Fundamentals of Molecular Catalysis (eBook)

Hideo Kurosawa, Akio Yamamoto (Herausgeber)

eBook Download: PDF | EPUB

2003 | 1. Auflage
536 Seiten
Elsevier Science (Verlag)
978-0-08-053213-4 (ISBN)

Infos

"Almost all contemporary organic synthesis involve transition metal complexes as catalysts or particular reagents. The aim of this book is to provide the reader with detailed accounts of elementary processes within molecular catalysis to allow its development and as an aid in designing novel catalytic systems. The book comprises authoritative reviews on elementary processes from experts working at the forefront of organometallic chemistry.

?This is the first book that focuses on elementary processes in transition metal complexes for understanding catalytic mechanisms
?Provides detailed description of elementary processes involved in catalytic cycles by experts in the field
?Provides an overview of the mechanisms of various homogeneous catalyses"

Inhalt

Cover 1
Contents 10
Preface 6
List of Contributors 8
Chapter 1. General Introduction 16
1.1 Introduction 16
1.2 Elucidation of catalytic mechanisms as cycles composed of elementary steps 19
1.3 Comments on elementary processes involved in metal-catalyzed organic synthesis 20
1.4 Catalytic cycles constituted of multiple components of elementary processes 66
1.5 Other relevant aspects 68
1.6 Further prospects 70
1.7 References 71
Chapter 2. Activation of Substrates with Non-Polar Single Bonds 80
2.1 Significance of the area 80
2.2 Activation pathways 80
2.3 s bond complexes 84
2.4 Non-polar s bond activation 101
2.5 Conclusion 121
2.6 References 122
Chapter 3. Activation of Substrates with Polar Single Bonds 130
3.1 Introduction 130
3.2 Carbon–halogen bond cleavage reactions 130
3.3 Carbon–oxygen bond cleavage reactions 141
3.4 Carbon–sulfur bond cleavage reactions 165
3.5 Recent developments on other polar single bond cleavage 182
3.6 Summary 195
3.7 References 195
Chapter 4. Transition Metal–Carbene Complexes in Olefin Metathesis and Related Reactions 202
4.1 Scope 202
4.2 Classification of transition metal–carbene complexes 202
4.3 Reactivity of transition metal–carbene complexes 207
4.4 Olefin metathesis 212
4.5 Catalysts for olefin metathesis 222
4.6 Conclusions 240
4.7 References 240
Chapter 5. Transmetalation 248
5.1 Introduction 248
5.2 Organic ligand transfer from main group metal to transition metal 251
5.3 Organic ligand transfer between transition metals 276
5.4 Transmetalation of main group metal compounds 298
5.5 Summary 299
5.6 References 300
Chapter 6. 1,2-Insertion and ß-Elimination 308
6.1 Introduction 308
6.2 Insertion of alkenes into M–H or M–C bonds 310
6.3 Insertion of other substrates into M–H and M–C bonds 363
6.4 Insertion into other M–E bonds 367
6.5 References 379
Chapter 7. 1,1-Insertion into Metal–Carbon Bond 388
7.1 Introduction 388
7.2 CO insertion 389
7.3 Isocyanide insertion 405
7.4 SO2 insertion 410
7.5 a-Elimination and 1,1-insertion involving alkylidene ligands 415
7.6 References 419
Chapter 8. Addition to Unsaturated Ligands 426
8.1 Introduction 426
8.2 Nucleophilic attack at coordinated ligand 427
8.3 Electrophilic attack at coordinated ligand 476
8.4 Radical attack at coordinated ligand 483
8.5 Summary 486
8.6 References 487
Chapter 9. Reductive Elimination 494
9.1 Introduction 494
9.2 Reductive elimination from d8 cis-MR(R’ )L2 complexes 495
9.3 Reductive elimination from d8 trans-MR(R’ )L2 complexes. 506
9.4 Reductive elimination from d8 p-allyl complexes 509
9.5 Reductive elimination from d6 metal complexes 511
9.6 Reductive elimination from other metal complexes 520
9.7 References 522
Subject index 528

Produkt-Details

• Erscheint lt. Verlag: 2.4.2003
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Anorganische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Organische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Physikalische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Technische Chemie
• Themenwelt: Technik ► Umwelttechnik / Biotechnologie
• ISBN-10: 0-08-053213-6 / 0080532136
• ISBN-13: 978-0-08-053213-4 / 9780080532134