Recent Advances in Hydride Chemistry (eBook)

Maurizio Peruzzini, Rinaldo Poli (Herausgeber)

eBook Download: PDF

2002 | 1. Auflage
578 Seiten
Elsevier Science (Verlag)
978-0-08-054033-7 (ISBN)

Infos

This book has been conceived to collect the most important recent advances in all areas of hydride chemistry research, including chemical reactivity, instrumental investigation, theory, and applications in the areas of catalysis, biochemistry and materials science.

Many of the chapters have been written by the plenary lecturers of the EURO-Hydrides 2000 conference, but other leading scientists in this field have also been invited to contribute.

The first part of the book focuses on the chemistry and catalysis of transition metal hydrides.

Another block of chapters illustrates the most recent advances in the application of instrumental techniques to the study of the properties and reactivity of hydride compounds.

The final part of the book illustrates the relevance of metal-hydrogen bonds in biochemistry and materials science.

All of the chapters of this book have been evaluated by independent reviewers.

Inhalt

Cover 1
Contents 12
Chapter 1. Non-classical Hydrogen Bonding along the Pathway to the Heterolytic Splitting of Dihydrogen 14
Chapter 2. Protonation of Transition Metal Hydrides to Give Dihydrogen Complexes: Mechanistic Implications and Catalytic Applications 52
Chapter 3. Hydrides and Hydrogen Bonding: Combining Theory with Experiment 88
Chapter 4. Hydridicity of Transition Metal Hydrides and its Implications for Reactivity 102
Chapter 5. Heterolytic Cleavage of Dihydrogen by Ruthenium and Molybdenum Complexes 130
Chapter 6. Paramagnetic Mono- and Polyhydrides of the Transition Metals 152
Chapter 7. Ruthenium- and Osmium-Hydride Compounds Containing Triisopropylphosphine as Precursors for Carbon-Carbon and Carbon-Heteroatom Coupling Reactions 202
Chapter 8. New Trends in Organolanthanide Hydride Chemistry 262
Chapter 9. Dihydrogen Metal Complexes in Catalysis 284
Chapter 10. Mechanistic Aspects of Dihydrogen Activation and Catalysis by Dinuclear Complexes 312
Chapter 11. Mechanistic Aspects of Inorganic Chemistry Probed via the Parahydrogen Phenomenon 342
Chapter 12. NMR Relaxation Studies of Polynuclear Hydrides Derivatives 364
Chapter 13. Deuterium NMR Relaxation as a Method for the Characterization and Study of Transition Metal Hydride Systems in Solution 388
Chapter 14. Dihydrogen Bonded Complexes and Proton Transfer to Hydride Ligands by Spectral (IR, NMR) Studies 404
Chapter 15. Quantum Mechanical Phenomena in Dihydrogen and Polyhydride Transition Metal Systems: A Unified View 432
Chapter 16. Metal Hydride Intermediates in Hydrogenases and Nitrogenases: Enzymological and Model Studies 476
Chapter 17. Proton Wave Functions in Palladium Studied by Ab Initio Calculations and Inelastic Neutron Scattering Methods 520
Chapter 18. Hydrides for Hydrogen Storage 544
Index 570

Produkt-Details

• Erscheint lt. Verlag: 30.1.2002
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Analytische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Anorganische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Technische Chemie
• Themenwelt: Naturwissenschaften ► Physik / Astronomie
• Themenwelt: Technik
• ISBN-10: 0-08-054033-3 / 0080540333
• ISBN-13: 978-0-08-054033-7 / 9780080540337