Zeolites and Microporous Crystals (eBook)

T. Hattori, T. Yashima (Herausgeber)

eBook Download: PDF

1994 | 1. Auflage
501 Seiten
Elsevier Science (Verlag)
978-0-08-088771-5 (ISBN)

Infos

This volume comprises the proceedings of the International Symposium on Zeolites and Microporous Crystals (ZMPC '93). At this meeting progress in the following areas was discussed: crystal chemistry, synthesis, ion exchange and modification, adsorption and diffusion, intercalation and cross-linking, host-guest interaction, catalysis, applications.

Inhalt

Front Cover 1
Zeolites and Microporous Crystals 4
Copyright Page 5
Organization 6
List of Contributors 8
Preface 22
Contents 24
Part I: Synthesis 30
Chapter 1. Further Results in the Synthesis of Microporous Alumino-and Gallophosphates in the Presence of Fluoride 32
Chapter 2. Preparation, Characterisation, and Catalytic Properties of Microporous Zirconophosphate Molecularly Engineered Layered Structures (MELS(®)) 40
Chapter 2. Preparation, Characterisation, and Catalytic Properties of Microporous Zircono-phosphate Molecularly Engineered Layered Structures (MELS®) 40
Chapter 3. Synthesis of Manganese Oxide Octahedral Molecular Sieves (OMS) 48
Chapter 4. Preparation and Properties of the Pyridine Intercalates of Bismuth Molybdic Acid 54
Chapter 5. Synthesis of Titanium Pillared Clay Using Organic Medium 62
Chapter 6. Oxygenated Stabilizing Agents in the Synthesis of MFI Zeolites 70
Chapter 7. The Synthesis of Discrete Colloidal Zeolite Particles 78
Chapter 8. Study on the Isomorphous Substitution of Silicon by Tetravalent Elements (Zr, Ge, Ti) in the Framework of MFI Type Zeolites 86
Chapter 9. Synthesis and Catalytic Reaction of [Zr] ZSM-5 96
Part II: Structure 104
Chapter 10. Fine Structures of Zeolites: Defects, Interfaces and Surface Structures. An HREM Study 106
Chapter 11. Statistical Mechanics of Si, Al Ordering in A-type Zeolites 114
Chapter 12. Topological and Stereochemical Characteristics of Zeolite Frameworks 122
Chapter 13. Symmetry and Location of Titanium Within Titanium Silicalite Framework of MFI Structure 130
Chapter 14. The Topography of Vanadium in Silicalite-2 Crystal Lattice and its Catalytic Role in the Oxyfunctionalization of Alkanes 138
Chapter 15. Structure and Dynamics of Ion-exchanged Zeolites as Investigated by Molecular Dynamics and Computer Graphics 146
Chapter 16. Structural Characterization of Rhenium Impregnated Zeolite Y and ZSM-5 by 29Si and 27AI MAS NMR and IR Spectroscopy 154
Part III: Modification 162
Chapter 17. Solid-state Reactions of Zeolites 164
Chapter 18. Anion Exchange Reactions in Layer Structured Crystals 176
Chapter 19. Reactant Shape-selectivity for Cracking of Linear Paraffin on HZSM-5 Modified by CVD of Silicon Alkoxide: A Strong Dependence upon the Reaction Temperature 184
Chapter 20. New Approaches in Shape Selective Alkylation Reactions Using Pore Size Regulated MFI Zeolites 192
Chapter 21. Layered Silicate-Organic Intercalation Compounds as Photofunctional Materials 200
Chapter 22. Polymerization Inside the Molecular Sieves 208
Chapter 23. Studies of Zeolite Single Crystals: Ethene Oligomerization in HZSM-5 216
Part IV: Adsorption 224
Chapter 24. Adsorption of Lower Hydrocarbons in Zeolite NaY and Theta-1. Comparison of Low and High Pressure Isotherm Data 226
Chapter 25. Determination of Sorption Thermodynamic Functions for Multi-component Gas Mixtures Sorbed by Molecular Sieves 238
Chapter 26. Adsorption Characteristics of Hydrophobic Zeolites 246
Chapter 27. Measurements of Adsorption on Outer Surface of Zeolite and Their Influence on Evaluation of Intracrystalline Diffusivity 254
Chapter 28. Interpretation of Xenon Adsorption Isotherms and Xe-129 NMR Chemical Shifts on Ion-exchanged NaY Zeolites 262
