Inorganic Hydrides (eBook)

The Commonwealth and International Library: Chemistry Division

B. L. Shaw (Autor)

L. A. K. Stavely (Herausgeber)

eBook Download: PDF

2013 | 1. Auflage
152 Seiten
Elsevier Science (Verlag)
978-1-4831-6032-0 (ISBN)

Infos

Inorganic Hydrides focuses on the hydrides of chemical elements. The hydrides discussed in this book are classified into four principal categories - ionic, covalent, transition metal hydrides, and metallic hydrides. Hydrides that do not fit into general classification, such as hydrides of copper and zinc, can be described as borderline hydrides and form a transition in type between the covalent hydrides of the later elements of the periodic table and the metallic hydrides of the transition elements. This text begins with an introduction to the classes of hydrides and hydrides of hydrogen, discussing element by element through frequent comparisons. The transition metal hydrides and metallic hydrides are also elaborated. This selection concludes with the chapter on bonding and bond strengths in hydrides, followed by the applications of infrared, Raman, and nuclear magnetic resonance spectroscopy. The general chemistry of water and its solvent properties are also briefly deliberated. This publication is suitable for undergraduates, particularly on covering the developments and chemistry of inorganic hydrides.

Inhalt

Front Cover 1
Inorganic Hydrides 4
Copyright Page 5
Table of Contents 6
Preface 8
CHAPTER 1. The Classes of Hydrides 10
CHAPTER 2. Hydrogen and the Hydrogen Molecule 13
Hydrogen Atoms 13
Molecular Hydrogen 15
CHAPTER 3. The Alkali Metal Hydrides 19
Lithium 19
Sodium 20
Potassium 21
Rubidium 22
Caesium 22
CHAPTER 4. Beryllium, Magnesium, Calcium, Strontium, Barium 23
Beryllium 23
Magnesium 24
Calcium 25
Strontium 26
Barium 27
CHAPTER 5. Boron, Aluminium, Gallium, Indium, Thallium 28
Boron 28
Aluminium 47
Gallium 51
Indium 52
Thallium 52
CHAPTER 6. Silicon, Germanium, Tin, Lead 53
Silicon 53
Germanium 57
Tin 59
Lead 61
CHAPTER 7. Nitrogen, Phosphorus, Arsenic, Antimony, Bismuth 62
Nitrogen 62
Phosphorus 72
Arsenic 76
Antimony 77
Bismuth 78
CHAPTER 8. Oxygen, Sulphur, Selenium, Tellurium, Polonium 79
Oxygen 79
Sulphur 83
Selenium 84
Tellurium 85
Polonium 86
CHAPTER 9. Fluorine, Chlorine, Bromine, Iodine 87
Fluorine 87
Chlorine 88
Bromine 89
Iodine 89
CHAPTER 10. Complex Hydrides of Transition Metals 90
Transition Metal Hydrides Stabilized by Tertiary Phosphines and Tertiary Arsines 90
Cyclopentadienyl Hydrides 95
Carbonyl Hydrides 97
Cyano Hydrides 107
Aryl Complex Hydrides 107
Potassium Rhenium Hydride 108
CHAPTER 11. Metallic Hydrides 110
Properties 114
Bonding in Metallic Hydrides 114
CHAPTER 12. Copper, Silver, Gold, Zinc, Cadmium, Mercury 116
Copper 116
Silver 117
Gold 117
Zinc 117
Cadmium 118
Mercury 118
CHAPTER 13. Bonding, Bond Angles and Bond Strengths in Covalent Hydrides 119
Bond Energies in Covalent Hydrides 122
Force Constants 123
Bonding in Boron Hydrides 124
CHAPTER 14. Infrared, Raman and Nuclear Magnetic Resonance Spectroscopy 126
Bibliography 150
General Textbooks 150
Hydride Chemistry 150
Valency, Bonding and Bond Strength 151
Infrared and Nuclear Magnetic Resonance Spectroscopy 151
Index 152

Produkt-Details

• Erscheint lt. Verlag: 22.10.2013
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Anorganische Chemie
• Themenwelt: Technik
• ISBN-10: 1-4831-6032-7 / 1483160327
• ISBN-13: 978-1-4831-6032-0 / 9781483160320