Chromium Oxidations in Organic Chemistry
Springer Berlin (Verlag)
978-3-642-69364-9 (ISBN)
I. Introduction.- 1. The Oxidation States of Chromium.- 2. The Chemistry of Chromium(VI).- 3. Chromium(VI) as Oxidant in Organic Chemistry.- References of Chapter I.- II. Oxidation of Carbon-Hydrogen Bonds.- A. Oxidation of Alkanes.- B. Oxidation of Arylalkanes (Benzylie Oxidation).- C. Allylic Oxidation.- 1. Allylic Oxidation of Olefins With Chromium(VI) in Acetic Acid and Acetic Anhydride.- 2. Allylic Oxidation With Chromium Trioxide-Heterocyclic Bases Addition Compounds.- 3. Allylic Oxidation With Tert-butyl-chrornate.- 4. Mechanism of Allylic Oxidation.- References of Chapter II.- III. Oxidation of Carbon-Carbon Double Bonds.- A. Oxidation of Alkenes.- C. Ring Oxidation of Aromatic Compounds.- 1. Oxidation of Polynuclear Arenes With Chromium(VI) Under Acidic Conditions.- 2. Oxidation of Phenols and Aromatic Amines With Chromium(VI) Under Acidic Conditions.- 3. Oxidation of Phenols With Chromyl Chloride.- 4. Oxidation of Hydroquinone Silyl Ethers With Pyridinium Chlorochromate.- 5. Oxidation of Ortho-Allylphenols With Tetraalkylammonium Dichrornate.- 6. Oxidation of Some Aromatic Heterocyclic Compounds With Chromium(VI).- References of Chapter III.- IV. Oxidation of Alcohols.- A. Oxidation of Alcohols by Chromium(VI) Under Acidic Conditions.- B. Oxidation of Alcohols With Compounds of Chromium(VI) and Heterocyclic Bases.- C. Oxidation of Alcohols With Chromium(VI) Under Neutral Conditions.- D. Oxidation of Alcohols With Supported Chromium(VI) Reagents.- E. Mechanism of Oxidation of Alcohols.- F. Effect of the Structure and Stereochemistry of Secondary Alcohols on the Rate of Oxidation.- References of Chapter IV.- V. Oxidation of Aldehydes and Ketones.- A. Oxidation of Aldehydes.- B. Oxidation of Ketones.- References of Chapter V.- VI. Oxidation of Carbon-Metal Bonds.- A. Oxidation of Organoboron Compounds.- B. Oxidation of Organotin Compounds.- References of Chapter VI.- VII. Oxidation of Halides, Ethers, Acetals, Sulphides, and Some Nitrogen Containing Compounds.- A. Oxidation of Alkyl Halides.- B. Oxidation of Ethers.- C. Oxidation of Acetals.- D. Oxidation of Sulphides.- E. Oxidation of Alkyl Aryl Amines.- F. Oxidation of Oximes.- G. Oxidation of Hydroxylamine.- References of Chapter VII.- VIII. Some Remarks on Selectivity and Synthetic Use of Chromium (VI) Oxidation.- A. Oxidation of Carbon-Hydrogen Bond.- B. Oxidation of Carbon-Carbon Double Bonds.- C. Ring Oxidation of Aromatic Compounds.- D. Oxidation of Alcohols.- E. Oxidation of Aldehydes and Ketones.- F. Oxidation of Carbon-Metal Bonds.
Erscheint lt. Verlag | 18.11.2011 |
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Reihe/Serie | Reactivity and Structure: Concepts in Organic Chemistry |
Zusatzinfo | X, 264 p. |
Verlagsort | Berlin |
Sprache | englisch |
Maße | 170 x 244 mm |
Gewicht | 487 g |
Themenwelt | Naturwissenschaften ► Chemie ► Anorganische Chemie |
Naturwissenschaften ► Chemie ► Organische Chemie | |
Schlagworte | Alkane • Amine • aromatic • Chemistry • chromium • heterocyclic compound • Hydroxylamin • Ketone • metals • Organic Chemistry • Oxidations • Phenol • phosphorus • Polymer • Silver • sodium • stereochemistry |
ISBN-10 | 3-642-69364-4 / 3642693644 |
ISBN-13 | 978-3-642-69364-9 / 9783642693649 |
Zustand | Neuware |
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