLENATIONS WITH DIAZOMETHANE AND SUBSTITUTED DIAZOMETHANES 25
.....L...TI..S WITH HALOMETHYL–MERCURY COMPOUNDS 31
METHYLENATIONS WITH HALOMETHYL–ZINC COMPOUNDS 41
METHYLENATIONS VIA SODIUM TRICHLOROACETATE 42
ACKNOWLEDGEMENTS 43
REFERENCES 43
CHAPTER 3. CONFIGURATIONAL AND CONFORMATONAL STUDIES IN THE METALLOCENE FIELD 46
ABSTRACT 46
STEREOCHEMISTRY OF [3] FERROCENOPHANES 58
STEREOCHEMISTRY OF BIFERROCENYLS 59
ACKNOWLEDGEMENTS 64
REFERENCES 64
CHAPTER 4. RECENT DEVELOPMENTS IN THE FIELD OF ORGANIC DERIVATIVES OF GROUP IV . ELEMENTS 66
ABSTRACT 66
A. INTRODUCTION 66
.. NEW EVENTS IN THE CHEMISTRY OF CYCLOSILANES AND CYCLOGERMANES 67
C. FORMATION OF FREE RADICALS FROM ORGANOTIN COMPOUNDS 70
D. NEW EVENTS IN THE CHEMISTRY OF STANNYL RADICALS 71
ACKNOWLEDGEMENT 78
REFERENCES 78
CHAPTER 5. STRUCTURES AND REACTIVITIES OF ORGANOLITHIUM COMPOUNDS 80
ABSTRACT 80
ACKNOWLEDGEMENT 94
REFERENCES 95
CHAPTER 6. APPLICATION OF ELECTROCHEMICAL METHODS IN THE ORGANOMETALLIC CHEMISTRY OF TRANSITION METAL p-COMPLEXES 96
ABSTRACT 96
LOCALIZATION OF ELECTRON CHANGES ON METAL ATOM 104
ELECTRON CHANGES ON p-...D.D LIGAND ORBITALS 107
LOCALIZATION OF ELECTRON CHANGES ON THE ANTIBONDING ORBITALS OF s-BONDS 110
ACKNOWLEDGEMENT 118
REFERENCES 118
CHAPTER 7. SOME ASPECTS OF THE CHEMISTRY OF POLYNUCLEAR METAL CARBONYL COMPOUNDS 122
ABSTRACT 122
INTRODUCTION 122
PHOTOLYSIS, PYROLYSIS AND SN1 SUBSTITUTION 125
OXIDATION AND REACTION WITH ELECTROPHILIC REAGENTS 128
REDUCTION 129
NUCLEOPHILIC ATTACK 131
CONCLUSIONS 134
ACKNOWLEDGEMENTS 134
REFERENCES 134

Produkt-Details

• Erscheint lt. Verlag: 3.9.2013
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Anorganische Chemie
• Themenwelt: Technik
• ISBN-10: 1-4832-8468-9 / 1483284689
• ISBN-13: 978-1-4832-8468-2 / 9781483284682