Molten Salts Handbook (eBook)

George J. Janz (Autor)

eBook Download: PDF | EPUB

2013 | 1. Auflage
602 Seiten
Elsevier Science (Verlag)
978-0-323-14483-4 (ISBN)

Infos

Molten Salts Handbook focuses on the features, properties, and structure of molten salts. This book presents several topics in annotated bibliographic table form, including phase equilibria, chemical syntheses, and molten salt electrolytes. Organized into six chapters, this book starts with a tabular presentation of data of the physical properties, thermodynamic properties, electrochemical properties, practical features, as well as spectroscopy and structure of molten salts. This text then illustrates the design features of different experimental assemblies and provides information on the technique through a liberally annotated bibliography. Other chapters provide a chemical index, which offers a ready guide to the status of data over the entire range of interests. This book presents as well the properties of viscosity, density, surface tension, refractive index, and electrical conductance for different compounds as single salt melts. This book is a valuable resource for scientists and researchers from diverse fields, including theoretical and applied electrochemistry, inorganic coordination chemistry, and transition metal chemistry.

Textauszug

I.A

ATOMIC AND IONIC RADII, MELTING POINTS, AND BOILING POINTS OF SINGLE SALTS AND EUTECTICS

TABLE I.A. 1a

Atomic and Ionic (Crystal) Radii a

aIonic crystal radii are the Pauling values; see L. Pauling, “The Nature of the Chemical Bond.” Cornell Univ. Press, Ithaca, New York, 1948.

bThe number in parentheses indicates the valency of each element as the ion

TABLE I.A. 1b

Solid State Interionic Separations (Å) a,b

aAt room temperature.

bJ. Lumsden, Discussions Faraday Soc. 32, 138 (1961); from R. W. G. Wyckoff,“Crystal Structures.” Wiley (Interscience), New York, 1948.

TABLE I.A. 1c

Volumes of Anions

TABLE I.A. 2a

Formula Weights, Melting Points, and Boiling Points for Some Inorganic Compounds a,b

aThroughout Table I. A. 2a, the values enclosed in parentheses represent estimates (as reported in Ref. 2).

bThe mp is taken under pressure.

110.1 mm 400, 1 atm 540.

20.21 mm 500, 1 atm 900.

31 atm 1289.

40.2 mm 900,1 atm 1360.

51atm 282.

111 mm 900.

22mm 900.

32mm 900.

11atm O2 474.

21 atm O2 525.

31 atm O2 533.

41 atm O2 548.

51 atm O2 584.

1Explodes at 800°C.

TABLE I.A. 2b

The Effect of Pressure on Melting Points a

aJ. Lumsden, “The Thermodynamics of Molten-Salt Mixtures,” p. 10. Academic Press, New York, 1966. See also, S. P. Clark, J. Chem. Phys. 31, 1526 (1959).

TABLE I.A. 3

Melting Points of Some Quaternary Ammonium Salts R4N+X−

TABLE I.A. 4

Selected Low Melting Binary Eutectics a

Eutectic temp. (°C)

Components A-B

Composition (mole % B)

122

TlCl-CuCl

60

128

KCl-AlCl3

67

150

RbCl-CuCl

68

150

KCl-CuCl

65

171

ZnCl2-SnCl2

56

172

CuCl2-SnCl2

66

178

TlCl-SnCl2

72

180

KCl-SnCl2

62

183

NaCl-SnCl2

68

185

KBr-CuBr

68

(187) 170

NaOH-KOH

(38.7) 50.6b

193

TlCl-ZnCl2

52

210

TlCl-AgCl

60

214

CsCl-CuCl

77

215

NaCl-BeCl2; SnCl2-LiCl

50; 15

218

NaOH-LiOH

27c

220

KNO3-NaNO3

50

228

ZnCl2-KCl

46

233

SnCl2-MnCl2

5

235

AgCl-BeCl2

40

237

RbOH-NaOH

76

240

SnCl2-CoCl2

4

242

CuCl-ZnCl2

88

251

RbCl-AgCl

60

258

CsCl-AgCl

72

260

CuCl-AgCl

54

260

NaBr-NaOH

78

262

TlCl-PbCl2

14

262

KCl-ZnCl2

71

262

NaCl-ZnCl2

59.5

275

LiBr-LiOH

45

276

InCl3-ZnCl2

96

276

AgBr-PbBr2

47

280

CuCl-PbCl2

42

285

KBr-AgBr

68

286

NaOH-Na2CO3

10

290

LiCl-LiOH

63

292

PbCl2-BeCl2

53

300

LiCl-BeCl2

56

300

KBr-KOH

75

300

TlCl-BeCl2

56

306

RbOH-KOH

35

306

KCl-AgCl

70

310

AgCl-PbCl2

41

311

CoCl2-ZnCl2

93

314 (325)

NaCl-CuCl

75 (77)

316

NaCl-InCl3

39

318

RbCl-LiCl

58.3

323

CsCl-LiCl

59.3

325

AgCl-PbBr2

55

327

CdCl2-BeCl2

80

328

AgBr-PbCl2

52

334

KBr-MgBr2

35

340

PbBr2-PbO

15

340

LiCl-TlCl

62

348

PbF2-PbBr2

93

348

KBr-LiBr

60

354

KBr-PbBr2

93.5

360

LiF-FeF2

52

360

NaF-BeF2

60

361

LiCl-KCl

41.5

362

TlCl-MgCl2

26

368

CdCl2-PbCl2

62

369

InCl3-AgCl

77

372

BaCl2-BeCl2

87

378

TlCl-PbCl3

42

382

CdCl2-KCl

33

388

CdCl2-KCl

62

390

CsCl-TlCl

75

400

CuCl-CaCl2

20...

Produkt-Details

• Erscheint lt. Verlag: 11.6.2013
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Anorganische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Technische Chemie
• Themenwelt: Technik ► Bauwesen
• Themenwelt: Technik ► Umwelttechnik / Biotechnologie
• ISBN-10: 0-323-14483-7 / 0323144837
• ISBN-13: 978-0-323-14483-4 / 9780323144834