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Adsorption on New and Modified Inorganic Sorbents -

Adsorption on New and Modified Inorganic Sorbents (eBook)

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1996 | 1. Auflage
923 Seiten
Elsevier Science (Verlag)
978-0-08-052602-7 (ISBN)
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There has been a lack of authoritative, current information on the structure, investigation and preparation of inorganic sorbents, their numerous applications as well as the adsorption from gaseous and liquid phases on new and chemically modified inorganic solids. This volume deals with the above-mentioned themes and presents 34 up-to-date comprehensive and critical reviews written by well-recognized authorities. The sorbents discussed are primarily mineral ones. Each contribution treats a problem critically by showing its development, presenting documentation on the state-of-the-art and identifying subjects for further research.

The book will be of interest to researchers in academic institutes and industrial laboratories engaged in the fields of surface chemistry, inorganic chemistry, adsorption, ion-exchange, catalysis, chromatography and spectroscopy of the surface phenomena, as well as to students attending graduate and postgraduate courses.


There has been a lack of authoritative, current information on the structure, investigation and preparation of inorganic sorbents, their numerous applications as well as the adsorption from gaseous and liquid phases on new and chemically modified inorganic solids. This volume deals with the above-mentioned themes and presents 34 up-to-date comprehensive and critical reviews written by well-recognized authorities. The sorbents discussed are primarily mineral ones. Each contribution treats a problem critically by showing its development, presenting documentation on the state-of-the-art and identifying subjects for further research.The book will be of interest to researchers in academic institutes and industrial laboratories engaged in the fields of surface chemistry, inorganic chemistry, adsorption, ion-exchange, catalysis, chromatography and spectroscopy of the surface phenomena, as well as to students attending graduate and postgraduate courses.

Cover 1
Contents 14
Preface 6
Author Index 10
Section 1: Preparation, Structure and Properties of New and Modified Inorganic Sorbents 20
Chapter 1.1 Computational studies on the design of synthetic sorbents for selective adsorption of molecules 22
Chapter 1.2 Controlled porosity glasses (CPGs) as adsorbents, molecular sieves, ion–exchangers and support materials 50
Chapter 1.3 Influence of pH of precipitation of hydroxides on the structure of co–precipitated adsorbents 76
Chapter 1.4 Colloidal silicas 112
Chapter 1.5 Complex carbon–mineral adsorbents: preparation, surface properties and their modification 134
Chapter 1.6 Solid-phase hydrosilylation reactions with participation of modified silica surface 166
Chapter 1.7 Structure and molecular organization of bonded layers of chemically modified silicas 210
Chapter 1.8 The chemical basis of surface modification technology of silica and alumina by molecular layering method 232
Chapter 1.9 Kinetics of organic compounds chemisorption from the gas phase on oxides surface 256
Chapter 1.10 Functionalized polysiloxane sorbents: preparation, structure, properties and use 304
Chapter 1.11 Surface structure and molecular adsorption of apatites 320
Chapter 1.12 Surface chemistry and adsorption properties of Al13 colloids 338
Section 2: Adsorption from Gaseous Phase 352
Chapter 2.1 Computer simulation of adsorption on amorphous oxide surface 354
Chapter 2.2 On the nature of the energetic heterogeneity of water/oxide interface in adsorption phenomena occurring at oxide surfaces 376
Chapter 2.3 Energetic heterogeneity of porous inorganic oxides: Adsorption and chromatographic studies 430
Chapter 2.4 Adsorption kinetics on real surfaces 454
Chapter 2.5 Inverse gas chromatography in the examination of acid–base and some other properties of solid materials 484
Chapter 2.6 Chemical and morphological characteristics of inorganic sorbents with respect to gas adsorption 498
Chapter 2.7 Structure and properties of the films formed by organic substances on silica gel surface. Investigations by inverse gas chromatography (IGC) 522
Chapter 2.8 The use of gas chromatography to study the adsorption from gaseous phase at the infinite dilution 536
Chapter 2.9 Molecular statistic and gas chromatographic study of hydrocarbons adsorption on the modified layer silicates and silica in the Henry region 558
Chapter 2.10 Micropore filling mechanism in inorganic sorbents 592
Chapter 2.11 Phase transitions in adsorbed layers 618
Chapter 2.12 Drying of gases and liquids by activated alumina 648
Section 3: Adsorption from Solution 666
Chapter 3.1 Characterization of inorganic sorbents by means of adsorption at the liquid – solid interface 668
Chapter 3.2 Study of adsorption from solutions by chromatography 692
Chapter 3.3 Equilibria of adsorption from solutions on the silica surface 724
Chapter 3.4 Adsorption from dilute solutions - some novel aspects 748
Chapter 3.5 Ion adsorption on mineral oxide surfaces 776
Chapter 3.6 Recent progress in the studies of adsorption of ionic surfactants from aqueous solutions on mineral substrates 816
Chapter 3.7 The reaction of anions and cations with metal oxides as models for their reaction with soil 848
Chapter 3.8 Problems in modelling the electrical interfacial layer in metal/oxide aqueous systems 876
Chapter 3.9 Adsorption and immersional wetting on hydrophilic and hydrophobic silicates 898
Chapter 3.10 Liquid chromatography of fullerenes and study of adsorption properties of fullerenes crystals 918
Subject Index 934
STUDIES IN SURFACE SCIENCE AND CATALYSIS 940

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