Introduction to Co-Ordination Chemistry (eBook)

International Series of Monographs in Inorganic Chemistry

D. P. Graddon (Autor)

A. G. Maddock, H. Taube (Herausgeber)

eBook Download: PDF

2017 | 2. Auflage
172 Seiten
Elsevier Science (Verlag)
978-1-4831-8411-1 (ISBN)

Infos

An Introduction to Co-Ordination Chemistry, Second Edition covers the fundamental aspects of co-ordination chemistry. The title is designed to introduce the readers to the basic principles and theories that govern co-ordination chemistry. The text first reviews the history of co-ordination chemistry, and then proceeds to discussing the modern theories of co-ordination chemistry. Next, the selection covers transition metal stereochemistry. Chapter IV talks about the stability of complex salts, while Chapter V deals with the stabilization of oxidation states. The text also covers carbonyls and II-complexes. In the last chapter, the title presents the practical applications of co-ordination chemistry. The book will be of great use to students, researchers, and practitioners of chemistry related disciplines.

Inhalt

Front Cover 1
An Introduction to Co-Ordination Chemistry 4
Copyright Page 5
Table of Contents 6
PREFACE TO SECOND EDITION 8
CHAPTER I. HISTORICAL INTRODUCTION 10
WERNER'S THEORY 13
SYSTEMATIC NOMENCLATURE 17
ISOMERISM 18
STEREOCHEMISTRY OF 6:CO-ORDINATE COMPOUNDS 23
STEREOCHEMISTRY OF 4:CO-ORDINATE COMPOUNDS 26
STEREOCHEMISTRY IN SOLUTION AND IN THE SOLID STATE 31
FURTHER READING 32
CHAPTER II: MODERN THEORIES OF CO-ORDINATION CHEMISTRY 33
THE OCTET THEORY-EFFECTIVE ATOMIC NUMBER 33
THE VALENCY-BOND THEORY 35
PARAMAGNETISM 39
THE CRYSTAL-FIELD THEORY 47
THE SIDGWICK-POWELL THEORY 59
FURTHER READING 63
CHAPTER III. TRANSITION METAL STEREOCHEMISTRY 64
BERYLLIUM, MAGNESIUM AND ALUMINIUM 65
NICKEL 81
COBALT 85
HIGH CO-ORDINATION NUMBERS 89
METAL-METAL BONDS 91
FURTHER READING 93
CHAPTER IV. THE STABILITY OF COMPLEX SALTS 94
THE DETERMINATION OF STABILITY CONSTANTS 95
FACTORS AFFECTING STABILITY CONSTANTS 99
CHELATION 107
CHANGE OF CO - ORDINATION NUMBER 115
FURTHER READING 116
CHAPTER V. THE STABILIZATION OF OXIDATION STATES 117
STANDARD REDUCTION POTENTIALS 117
UNUSUALLY HIGH OXIDATION STATES 126
UNUSUALLY LOW OXIDATION STATES 128
FURTHER READING 129
CHAPTER VI. CARBONYLS AND II-COMPLEXES 130
NITROSYLS 136
NITROPRUSSIDES AND COMPLEX ACETYLIDES 136
OLEFIN COMPLEXES 138
CYCLOPENTADIENYLS AND RELATED COMPOUNDS 139
FURTHER READING 148
CHAPTER VII. SOME PRACTICAL APPLICATIONS 149
INNER COMPLEXES 150
SOLVENT EXTRACTION 155
SEQUESTRATION 158
PORPHYRINS AND RELATED COMPOUNDS 160
FURTHER READING 164
AUTHOR INDEX 166
SUBJECT INDEX 168

Produkt-Details

• Erscheint lt. Verlag: 25.5.2017
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Analytische Chemie
• Themenwelt: Technik
• ISBN-10: 1-4831-8411-0 / 1483184110
• ISBN-13: 978-1-4831-8411-1 / 9781483184111