Bonding and Charge Distribution in Polyoxometalates: A Bond Valence Approach

Buch | Softcover

XII, 340 Seiten

2013 | 1. Softcover reprint of the original 1st ed. 1999
Springer Berlin (Verlag)
978-3-662-15621-6 (ISBN)

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This book presents the fundamentals of bonding in polyoxometalates and related oxides based on classical bonding concepts and the bond valence model. The in-depth treatment includes a revision of the procedure for the determination of the parameters of bond length-bond valence functions, the application of the bond valence model to polyoxometalates and related oxides, and the explanation of the distribution of the bond valences, and hence of the bond lengths, over the metal-oxygen bond and of the ionic charge on the oxygen atoms. Numerous tables and figures underline and illuminate the results. The principal author is a leader in the field of polyoxometalate chemistry. This work provides for the first time a comprehensive analysis of the structure and bonding in polyoxometalates, based on classical chemical concepts and the bond valence approach, and as such is a valuable resource for chemists, physicists and material scientists working in the field.

Bond length-bond valence relationships with particular reference to polyoxometalate chemistry.- A bond model for polyoxometalate ions composed of MO6 octahedra (MOk polyhedra with k>4).- Bonding and charge distribution in isopolyoxometalate ions and relevant oxides-A bond valence approach.

Erscheint lt. Verlag	3.10.2013
Reihe/Serie	Structure and Bonding
Co-Autor	S. Fischer, D. Kurad, J. Mehmke, K.H. Tytko
Zusatzinfo	XII, 340 p.
Verlagsort	Berlin
Sprache	englisch
Maße	155 x 235 mm
Gewicht	545 g
Themenwelt	Naturwissenschaften ► Chemie ► Anorganische Chemie
	Naturwissenschaften ► Chemie ► Physikalische Chemie
	Naturwissenschaften ► Physik / Astronomie ► Thermodynamik
Schlagworte	Bindungslänge-Bindungsvalenz-Beziehungen • Bindungsvalenz-Methode • bond legth-bondvalence relationships • bond valence approach • chemical bonding • Chemische Bindung • Distribution • Polyanionen • polyanions • Polyoxometalates • Polyoxometallate
ISBN-10	3-662-15621-0 / 3662156210
ISBN-13	978-3-662-15621-6 / 9783662156216
Zustand	Neuware