Side Reactions in Organic Synthesis II
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Following in the footsteps of the successful "Side Reactions in Organic Synthesis" by the same, highly experienced author, this new textbook focuses on aromatic substitution reactions, both electrophilic and nucleophilic.
The coverage is reader-friendly with each chapter dealing with a certain reaction class in terms of its scope and limitations in detail, and unique in its approach since unexpected and unwanted side reactions are hard to find in the literature.
A valuable addition to the classical textbooks on organic chemistry, this is a must-have for graduate students as well as for synthetic chemists in academia and industry.
Florencio Zaragoza Dörwald studied chemistry at the Georg-August University in Göttingen, Germany, and Université LouisPasteur, Strasbourg, France, where he obtained his Ph.D. in 1990 on the synthesis of natural products under the guidance of M. Franck-Neumann and M. Miesch. He spent one postdoctoral year in both the groups of A. Pfaltz (University of Basel) and A. P. Marchand (University of North Texas), and then worked on the synthesis of unnatural amino acids at the Technical University of Dresden. From 1994 to 2007 he had a position as a medicinal chemist at Novo Nordisk A/S, Denmark. Currently, he is employed as organic chemist at Lonza AG in Visp, Switzerland.
Preface
ELECTROPHILIC ALKYLATION OF ARENES
General Aspects
Problematic Arenes
Problematic Electrophiles
ELECTROPHILIC OLEFINATION OF ARENES
General Aspects
Olefinations with Leaving-Group-Substituted Olefins
Olefinations with Unsubstituted Olefins
Olefinations with Alkynes
ELECTROPHILIC ARYLATION OF ARENES
General Aspects
Arylations with Aryl Halides
Arylations with Diazonium Salts
Arylations with Other Functionalized Arenes
Arylations with Unsubstituted Arenes
ELECTROPHILIC ACYLATION OF ARENES
General Aspects
Problematic Arenes
Problematic Electrophiles
ELECTROPHILIC HALOGENATION OF ARENES
General Aspects
Typical Side Reactions
Regioselectivity
Catalysis
Fluorinations
Electron-Deficient Arenes
Sensitive Functional Groups
ELECTROPHILIC FORMATION OF AROMATIC C-N BONDS
Nitration of Arenes
Electrophilic Aromatic Aminations
Electrophilic Aromatic Amidations
ELECTROPHILIC FORMATION OF AROMATIC C-S BONDS
Sulfonylation
Sulfinylation
Sulfenylation
AROMATIC NUCLEOPHILIC SUBSTITUTIONS
General Aspects
Problematic Electrophiles
Problematic Nucleophiles
EPILOGUE: ECONOMICS, POLITICS, AND THE QUALITY OF CHEMICAL RESEARCH
Prosperity
Slavery and Freedom
The Quality of Chemical Research
Index
| Erscheint lt. Verlag | 15.7.2014 |
|---|---|
| Verlagsort | Weinheim |
| Sprache | englisch |
| Maße | 170 x 244 mm |
| Gewicht | 687 g |
| Einbandart | Paperback |
| Themenwelt | Naturwissenschaften ► Chemie ► Organische Chemie |
| Schlagworte | Katalyse • Organische Synthese |
| ISBN-10 | 3-527-33721-0 / 3527337210 |
| ISBN-13 | 978-3-527-33721-7 / 9783527337217 |
| Zustand | Neuware |
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