Chapter 29. Adsorption of C8 Aromatic Isomers on Faujasite Zeolite 272
Chapter 30. Study on a New Humidity Controlling Material Using Zeolite for Building 280
Part V: Catalysis 290
Chapter 31. Novel Catalytic Functions of Metallosilicates Exerted by Isomorphous Substitution 292
Chapter 32. Selective Synthesis of Ethylenediamine from Ethanolamine and Ammonia over Zeolite Catalysts 302
Chapter 33. Para-Selectivity of Zeolites and Metallosilicates with MFI Structure 308
Chapter 34. Transition State and Diffusion Controlled Shape Selectivity in the Formation and Reaction of Xylenes 316
Chapter 35. Selective Synthesis of 4,4'-Diisopropylbiphenyl Using Mordenite Catalysts 324
Chapter 36. Mechanism of the Activation of Butanes and Pentanes over ZSM-5 Zeolites 332
Chapter 37. Conversion of Ethane into Aromatic Hydrocarbons on Zinc Containing ZSM-5 Zeolites Prepared by Solid State Ion Exchange 342
Chapter 38. Platinum-Nickel/L-zeolite Bimetallic Catalysts: Effect of Sulfur Exposure on Metal Particle Size and n-Hexane Aromatization Activity and Selectivity 350
Chapter 39. Characterization and Catalytic Performance of the Platinum KL Zeolite Treated with Chlorotrifluoromethane 360
Chapter 40. Characterization and Catalytic Properties of Zeolite-Supported Platinum-Iridium Bimetallic Catalysts Prepared by Decoration of Iridium 368
Chapter 41. Infrared Spectroscopic Study of CO Adsorption on Pt-Co Bimetallic Particles Entrapped in NaY-Zeolite 376
Chapter 42. Some Characteristics of Transition-metal Containing Y-Zeolite in CO Hydrogenation 384
Chapter 43. Ni-Mo-Y Zeolites as Catalysts for the Water-Gas Shift Reaction 392
Chapter 44. Synthesis, Characterization and Catalytic Performance of Nitrosubstituted Fephthalocyanines on Zeolite Y 400
Chapter 45. Zeolite Catalyzed Aromatic Acylation and Related Reactions 408
Chapter 46. Diels-Alder Condensation of Methyl and (-)-Menthyl Acrylates with Cyclopentadiene over Zeolites and Cation Exchanged Clays 420
Chapter 47. Controlled Preparation of Neoalkanals and Novel Cyclic Dioxepenes, Depending upon the Use of Shape Selective and Non Shape Selective Catalysts 428
Chapter 48. Redox Molecular Sieves: Recyclable Catalysts for Liquid Phase Oxidations 436
Chapter 49. Titanium Silicalites as Shape-Selective Oxidation Catalysts 446
Chapter 50. Carbon Supported TS-1 Catalysts 454
Chapter 51. Alteration of Alumina Pillared Clays for Enhanced Catalytic Activity 462
Chapter 52. Development of Pillared Clays for Industrial Catalysis 472
Chapter 53. Ni-Exchanged Sepiolite as a Fibrous Clay Catalyst for Selective Dehydration of n-Butyl Alcohol to Dibutyl Ether 482
Chapter 54. Role of the Zeolite Catalysts in the New Refining Strategies 490
Chapter 55. Liquid-Phase Hydration of Cyclohexene with Highly Silicious Zeolites 502
Chapter 56. The Synthesis of Methyl Isobutyl Ketone over Palladium Supported Zeolites 510
Chapter 57. Influence of Zeolite Secondary Porosity on Performance of Resid Hydrocracking Catalysts 518
Chapter 58. Regeneration Behaviors of Hydroisomerization Catalysts 526

Produkt-Details

• Erscheint lt. Verlag: 28.6.1994
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Anorganische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Organische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Physikalische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Technische Chemie
• Themenwelt: Naturwissenschaften ► Geowissenschaften ► Mineralogie / Paläontologie
• Themenwelt: Naturwissenschaften ► Physik / Astronomie
• Themenwelt: Technik ► Elektrotechnik / Energietechnik
• Themenwelt: Technik ► Maschinenbau
• Themenwelt: Technik ► Umwelttechnik / Biotechnologie
• ISBN-10: 0-08-088771-6 / 0080887716
• ISBN-13: 978-0-08-088771-5 / 9780080887715