Organobismuth Chemistry (eBook)

Tohru Ikegami, Naoki Komatsu, Yoshihiro Matano, Toshihiro Murafuji, Takuji Ogawa, Hitomi Suzuki (Autoren)

eBook Download: PDF

2001 | 1. Auflage
636 Seiten
Elsevier Science (Verlag)
978-0-08-053815-0 (ISBN)

Infos

This book is written for scientists who require information on organobismuth chemistry, either by specific topic or by compound. Organobismuth Chemistry covers, through early 1999, stoichiometric compounds that contain the Bi-C bond, not included, with the exception of a few examples, are inorganic compounds, minerals, metal alloys, and non-stoichiometric materials.

Organobismuth chemistry is covered in a comprehensive, self-contained manner. The book focuses on the academic aspects of the field, therefore, references to patents are made only when pertinent. Chapter 1 serves as an introduction to bismuth as the element. In chapters 2 to 4, organobismuth compounds are classified according to the types of compounds and dealt in detail. Chapter 5 is devoted to the use of bismuth and derivatives in organic transformations. In the first four chapters, brief to moderate descriptions for selected experimental procedures are included, they are intended to inform the readers of relevant protocols and should serve in preparative studies which are based on analogies. In the final chapter the X-ray data of fundamental and/or structurally interesting organobismuth (III) and (V) compounds are collected. At the beginning of each chapter, the text is preceded by detailed table of contents of the subject dealt in it. By inspection of the table, it should be possible to locate quickly information on a specific organobismuth compound.

Definite efforts have been made to include all factual data pertinent to an understanding of each class of organobismuth compounds. The main attention is paid to the methods of synthesis, molecular structure, and chemical behaviours of organobismuth compounds, although some knowledge of spectroscopy and other physical properties are also included. The format for presenting information has both descriptive information and numerical data. Numerical data are mostly presented in tabular form. Tables of known compounds in each chapter are organized so as to enable the readers to make easy access to the most relevant data source of a compound. The nomenclature does not follow strictly the recommendations of IUPAC, but usage is mostly consistent with common practice in the current literature. In order to help the readers to save time in looking for appropriate spectral data, an effort has also been made to provide the IR, MS, NMR and UV spectral data sources in tabular form. All references for chapters are collected together in a list at the end of the book. In the list, references are given chronologically both in code and in full form, with authors names.

This book will appeal to academic and industrial researchers alike, and will be particularly useful to chemists engaged in bench work. In addition it is hoped that this book will provide a stimulus as the basis for further development of organobismuth chemistry.

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This book is written for scientists who require information on organobismuth chemistry, either by specific topic or by compound. "e;Organobismuth Chemistry"e; covers, through early 1999, stoichiometric compounds that contain the Bi-C bond; not included, with the exception of a few examples, are inorganic compounds, minerals, metal alloys, and non-stoichiometric materials.Organobismuth chemistry is covered in a comprehensive, self-contained manner. The book focuses on the academic aspects of the field; therefore, references to patents are made only when pertinent. Chapter 1 serves as an introduction to bismuth as the element. In chapters 2 to 4, organobismuth compounds are classified according to the types of compounds and dealt in detail. Chapter 5 is devoted to the use of bismuth and derivatives in organic transformations. In the first four chapters, brief to moderate descriptions for selected experimental procedures are included; they are intended to inform the readers of relevant protocols and should serve in preparative studies which are based on analogies. In the final chapter the X-ray data of fundamental and/or structurally interesting organobismuth (III) and (V) compounds are collected. At the beginning of each chapter, the text is preceded by detailed table of contents of the subject dealt in it. By inspection of the table, it should be possible to locate quickly information on a specific organobismuth compound.Definite efforts have been made to include all factual data pertinent to an understanding of each class of organobismuth compounds. The main attention is paid to the methods of synthesis, molecular structure, and chemical behaviours of organobismuth compounds, although some knowledge of spectroscopy and other physical properties are also included. The format for presenting information has both descriptive information and numerical data. Numerical data are mostly presented in tabular form. Tables of known compounds in each chapter are organized so as to enable the readers to make easy access to the most relevant data source of a compound. The nomenclature does not follow strictly the recommendations of IUPAC, but usage is mostly consistent with common practice in the current literature. In order to help the readers to save time in looking for appropriate spectral data, an effort has also been made to provide the IR, MS, NMR and UV spectral data sources in tabular form. All references for chapters are collected together in a list at the end of the book. In the list, references are given chronologically both in code and in full form, with authors names.This book will appeal to academic and industrial researchers alike, and will be particularly useful to chemists engaged in bench work. In addition it is hoped that this book will provide a stimulus as the basis for further development of organobismuth chemistry.

Inhalt

Front Cover 1
Organobismuth Chemistry 4
Copyright Page 5
Contents 12
Foreword 6
Preface 8
About the Authors 10
Chapter 1. Introduction 18
1.1 Elemental bismuth 18
1.2 Occurrence and production 19
1.3 Physical properties of bismuth 22
1.4 Chemical properties of bismuth 25
1.5 Bismuth compounds commercially available 26
1.6 Present-day use of bismuth 30
1.7 Toxicology of bismuth and bismuth compounds 35
Chapter 2. Organobismuth(III) Compounds 38
2.1 Organobismuth(III) compounds with Bi–Group 14 element bonds 38
2.2 Organobismuth(III) compounds with Bi–Group 15 or Bi–Group 16 element bonds 90
2.3 Organobismuth(III) compounds with Bi–Group 17 element bonds 215
2.4 Triorganylbismuthine–transition metal complexes 249
2.5 Organobismuth(III) compounds with Bi–transition metal linkage 256
Chapter 3. Organobismuth(V) Compounds 264
3.1 Triorganylbismuth dihalides and related compounds 264
3.2 Oxybis(triorganylbismuth) compounds 296
3.3 Quaternary organobismuth(V) compounds 302
3.4 Quinquenary organobismuth(V) and related compounds 318
3.5 Bismuthonium ylides 323
3.6 Bismuthine imides 330
3.7 Bismuthinates and bismuthinic acids 336
3.8 Triorganylbismuthine oxides 339
Chapter 4. Bismuth-Containing Heterocycles 346
4.1 Bismacycles 346
4.2 Heterobismacycles 362
Chapter 5. Bismuth Compounds in Organic Transformations 388
5.1 Introduction 388
5.2 Oxidation 389
5.3 Reduction 414
5.4 Carbon–carbon bond forming reactions 418
5.5 Carbon–heteroatom bond forming reactions 442
Chapter 6. Structural Chemistry of Organobismuth Compounds 458
6.1 Fundamental structure parameters 458
6.2 Structures of organobismuth compounds 459
Formula Index for X-Ray Data 564
Abbreviations and Symbols 572
Procedure Index 576
Preparation of selected organobismuth compounds 576
Organic transformations based on bismuth compounds 579
Reference Code Index 582
References 588
Subject Index 632

Produkt-Details

• Erscheint lt. Verlag: 22.2.2001
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Anorganische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Organische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Physikalische Chemie
• Themenwelt: Technik
• ISBN-10: 0-08-053815-0 / 0080538150
• ISBN-13: 978-0-08-053815-0 / 9780080538150