Compounds of the Transition Elements Involving Metal-Metal Bonds (eBook)

Pergamon Texts in Inorganic Chemistry, Volume 27

D. L. Kepert, K. Vrieze (Autoren)

eBook Download: PDF

2013 | 1. Auflage
175 Seiten
Elsevier Science (Verlag)
978-1-4831-5174-8 (ISBN)

Infos

Compounds of the Transition Elements Involving Metal-Metal Bonds deals with compounds of the transition elements involving metal-metal bonds, with particular emphasis on metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. Factors that influence the formation, stability, and properties of such compounds, as well as their application in various fields of chemistry and physics, are discussed. This book is divided into four sections and begins with a classification of metal-metal bonds and some of the physical and chemical methods used to study them, including X-ray crystallography, magnetic susceptibility and electron spin resonance, nuclear spin resonance, Mössbauer measurements, infrared and Raman spectroscopy, visible and ultraviolet spectroscopy, mass spectrometry, electrical conductivity, electrochemical methods, and chemical reactivity. Factors influencing the strength of metal-metal bonds in metals and compounds are also examined. The remaining sections deal with metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. This monograph will be a useful resource for inorganic chemists.

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Compounds of the Transition Elements Involving Metal-Metal Bonds deals with compounds of the transition elements involving metal-metal bonds, with particular emphasis on metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. Factors that influence the formation, stability, and properties of such compounds, as well as their application in various fields of chemistry and physics, are discussed. This book is divided into four sections and begins with a classification of metal-metal bonds and some of the physical and chemical methods used to study them, including X-ray crystallography, magnetic susceptibility and electron spin resonance, nuclear spin resonance, Mossbauer measurements, infrared and Raman spectroscopy, visible and ultraviolet spectroscopy, mass spectrometry, electrical conductivity, electrochemical methods, and chemical reactivity. Factors influencing the strength of metal-metal bonds in metals and compounds are also examined. The remaining sections deal with metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. This monograph will be a useful resource for inorganic chemists.

Inhalt

Front Cover 1
Compounds of the Transition Elements Involving Metal–Metal Bonds 4
Copyright Page 5
Table of Contents 6
PREFACE 8
Part 47: COMPOUNDS OF THE TRANSITION ELEMENTS INVOLVING METAL-METAL BONDS 10
Chapter 1. INTRODUCTION 10
1.1. GENERAL REMARKS 10
1.2. CLASSIFICATION OF METAL-METAL BONDS 11
1.3. IDENTIFICATION AND METHODS OF STUDYING METAL-METAL BONDS IN COMPOUNDS 13
1.4. FACTORS INFLUENCING THE STRENGTHS OF METAL-METAL BONDS IN METALS 23
1.5. FACTORS INFLUENCING THE STRENGTHS OF METAL-METAL BONDS IN COMPOUNDS 31
Chapter 2. METAL-METAL BONDS IN COORDINATION COMPOUNDS AND ORGANOMETALLIC COMPLEXES 41
2.1. BONDS BETWEEN TRANSITION METAL ATOMS OF THE SAME ELEMENT 41
2.2. BONDS BETWEEN DISSIMILAR TRANSITION METAL ATOMS 121
2.3. BONDS BETWEEN TRANSITION METAL AND POST-TRANSITION METAL ATOMS 126
Chapter 3. METAL-METAL BONDS IN HALIDES 148
3.1. TETRAHALIDES 148
3.2. TRIHALIDES 150
3.3. COMPOUNDS BASED ON NIOBIUM AND TANTALUM CLUSTERS 153
3.4. COMPOUNDS BASED ON MOLYBDENUM AND TUNGSTEN CLUSTERS 157
3.5. COMPOUNDS BASED ON RHENIUM CLUSTERS 158
3.6. DINUCLEAR COMPOUNDS 159
Chapter 4. METAL-METAL BONDS IN OXIDES 161
4.1. DIOXIDES (AND RELATED STRUCTURES) 161
4.2. SESQUIOXIDES (AND RELATED STRUCTURES) 164
4.3. MIXED OXIDES 165
INDEX 168
Contents of Comprehensive Inorganic Chemistry 174
INDEPENDENT OPINION 176

Produkt-Details

• Erscheint lt. Verlag: 22.10.2013
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Anorganische Chemie
• Themenwelt: Technik
• ISBN-10: 1-4831-5174-3 / 1483151743
• ISBN-13: 978-1-4831-5174-8 / 9781483151748