International Thermodynamic Tables of the Fluid State Helium-4 (eBook)

S. Angus, R. D. McCarty, K. M. de Reuck (Herausgeber)

eBook Download: PDF

2016 | 1. Auflage
292 Seiten
Elsevier Science (Verlag)
978-1-4832-8068-4 (ISBN)

Infos

International Thermodynamic Tables of the Fluid State Helium-4 presents the IUPAC Thermodynamic Tables for the thermodynamic properties of helium. The IUPAC Thermodynamic Tables Project has therefore encouraged the critical analysis of the available thermodynamic measurements for helium and their synthesis into tables. This book is divided into three chapters. The first chapter discusses the experimental results and compares with the equations used to generate the tables. These equations are supplemented by a vapor pressure equation, which represents the 1958 He-4 scale of temperature that is defined in terms of the vapor pressure of helium-4. The second chapter are devoted to various equation of state used for the determination of thermodynamic properties. The third chapter contains IUPAC Tables, including their construction, limits, use, and accuracy. This book will be of value to physical chemists and researchers in the field.

Inhalt

Front Cover 1
International Thermodynamic Tables of the Fluid State Helium-4 4
Copyright Page 5
Table of Contents 6
List of Figures 9
Tables in Text 10
Preface 12
Introduction 16
Symbols 24
Units and Conversion Factors 25
Chapter 1. Experimental Results 28
1.1 Temperature Scale 28
1.2 The Phase Diagram 29
1.3 Invariant Points 30
1.4 Two-phase Regions 33
1.5 Single-phase Region 45
1.6 Ideal Gas Properties 55
Chapter 2. The Equation of State 57
2.1 The Estimation of the Second Virial Coefficient 57
2.2 The Estimation of the Coefficients for Equation (14A) 59
2.3 The Estimation of the Coefficients for Equation (14B) 59
2.4 The Estimation of the Coefficients for Equation (14C) 60
2.5 The Critical Region 60
Chapter 3. The IUPAC Tables 62
3.1 Physical Constants 62
3.2 Construction of the Tables 62
3.3 Limits of the Tables 75
3.4 Use and Accuracy of the Tables 76
3.5 Recommendations for Improvement of the Tables 76
Acknowledgements 78
References 80
Ideal Gas Properties 86
Table 1. Molar Entropy and Enthalpy Temperature Range, 2.5 K to 1400 K 86
Zero-pressure Properties 86
Table 1. Isothermal Enthalpy-Pressure Coefficient, Second Virial Coefficient and Speed of Sound Temperature Range, 2.5 K to 1400 K 86
Single-phase Properties 90
Table 2. Molar Volume, Entropy, Enthalpy and Isobaric Heat Capacity Pressure Range, 0.001 MPa to 70 MPa 0.001 MPa to 25 MPa Temperature Range, 2.5 K to 450 K
Table 3. Density, Compression Factor, Fugacity/Pressure Ratio and Speed of Sound Pressure Range, 0.001 MPa to 70 MPa 0.001 MPa to 25MPa Temperature Range, 2.5 K to 450 K
Table 4. Pressure, Molar Entropy, Internal Energy and Isochoric Heat Capacity Density Range, Wmolm3 to 70000molm'3 Temperature Range, 2.5 K to 1400 K 222
Properties on the Saturation Curve 276
Table 5. Pressure, Molar Volume, Enthalpy and Entropy of Gas and Liquid Phases Temperature Range, TL (2.177 3 K) to Tc (5.201 4 K) 276
Table 6. Temperature, Molar Volume, Enthalpy and Entropy of Gas and Liquid Phases Pressure Range, PL (0.005040 MPa) to Pc (0.22746 MPa) 276
Properties on the Melting Curve from the (a-y-I) Triple Point to the (a-0-1) Triple Point 284
Table 7. Pressure, Molar Volume, Entropy and Enthalpy of the Liquid Phase Temperature Range, 1.777 8 K to 14.9 K 285
Table 8. Temperature, Molar Volume, Entropy and Enthalpy of the Liquid Phase Pressure Range, 3.043 MPa to 110 MPa 286
Properties on the Lambda Curve 288
Table 9. Pressure and Molar Volume as a Function of Temperature Temperature Range, Tv (1.767 8 K) to TL (2.177 3 K) 289
Table 10. Temperature and Molar Volume as a Function of Pressure Pressure Range, PL (0.005040 MPa) to Pv (3.013 MPa) 290

Produkt-Details

• Erscheint lt. Verlag: 20.4.2016
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie
• Themenwelt: Naturwissenschaften ► Physik / Astronomie ► Thermodynamik
• Themenwelt: Technik
• ISBN-10: 1-4832-8068-3 / 1483280683
• ISBN-13: 978-1-4832-8068-4 / 9781483280684