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Mo Molybdenum

Hydrous Molybdates of Groups VA to VIB Metals (System Nos. 18 to 52)

Hartmut Katscher, Friedrich Schröder (Herausgeber)

Buch | Softcover

XXIV, 362 Seiten

2013 | 8th ed. 1985. Softcover reprint of the original 8th ed. 1985
Springer Berlin (Verlag)
978-3-662-07838-9 (ISBN)

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This volume contains the hydrous oxo compounds of the metals Sb to Cr (System Nos. 18 to 52) with molybdenum. (The corresponding anhydrous compounds have been described in the volumes "Molybdan" Erg.-Bd. B 1 and B 2.) With these metals, molybdenum forms monomolyb dates, isopolymolybdates, peroxomolybdates, and molybdometalates. Antimony forms only the compound H3SbM01204o' n H0 and with bismuth no hydrous oxo 2 compounds are known. More than half the volume describes the monomolybdates, isopolymolybdates, and peroxo molybdates of the alkali and alkaline earth metals, including ammonium and organic cations. First, a detailed review on the structures, spectra, and other properties of the various iso polymolybdate types is given. It also contains a comprehensive description on photochromism, a property characteristic of many of the organic ammonium polymolybdates. Then follows the description of the individual alkali compounds. The large group of molybdates with organic cations is placed after the caesium molybdates. The photochromism and the photogalvanic effect are investigated at length for (i-C3H7NH3)6[M07024)' 3 H0. The alkaline earth molybdates 2 are treated briefly compared with the alkali molybdates, e. g., no new data are available on beryllium molybdates.

1 Molybdate Hydrates with Main Group 5 Metals.- 2 Molybdate Hydrates with Alkali Metals and Ammonium.- 3 Molybdate Hydrates with Alkaline Earth Metals.- 4 Molybdate Hydrates with Subgroup 2 Metals.- 5 Molybdate Hydrates with Main Group 3 Metals.- 6 Molybdate Hydrates with Subgroup 3 Metals.- 7 Molybdate Hydrates with Subgroup 4 Metals and Thorium.- 8 Molybdate Hydrates with Main Group 4 Metals.- 9 Molybdate Hydrates with Subgroup 5 Metals.- 10 Molybdate Hydrates with Chromium.- Table of Conversion Factors.

Erscheint lt. Verlag	3.10.2013
Reihe/Serie	Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition
Reihe/Serie	Mo. Molybdän. Molybdenum (System-Nr. 53)
Mitarbeit	Chef-Herausgeber: Hartmut Katscher
Zusatzinfo	XXIV, 362 p.
Verlagsort	Berlin
Sprache	englisch
Maße	178 x 254 mm
Gewicht	743 g
Themenwelt	Naturwissenschaften ► Chemie ► Allgemeines / Lexika
Themenwelt	Naturwissenschaften ► Chemie ► Anorganische Chemie
Schlagworte	alkaline earth metal • Beryllium • Bismuth • Caesium • chromium • metals • Molybdenum
ISBN-10	3-662-07838-4 / 3662078384
ISBN-13	978-3-662-07838-9 / 9783662078389
Zustand	Neuware