Physical Chemistry of Ionic Materials
John Wiley & Sons Ltd (Verlag)
978-0-471-99991-1 (ISBN)
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Defects play an important role in determining the properties of solids. This book provides an introduction to chemical bond, phonons, and thermodynamics; treatment of point defect formation and reaction, equilibria, mechanisms, and kinetics; kinetics chapters on solid state processes; and electrochemical techniques and applications. Offers a coherent description of fundamental defect chemistry and the most common applications. Up-to-date trends and developments within this field. Combines electrochemical concepts with aspects of semiconductor physics.
Preface; 1. Introduction; Motivation; The defect concept: Point defects as the main actors; 2. Bonding aspects: From atoms to solid state 23; Chemical bonding in simple molecules; Many atoms in contact: The solid state as a giant molecule; 3. Phonons; Einstein and Debye models; Complications; 4. Equilibrium thermodynamics of the perfect solid; Preliminary remarks; The formalism of equilibrium thermodynamics; Examples of equilibrium thermodynamics; 5. Equilibrium thermodynamics of the real solid; Preliminary remarks; Equilibrium thermodynamics of point defect formation; Equilibrium thermodynamics of electronic defects; Higher dimensional defects; Point defect reactions; Doping effects; Interactions between defects; Boundary layers and size effects; 6. Kinetics and irreversible t hermo dynamics; Transport and reaction; Electrical mobility; Phenomenological diffusion coefficients; Concentration profiles; Diffusion kinetics of stoichiometry change; Complications of matter transport; Surface reactions; Catalysis; Solid state reactions; 7 Solid state electrochemistry: Measurement techniques and applications; Preliminary remarks: Current and voltage in the light of defect chemistry; Open circuit cells; Cells under current load; Cells generating current; 8. Bibliography; Index
| Erscheint lt. Verlag | 2.4.2004 |
|---|---|
| Verlagsort | Chichester |
| Sprache | englisch |
| Maße | 178 x 252 mm |
| Gewicht | 1166 g |
| Einbandart | gebunden |
| Themenwelt | Naturwissenschaften ► Chemie ► Physikalische Chemie |
| ISBN-10 | 0-471-99991-1 / 0471999911 |
| ISBN-13 | 978-0-471-99991-1 / 9780471999911 |
| Zustand | Neuware |
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