Determination of Impurities in Nuclear Grade Sodium Metal (eBook)

Louis Silverman (Autor)

R. Belcher, H. Freiser (Herausgeber)

eBook Download: PDF

2013 | 1. Auflage
154 Seiten
Elsevier Science (Verlag)
978-1-4832-7871-1 (ISBN)

Infos

International Series of Monographs in Analytical Chemistry, Volume 44: The Determination of Impurities in Nuclear Grade Sodium Metal (and Related Sodium Compounds) provides analytical chemical procedures for the determination of impurities in nuclear grade sodium metal. This book is composed of 25 chapters, and begins with a presentation of the methods for dissolving, bulk separation, sampling, and handling of sodium metal. The rest of the book describes the procedures for impurity determination in nuclear grade sodium metals, including aluminum, bismuth, boron, cadmium, calcium, magnesium, carbon, cesium, and chloride. Other impurities considered include chromium, cobalt, copper, hydrogen, iodine, iron, lead, lithium, manganese, nickel, oxide, oxygen, and phosphorus. The last chapters examine the procedures for determination of potassium, silicon, sulfur, and uranium impurities. This book is of value to analytical and inorganic chemists.

Inhalt

Front Cover 1
The Determination of Impurities in Nuclear Grade Sodium Metal 4
Copyright Page 5
Table of Contents 8
Dedication 6
PREFACE 10
CHAPTER 1. INTRODUCTION 12
METHODS FOR DISSOLVING SODIUM METAL 12
METHODS FOR PRELIMINARY BULK SEPARATIONS OF THE SODIUM IN SALTS 13
THE SAMPLING AND HANDLING OF BULK SODIUM 14
CHAPTER 2. DETERMINATION OF ALUMINUM IN SODIUM METAL 15
REFERENCES 20
CHAPTER 3. DETERMINATION OF BISMUTH IN SODIUM METAL 21
REFERENCES 26
CHAPTER 4. DETERMINATION OF BORON IN SODIUM METAL 27
REFERENCES 33
CHAPTER 5. DETERMINATION OF CADMIUM IN SODIUM METAL 34
REFERENCES 38
CHAPTER 6. DETERMINATION OF CALCIUM AND MAGNESIUM IN SODIUM METAL 39
PART A. HYDROGEN CHLORIDE SEPARATION 39
PART B. DIRECT 8-HYDROXYQUINOLINE SEPARATION 42
REFERENCES 44
CHAPTER 7. DETERMINATION OF CARBON IN SODIUM 45
PART A. RAPID QUALITATIVE METHOD FOR ELEMENTAL CARBON BASED ON PARTICLE SIZE DISTRIBUTION 45
PART B. METHOD FOR ELEMENTAL CARBON—WET OXIDATION (1) 46
PART C. SEMI-QUANTITATIVE METHOD FOR CARBON MONOXIDE AND ACETYLENE. WET ANALYTICAL METHODS 50
PART D. A METHOD FOR TOTAL CARBON (HYDROCARBON + OXIDE CARBON + ELEMENTAL CARBON) 52
PART E. DETECTION OF CYANIDE CARBON 54
PART F. DRY COMBUSTION METHODS FOR TOTAL CARBON 56
REFERENCES 59
CHAPTER 8. DETERMINATION OF CESIUM IN SODIUM METAL 60
REFERENCES 62
CHAPTER 9. DETERMINATION OF CHLORIDE IN SODIUM METAL 63
REFERENCES 66
CHAPTER 10. DETERMINATION OF CHROMIUM IN SODIUM METAL 67
REFERENCES 73
CHAPTER 11. DETERMINATION OF COBALT IN SODIUM METAL 74
REFERENCES 78
CHAPTER 12. DETERMINATION OF COPPER IN SODIUM METAL 79
REFERENCES 84
CHAPTER 13. DETERMINATION OF HYDROGEN IN SODIUM METAL 85
REFERENCES 89
CHAPTER 14. DETERMINATION OF IODINE IN SODIUM METAL 90
REFERENCES 92
CHAPTER 15. DETERMINATION OF IRON IN SODIUM METAL 93
REFERENCES 98
CHAPTER 16. DETERMINATION OF LEAD IN SODIUM METAL 99
REFERENCES 106
CHAPTER 17. DETERMINATION OF LITHIUM IN SODIUM METAL 107
REFERENCES 110
CHAPTER 18. DETERMINATION OF MANGANESE IN SODIUM METAL 111
REFERENCES 113
CHAPTER 19. DETERMINATION OF NICKEL IN SODIUM METAL 114
REFERENCES 117
CHAPTER 20. DETERMINATION OF OXIDE–OXYGEN IN SODIUM METAL 118
PART A. AMALGAMATION METHOD, DRY BOX TECHNIQUE 118
PART B. BUTYL BROMIDE METHOD (WURTZ SYNTHESIS) 123
PART C. DISTILLATION METHOD (APPLICABLE ONLY TO SODIUM METAL) 125
REFERENCES 128
CHAPTER 21. DETERMINATION OF PHOSPHORUS IN SODIUM METAL 130
REFERENCES 133
CHAPTER 22. DETERMINATION OF POTASSIUM IN SODIUM METAL 134
REFERENCES 138
CHAPTER 23. DETERMINATION OF SILICON IN SODIUM METAL 139
REFERENCES 144
CHAPTER 24. DETERMINATION OF TOTAL SULFUR IN SODIUM METAL 145
REFERENCES 151
CHAPTER 25. DETERMINATION OF URANIUM IN SODIUM METAL 152
REFERENCES 155
INDEX 156

Produkt-Details

• Erscheint lt. Verlag: 22.10.2013
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Anorganische Chemie
• Themenwelt: Technik
• ISBN-10: 1-4832-7871-9 / 1483278719
• ISBN-13: 978-1-4832-7871-1 / 9781483278711