Orthogonal Supramolecular Interaction Motifs for Functional Monolayer Architectures
Seiten
2012
|
2012
Springer Berlin (Verlag)
978-3-642-30256-5 (ISBN)
Springer Berlin (Verlag)
978-3-642-30256-5 (ISBN)
This book describes a combination of orthogonal supramolecular interactions for the design of functional monolayer architectures on surfaces, that can be used as chemical and biosensors in a wide range of applications.
Deniz Yilmaz' thesis describes a combination of orthogonal supramolecular interactions for the design of functional monolayer architectures on surfaces, that can be used as chemical and biosensors in a wide range of applications. The term "orthogonal supramolecular interactions" refers to non-covalent interactions that do not influence each other's assembly properties. Orthogonal self-assembly thus allows extended control over the self-assembly process and promotes new materials properties. The first part of the thesis employs orthogonal host-guest and lanthanide-ligand coordination interaction motifs to create supramolecular luminescent monolayers. The second part of the thesis describes the fabrication of functional monolayers on silicon and gold substrates for applications in electronics.
The results illustrate the power of weak supramolecular interactions to direct the immobilization of functional systems on surfaces. The combination of host-guest and lanthanide-ligand coordination interaction motifs on surfaces demonstrates that hybrid, multifunctional supramolecular monolayers can be fabricated by integrating different non-covalent interactions in the same system. This combination opens up new avenues for the fabrication of complex hybrid organic-inorganic materials and stimuli-responsive surfaces. Their utility is demonstrated through applications of the functional interfaces to biosensing and nanotechnology.
Deniz Yilmaz' thesis describes a combination of orthogonal supramolecular interactions for the design of functional monolayer architectures on surfaces, that can be used as chemical and biosensors in a wide range of applications. The term "orthogonal supramolecular interactions" refers to non-covalent interactions that do not influence each other's assembly properties. Orthogonal self-assembly thus allows extended control over the self-assembly process and promotes new materials properties. The first part of the thesis employs orthogonal host-guest and lanthanide-ligand coordination interaction motifs to create supramolecular luminescent monolayers. The second part of the thesis describes the fabrication of functional monolayers on silicon and gold substrates for applications in electronics.
The results illustrate the power of weak supramolecular interactions to direct the immobilization of functional systems on surfaces. The combination of host-guest and lanthanide-ligand coordination interaction motifs on surfaces demonstrates that hybrid, multifunctional supramolecular monolayers can be fabricated by integrating different non-covalent interactions in the same system. This combination opens up new avenues for the fabrication of complex hybrid organic-inorganic materials and stimuli-responsive surfaces. Their utility is demonstrated through applications of the functional interfaces to biosensing and nanotechnology.
Orthogonal Supramolecular Interaction Motifs for Functional Monolayer Architectures.- Expression of Sensitized Eu3+ Luminescence at a Multivalent Interface.- Ratiometric Fluorescent Detection of an Anthrax Biomarker at Molecular Printboards.- A Supramolecular Sensing Platform in a Microfluidic Chip.- Local Doping of Silicon Using Nanoimprint Lithography and Molecular Monolayers.- Fabrication of Two-Dimensional Organic Spin Systems on Gold.
| Erscheint lt. Verlag | 7.6.2012 |
|---|---|
| Reihe/Serie | Springer Theses |
| Zusatzinfo | XIX, 101 p. 69 illus., 51 illus. in color. |
| Verlagsort | Berlin |
| Sprache | englisch |
| Maße | 155 x 235 mm |
| Gewicht | 335 g |
| Themenwelt | Naturwissenschaften ► Chemie ► Physikalische Chemie |
| Naturwissenschaften ► Physik / Astronomie ► Festkörperphysik | |
| Technik ► Maschinenbau | |
| Schlagworte | Anthrax Biomarker Detection • Chemical Monolayer Architecture • host-guest chemistry • Lanthanide Fluorescence • Multivalent Interactions • Noncovalent Interactions • Self-Assembly • supramolecular chemistry • Supramolekulare Chemie |
| ISBN-10 | 3-642-30256-4 / 3642302564 |
| ISBN-13 | 978-3-642-30256-5 / 9783642302565 |
| Zustand | Neuware |
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